Article
Food Science & Technology
Mariana Baptistao, Rodolfo Lorencatto, Marcos Nogueira Eberlin, Ana Valeria Colnaghi Simionato
Summary: A method using ICP-MS was developed and validated to analyze the elemental composition of urucum seeds. It was found that elements such as Ca, Mg, and K were present in higher levels, while elements like Al, Ba, Co, Cu, Fe, Mn, Mo, Ni, and Zn were present in lower concentrations. Statistical analysis revealed correlations between certain elements and the uneven distribution of Mo in the samples, potentially caused by soil treatment. This study provides useful information for future research on nutritional composition and farming procedures.
FOOD AND BIOPROCESS TECHNOLOGY
(2023)
Article
Chemistry, Analytical
Zheng Bo Liu, Jing Zhang, Shuo Jiang, Han Su
Summary: A new and accurate method was developed to determine the dissolved concentrations of Ga in natural waters. Chelex-100, Nobias Chelate PA-1, and Presep((R)) PolyChelate resins were compared for Ga extraction from river water and seawater. Presep((R)) PolyChelate resins were chosen for analysis due to their wide extraction range at low pHs. The optimal isotope dilution conditions for Ga concentration measurements in natural water were discussed.
Article
Chemistry, Analytical
Yanbei Zhu, Akihide Itoh
Summary: A practical method called pseudo isotope dilution (PID) was proposed to correct barium-related spectral interferences on the measurement of europium. Results confirmed its validity by determining europium in standard solutions with different concentrations of barium.
ANALYTICA CHIMICA ACTA
(2021)
Article
Chemistry, Multidisciplinary
Maite Aramendia, Diego Leite, Javier Resano, Martin Resano, Kharmen Billimoria, Heidi Goenaga-Infante
Summary: This paper presents a methodology based on isotope dilution for the mass determination and sizing of silver nanoparticles using single-particle ICP-TOFMS. The proposed method measures NP isotope ratios in a particle-to-particle approach, allowing for the characterization of NP mass and size distributions. The method optimization for precision and accuracy included the selection of spike isotopic composition and concentration.
Article
Spectroscopy
Liang Yang, Wenting Bu, Ke Xiong, Yanqiu Yang, Tongzai Yang
Summary: This study developed a method for monitoring 99Tc in solid environmental samples. The use of alkali fusion instead of acid digestion ensured minimal loss of Tc during sample preparation. A simple separation method using TRU resin in alkaline solution was established, and water was used for elution and direct measurement of Tc. The method achieved high chemical recoveries and demonstrated fast and efficient analysis.
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY
(2022)
Article
Chemistry, Analytical
Liang Fu, Guangsheng Huang, Yaobo Hu, Xianhua Chen, Jingfeng Wang, Fusheng Pan
Summary: A new strategy using N2O as a reaction gas for the simultaneous determination of nonmetallic impurity elements in high-purity magnesium alloys by ICP-MS/MS was proposed. Through O-atom and N-atom transfer reactions, spectral interferences were eliminated and higher sensitivity and lower LODs were achieved compared to other reaction modes. The accuracy of the method was evaluated and it showed consistent results with SF-ICP-MS. This study provides a systematic method for precise quantification of impurity elements and can be applied to other fields.
ANALYTICAL CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Vitor N. da Conceicao, Taynara G. Campos, Bruna M. Dalfiior, Otavio A. Heringer, Geisamanda P. Brandao, Maria Tereza W. D. Carneiro
Summary: This study successfully determined As, Co, Cr, Cu, Mn, and Pb in seawater using an optimized coprecipitation procedure, achieving low detection limits and good accuracy.
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY
(2021)
Article
Environmental Sciences
Olha Khomenko, Owen Fenton, J. J. Leahy, Karen Daly
Summary: Dairy processing sludge (DPS) and its secondary products, such as struvite, biochar, hydrochar, and ash (SRUBIAS), are being considered as alternatives to rock phosphate fertilizers. However, their impact on soil phosphorus availability and turnover rates is not well understood. This study used an isotope dilution technique (IPD) to compare the performance of chemically and thermally treated DPS in terms of phosphorus turnover in soils. The results showed that thermally treated products had poor agronomic performance as phosphorus fertilizers, potentially inhibiting phosphorus availability. On the other hand, chemically treated fertilizers demonstrated better agronomic performance but had slower rates of phosphorus buildup compared to chemical fertilizers.
