期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 74, 期 10, 页码 3913-3918出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo900479v
关键词
-
资金
- Ministerio de Ciencia y Tecnologia of Spain [CTQ2005-05026/BQU]
- Junta de Castilla y Leon [SA079A06]
- Universidad de Salamanca
Radical couplings of epoxides and nitriles mediated by Cp2TiCl provide a diastereoselective route to the synthesis of beta-hydroxyketones. The conditions of this aldol-like reaction are mild enough to avoid the dehydration of the beta-hydroxyketone. The scope of the coupling reaction with functionalized and tetrasubstituted epoxides has been studied. The radical character of the coupling reactions is demonstrated.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据