期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 73, 期 9, 页码 3654-3657出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo8003474
关键词
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[GRPHICS] Alkenyl-substituted N-heterocycles react in superacidic CF3SO3H (triflic acid) to produce dicationic intermediates. These superelectrophiles undergo cyclizations to give varied aza-polycyclic aromatic compounds in generally good yields (27-99%, 16 examples). Theoretical calculations indicate a preference for charge-separated dicationic intermediates.
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