期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 74, 期 8, 页码 3221-3224出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo900240d
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资金
- CNRS
- Ministere de l'Enseignement Superieur et de la Recherche
A cobalt-catalyzed cross-coupling of aryl halides with 2-chloropyrimidines or 2-chloropyrazines is reported in satisfactory to high yields. The key step of this procedure is the formation of aromatic organozinc reagents and their coupling with 2-chlorodiazines using the same cobalt halide as catalyst and Zn dust under mild reaction conditions. This new cobalt-catalyzed coupling reaction represents a practical and interesting alternative to previously known methods for the synthesis of 2-aryldiazines.
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