期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 77, 期 15, 页码 6545-6552出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo301083a
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资金
- Deutsche Forschungsgemeinschaft (DFG) [WE4815/3-1]
A molecular triad composed of a triarylamine donor, a triarylborane acceptor, and a photoisomerizable dithienylethene bridge has been synthesized and explored by cyclic voltammetry, UV-vis, and luminescence spectroscopy. The effects of irradiation with UV light and fluoride addition on the electrochemical and optical spectroscopic properties of the donor-bridge-acceptor molecule were investigated. Photoisomerization of the dithienylethene bridge affects the triarylboron reduction potential, but not the triarylamine oxidation potential. UV-vis experiments reveal that the association constant for fluoride binding at the triarylborane site is independent of the isomerization state of the bridge. Irradiation of a THF solution of our donor-bridge-acceptor molecule with UV light, followed by F- addition, leads to a different color of the sample than UV irradiation alone or F- addition alone.
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