期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 76, 期 7, 页码 2277-2281出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo102395c
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资金
- Regional Government of Andalucia [P09-FQM-4571]
A mild method for the selective esterification of primary alcohols is described. The use of different phosphines, I-2, and imidazole allows the selective esterification: of a wide variety of acids with excellent results. The generation of a bulky phosphonitun-carboxylate salt as intermediate could justify the selectivity observed in this process. Additionally, amides also can be synthesized with use of this method.
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