JOURNAL OF ENVIRONMENTAL MANAGEMENT
(2023)
Review
Chemistry, Multidisciplinary
Philip A. Doble, Raquel Gonzalez de Vega, David P. Bishop, Dominic J. Hare, David Clases
Summary: Elemental imaging provides insights into the chemical composition of living organisms, with potential applications in understanding disease states. Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) has emerged as a principal elemental imaging technique for biologists.
Article
Physics, Atomic, Molecular & Chemical
Steve Shen, Eirik Krogstad, Elise Conte, Christopher Brown
Summary: This study presents a method for analyzing rare earth elements (REEs) by isotope dilution without the need for separating individual elements, demonstrating its reliability and accuracy. Compared to traditional methods, this approach eliminates time-consuming REE separation steps while ensuring the accuracy and stability of the analysis results.
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY
(2022)
Article
Soil Science
Zunqi Liu, Na Xu, Ting Cao, Zhengfeng An, Xu Yang, Tianyi He, Tingting Yang, Jun Meng
Summary: Soil nitrogen transformation plays a vital role in determining the availability of nitrogen in farmland. This study compared the effects of biochar and its feedstock on gross nitrogen transformation during crop growth. The results showed that straw was more effective than biochar in improving soil nitrogen transformation and availability in the long term.
EUROPEAN JOURNAL OF SOIL SCIENCE
(2023)
Article
Soil Science
Zunqi Liu, Na Xu, Ting Cao, Zhengfeng An, Xu Yang, Tianyi He, Tingting Yang, Jun Meng
Summary: Soil nitrogen (N) transformation plays a vital role in determining the availability of N in farmland. This study investigated the dynamics of soil gross N transformation during maize growth in long-term biochar-amended soils and compared it with the effect of its feedstock, straw. The results showed that straw was more effective than biochar at improving soil N transformation and availability in the long term. Biochar did not significantly change the rate of gross N mineralization compared to no amendment, while straw significantly increased it, resulting in higher cumulative gross N mineralization.
EUROPEAN JOURNAL OF SOIL SCIENCE
(2023)
Article
Multidisciplinary Sciences
Thibaut Van Acker, Sarah Theiner, Eduardo Bolea-Fernandez, Frank Vanhaecke, Gunda Koellensperger
Summary: Inductively coupled plasma mass spectrometry (ICP-MS) combines plasma chemistry with mass spectrometric detection to ionize elemental samples. It is capable of handling liquid, solid, and gaseous samples efficiently. ICP-MS is widely used for (ultra-)trace multi-elemental analysis and isotopic analysis. This Primer discusses the major analytical applications of ICP-MS and provides examples of measurement strategies and challenges.
NATURE REVIEWS METHODS PRIMERS
(2023)
Article
Chemistry, Multidisciplinary
Marin Senila, Oana Cadar, Maria-Alexandra Hoaghia, Zamfira Dinca, Lacrimioara Senila, Ioan Aschilean, Cecilia Roman
Summary: This paper presents the validation of a method for determining exchangeable cations in zeolites using ICP-OES, showing rapid, accurate analysis. The method validation demonstrates that the method has suitable precision and accuracy, meeting the requirements of the ISO/IEC 17025:2017 standard.
STUDIA UNIVERSITATIS BABES-BOLYAI CHEMIA
(2021)
Article
Environmental Sciences
Simone Heilgeist, Ryo Sekine, David Clases, Oz Sahin, Rodney A. Stewart
Summary: This study investigates the behavior of nano-TiO2 in swimming pool water and the effectiveness of a common pool filter in removing nano-TiO2. The results show that the addition of sunscreen significantly increases the concentration of nano-TiO2 in the water, but most of it is removed after 3 days of filtration. The filter is able to remove Ti-containing particles, and Ti accumulates near the filter core.