期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 78, 期 6, 页码 2693-2697出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo302442g
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资金
- National Science Foundation [CHE-1213287]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1213287] Funding Source: National Science Foundation
A new type of diarylprolinol-based catalyst, which contains a dioctylamino group in the presence of a newly developed ionic liquid supported (ILS) benzoic acid as cocatalyst, is shown to be an effective catalytic system for the asymmetric direct crossed-aldol reaction of acetaldehyde in aqueous media using brine. For the reactions studied, the catalyst loading could be reduced to 5 mol %; high yields (up to 97%) and high enantioselectivities (up to 92% ee) were also achieved for a wide variety of aromatic aldehyde.
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