期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 77, 期 24, 页码 11232-11256出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo302378w
关键词
-
资金
- National Science Foundation
- National Institutes of Health Kansas University Center of Excellence in Chemical Methodology and Library Development [P50 GM069663]
A novel, efficient route to biologically and pharmaceutically important o-(dimethylamino)aryl ketones, acridones, acridinium salts, and 1H-indazoles has been developed starting from readily available hydrazones of aldehydes and o-(trimethylsilyl)aryl triflates. The reaction proceeds through arynes under mild conditions, tolerates a wide range of functional groups, and provides the final products in good to excellent yields.
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