期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 77, 期 19, 页码 8780-8786出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo301371n
关键词
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资金
- UGC-CAS program, Department of Chemistry, Jadavpur University
- CSIR, New Delhi, India
An efficient synthesis of functionalized phenanthrenes has been developed for the first time involving an iron(III)-catalyzed intramolecular coupling of 2'-alkynyl-biphenyl-2-carbaldehydes. A broad range of functionalized phenanthrene derivatives could be obtained in the present method in moderate to good yields with high chemo- and regioselectivity. This transformation can also be applied to the synthesis of an angularly fused tetracyclic compound. This method offers several advantages such as high selectivity, mild reaction conditions, and easy availability of starting materials.
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