期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 76, 期 14, 页码 5732-5737出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo200840y
关键词
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资金
- National Basic Research Program of China [2011CB936003]
- NSFC [20872126, 2107216]
A conceptual method for the preparation of 1,2-diketones is reported. The selective C-C bond cleavage of 1,3-diketones affords the 1,2-diketones in high yields under mild reaction conditions in air by the use of FeCl3 as the catalyst and tert-butyl nitrite (TBN) as the oxidant without the use of solvent. The possible reaction mechanism is discussed. This protocol provides an expeditious route to the useful 1,2-diketones.
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