期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 74, 期 16, 页码 6299-6302出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo901090u
关键词
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资金
- Ministry of Education, Culture, Sports, Science and Technology of Japan
- National Institute of Biomedical Innovation (NIBIO)
- Targeted Proteins Research Program
- Japan Society for the Promotion of Science (JSPS) for Young Scientists
A novel copper-catalyzed synthesis of 3-(aminomethyl) isoquinoline-fused polycyclic compounds. through four-component coupling, cyclization, and oxidation, has been developed. A Mannich-type reaction of 2-ethynylbenzaldehyde with paraformaldehyde and a secondary amine followed by treatment with a diamine component gave tricyclic isoquinolines through cascade cyclization and oxidation. Construction of fused isoquinolines of various ring sizes is also presented.
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