期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 76, 期 21, 页码 9060-9067出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo201679s
关键词
-
资金
- Alexander von Humboldt Foundation
o-Bromo(propa-1,2-dien-1-yl)arenes exhibit novel and orthogonal reactivity under Pd catalysis in the presence of secondary amines to form enamines (concerted Pd insertion, intramolecular carbopalladation, and terminative Buchwald-Hartwig coupling) and of amides to form indoles (addition, Buchwald-Hartwig cyclization, and loss of the acetyl group). The substrates for these reactions can be accessed in a reliable and highly selective two-step process from 2-bromoaryl bromides.
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