期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 77, 期 24, 页码 11119-11131出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo302135q
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资金
- EU [227127]
- Bulgarian National Science Fund [RG-09-0002(DRG-02/2)]
- Russian Foundation of Basic Research [RFBR 10-03-01122]
A synthetic route to symmetrical tetraaryltetraanthra[2,3]porphyrins (Ar(4)TAPs) was developed. Ar(4)TAPs bearing various substituents in meso-phenyls and anthracene residues were prepared from the corresponding pyrrolic precursors. The synthesized porphyrins possess high solubility and exhibit remarkably strong absorption bands in the near-infrared region (790-950 nm). The scope of the method, selection of the peripheral substituents, choice of the metal, and their influence on the optical properties are discussed together with the first X-ray crystallographic data for anthraporphyrin.
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