期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 77, 期 24, 页码 11027-11033出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo301987c
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资金
- IISc
- RL Fine Chem
- UGC
Palladium catalyzed cross-coupling reaction of hydrazones with aryl halides in the absence of external ligand is reported. The versatility of this coupling reaction is demonstrated in showcasing the selectivity of coupling reaction in the presence of hydroxyl and amine functional groups. This method allows synthesizing a variety of heterocyclic compounds, which are difficult to access from other traditional methods and are not synthesized by employing similar coupling reactions. Application of the present methodology is validated in tandem reaction of ketones to the corresponding substituted olefins in a single pot experiment.
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