期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 75, 期 15, 页码 5308-5311出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo9023396
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资金
- National Science Foundation [0750463]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0750463] Funding Source: National Science Foundation
A facile synthesis of the new electron-rich, sterically hindered proazaphosphatrane shown above is described herein. This proazaphosphatrane catalyzes the cyclotrimerization of a wide variety of isocyanates to isocyanurates under mild conditions with unprecedentedly fast reaction times, giving moderate to high product yields. It is also shown that this proazaphosphatrane can be recycled up to 5 times.
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