期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 78, 期 20, 页码 10405-10413出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo401848z
关键词
-
资金
- MEXT, Japan [24105512]
- Grants-in-Aid for Scientific Research [24105512] Funding Source: KAKEN
We developed a practical synthesis of optically pure 3,3 '-diaryl-1,1 '-binaphthyl-2,2 '-disulfonic acids (i.e., (R)- or (S)-3,3 '-Ar-2-BINSAs) from the parent chiral sulfonimides via stepwise N-S bond cleavage of the sulfonimides and the resultant sulfonamides. This unusual synthesis, which provides arylsulfonic acids from arylsulfonamides, is valuable since common methods particularly give amines with the decomposition of sulfone groups during deprotection.
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