期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 78, 期 19, 页码 9815-9821出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo401523m
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资金
- Natural Science Foundation of Zhejiang Province [LR12B02001]
- National Natural Science Foundation of China [20902084, 21172199]
- Open Research Fund of the Key Laboratory of the Ministry of Education for Advanced Catalysis Materials [ZJHX201310]
A highly regio- and stereoselective synthesis of stereodefined beta,beta-disubstituted alkenyl ethers featuring the sequential hydroboration/Suzuki-Miyaura coupling of ynol ethers has been described. A number of functional groups, including OMe, Ac, CO2Et, CN, halides, and alkyl, (hetero)aryl, and alkenyl groups, are well-tolerated under the reaction conditions. Furthermore, it allows a facile entry to the labile diarylacetaldehydes by TFA-mediated hydrolysis of beta,beta-disubstituted vinyl ethers.
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