期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 77, 期 10, 页码 4826-4831出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo3004293
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资金
- JST PRESTO from Japan Society for the Promotion of Science
- Waseda University
- Grants-in-Aid for Scientific Research [23750049] Funding Source: KAKEN
A novel example of the Suzuki-Miyaura cross-coupling reaction between sp(3)-carbon and sp(3)-carbon is described. The reaction of a diborylmethane derivative with allyl halides or benzyl halides proceeded efficiently in the presence of appropriate Pd-catalysts at room temperature. The present approaches provide functionalized homoallylboronates and alkylboronates with excellent regio- and chemoselectivities.
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