期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 73, 期 7, 页码 2879-2882出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo702413n
关键词
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The formation and 2-amino alcohol catalyzed addition of arylzinc reagents from and with boronic acids, respectively, is drastically accelerated to a few minutes under microwave irradiation without loss of enantioselectivity (up to 98% ee). Of the amino acid derived catalysts tested, the conformationally restricted bulky substituted aziridine-2-methanols derived from serine show the best overall performance in the formation of diarylmethanols.
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