期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 73, 期 21, 页码 8133-8141出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo801503c
关键词
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资金
- National Institutes of Health [GM57873]
- Department of Defense Breast Cancer Research Program [DAMD17-03-1-0685]
The key stereochemical factors that determine transfer of asymmetry from the chiral auxiliary to the cyclopentenone in the allene ether version of the Nazarov reaction have been elucidated. On the basis of the new insights into the mechanism, two highly effective chiral auxiliaries were designed and prepared.
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