期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 75, 期 6, 页码 2127-2130出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo902709c
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- IWT
- FWO
- KU Leuven
- Ministerie voor Wetenschapsbeleid
A variety of meso-pyrimidinyl-substituted A(2)B- and A(3)-corroles (A = 4,6-dichloropyrimidin-5-yl) have been synthesized by careful optimization of the macrocyclization conditions. meso-Pyrimidinylcorroles offer the distinct advantage of an unprecedented broad scope of functionalization options. Highly sterically encumbered triarylcorroles were readily prepared via efficient nucleophilic aromatic Substitution and Suzuki cross-coupling procedures.
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