期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 73, 期 23, 页码 9372-9378出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo8020715
关键词
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资金
- Spanish MEC-FEDER [CTQ2007-60573/BQU, CTQ2006-00500/BQU, 2005SGR-00442]
Two different reaction pathways, the enolate arylation and the acylation of the aryl halide, can be promoted by a Pd(0) catalyst starting from beta-(2-iodoanilino) carboxamides. The intramolecular acylation of beta-(2-iodoanilino) carboxamides reported here is the first example of a nucleophilic attack of a sigma-arylpalladium species at the carboxamide group, a framework that is usually inert toward organopalladium reagents.
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