期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 75, 期 5, 页码 1744-1747出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo902338w
关键词
-
资金
- National Science Foundation [07500463]
An efficient catalytic route to biaryls by employing (generally) only 0.25 mol % of Pd(OAc)(2) and 0.5 mol % of 1 in the Hiyama coupling reaction is reported. High yields for electron-rich, -neutral, and -deficient aryl chlorides are obtained. A variety of phenylsiloxanes undergo coupling with aryl bromides and chlorides with low Pd(OAc)(2)/1 loadings.
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