期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 17, 期 16, 页码 10759-10766出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cp01063b
关键词
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资金
- MACADEMIA
- EU Seventh Framework Programme for Research and Development, [FP7] [228862]
- Czech Science Foundation [14-07101S]
- KULeuven (Metusalem CASAS)
- IWT (MOFShape SBO grant) [110050]
- European Regional Development Fund, Polish Innovation Economy Operational Program [POIG. 02.01.00-12-023/08]
- Polish National Science Center [2013/11/N/ST5/01302]
- Marian Smoluchowski Krakow Research Consortium - Leading National Research Centre KNOW - Ministry of Science and Higher Education
- FWO
By combining experimental adsorption isotherms, microcalorimetric data, infrared spectroscopy and quantum chemical calculations the adsorption behaviour of the CPO-27/MOF-74 series (Ni, Co, Mg, Cu, and Zn) in the desulfurization of fuels is evaluated. The results show a clear influence of the metal ion on the adsorption capacity and affinity for S-heterocyclic compounds, with CPO-27(Ni) being the best performing material both in terms of capacity and affinity. The microcalorimetric data and infrared spectroscopy confirm the high affinity of CPO-27(Ni) for thiophene and similar compounds, while the computational data reveal that the origin of this outstanding adsorption performance is the strong sulfur-metal interaction.
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