期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 77, 期 6, 页码 2885-2892出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo3001194
关键词
-
资金
- NSF [DMR-1066116, DMS-0935165]
- P. Roy Vagelos Chair at Penn
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1066116] Funding Source: National Science Foundation
- Direct For Mathematical & Physical Scien
- Division Of Mathematical Sciences [0935165] Funding Source: National Science Foundation
trans-Chloro(1-naphthyl)bis(triphenylphosphine)nickel-(II) complex/PCy3 system has been successfully applied as catalyst for the Suzuki-Miyaura cross-coupling of aryl and heteroaryl neopentylglycolboronates with aryl and heteroaryl mesylates and sulfamates in THF at room temperature. This cross-coupling reaction tolerates various functional groups, including keto, imino, ester, ether, and cyano. Together with the nickel-catalyzed, one-pot, two-step neopentylglycolborylation, this bench stable and inexpensive Ni(II)-based catalyst can be utilized as an alternative to Ni(COD)(2)/PCy3 to provide an inexpensive, robust, and convenient synthesis of biaryl and heterobiaryl compounds.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据