期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 78, 期 13, 页码 6488-6494出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo400476b
关键词
-
资金
- International S&T Cooperation Program of China [2013DFR70580]
- National Basic Research Program of China [2010CB833203]
An enantioselective cascade Michael Michael reaction between chalcones enolates and nitromethane catalyzed by a bifunctional thiourea is developed. This reaction provides a mild but efficient approach to chiral benzopyrans bearing three consecutive stereocenters in high yields with excellent stereoselectivities, and the benzopyrans can be easily transformed to the corresponding tricyclic product.
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