期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 75, 期 13, 页码 4615-4618出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo1006152
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资金
- National Natural Science Foundation of China [20872159, 20821002, 20932008]
- National Basic Research Program of China (973 Program) [2009CB825300]
With an [Ir(COD)Cl](2)/phosphoramidite ligand system, an allylic substitution of O-allyl carbamothioates was developed. The reaction proceeded in the favor of branched products with up to 93:7 branched-to-linear ratio, affording chiral S-allyl carbamothioates with up to 95% ee.
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