期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 75, 期 24, 页码 8674-8676出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo101783m
关键词
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资金
- EPSRC [EP/G027919/1]
- Pfizer
- Engineering and Physical Sciences Research Council [EP/G027919/1] Funding Source: researchfish
- EPSRC [EP/G027919/1] Funding Source: UKRI
We have developed an in-flow process for the synthesis of beta-keto esters via the BF3 center dot OEt2-catalyzed formal C-H insertion of ethyl diazoacetate into aldehydes. The beta-keto esters were then condensed with a range of amidines to give a variety of 2,6-substituted pyrimidin-4-ols.
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