☆ 4.7 Article

Structural Effects on the Electronic Properties of Extended Fused-Ring Thieno[3,4-b]pyrazine Analogues

JOURNAL OF ORGANIC CHEMISTRY (2011)

期刊

JOURNAL OF ORGANIC CHEMISTRY

卷 76, 期 15, 页码 6383-6388

出版社

AMER CHEMICAL SOC

DOI: 10.1021/jo200850w

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类别

Chemistry, Organic

资金

National Science Foundation [DMR-0907043]
North Dakota State University
Direct For Mathematical & Physical Scien
Division Of Chemistry [0946990] Funding Source: National Science Foundation
Division Of Materials Research
Direct For Mathematical & Physical Scien [0907043] Funding Source: National Science Foundation

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摘要

The synthesis and characterization of the extended thieno[3,4-b]pyrazine analogues acenaphtho[1,2-b]thieno[3,4-e]pyrazine (3a), 3,4-dibromoacenaphtho[1,2-b]thieno[3,4-e]pyrazine (3b), 3-octylacenaphtho[1,2-b]thieno[3,4-e]pyrazine (3c), dibenzo[f,h]thieno[3,4-b]quinoxaline (4), and thieno[3',4':5,6]pyrazino[2,3-f][1,10]phenanthroline (5) are reported. Comparison of structural, electrochemical, and photophysical properties to those of simple thieno[3,4-b]pyrazines are provided in order to provide structure-function relationships within this series of compounds.

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