Article
Physics, Applied
Milan Kubicki, Susi Lindner-Franz, Mario Daehne, Martin Franz
Summary: The growth of Co phthalocyanine films on one-dimensional Si(111)(4 x 1)-In surface was studied using scanning tunneling microscopy. It was found that at low coverages, the molecules were mobile, but they stabilized and formed a highly ordered two-dimensional monolayer as the coverage approached saturation. A structure model for this film was developed based on STM images, showing molecules selectively adsorbing on In chains with a periodicity of (4 x 4).
APPLIED PHYSICS LETTERS
(2021)
Article
Chemistry, Multidisciplinary
Jianmei Huang, Qiang Wang, Pengfei Liu, Guang-hui Chen, Yanhui Yang
Summary: The study demonstrated that the interaction strength and interface distance of Gr/h-BN/metal can be tuned by regulating the chemical composition of the surface alloy. The absorption behavior of graphene on h-BN/Cu(111)-Ni and h-BN/Ni(111)-Cu interfaces varied significantly with different Ni/Cu atomic percentages.
Article
Chemistry, Physical
Umamahesh Thupakula, Priya Laha, Gertjan Lippertz, Koen Schouteden, Asteriona-Maria Netsou, Aleksandr Seliverstov, Herman Terryn, Lino M. C. Pereira, Chris Van Haesendonck
Summary: Two-dimensional allotropes of tellurium, known as tellurene, have recently attracted attention in materials research due to their exotic properties in ultrathin form. This study reports the observation of three different 2D superstructures of tellurene on Au(111) surfaces using an alternative experimental deposition approach. The superstructures were characterized using scanning tunneling microscopy and spectroscopy, Auger electron spectroscopy, and field emission AES. The study found that the formation of these superstructures led to changes in the surface reconstruction of Au(111), and the electronic properties of the tellurium atoms showed a strong dependence on their structural arrangement. The emergence of band gaps with a p-type charge character was observed in two of the superstructures on Au(111).
JOURNAL OF CHEMICAL PHYSICS
(2022)
Article
Chemistry, Multidisciplinary
Degong Ding, Shuang Wang, Yipu Xia, Pai Li, Daliang He, Junqiu Zhang, Sunwen Zhao, Guanghui Yu, Yonghui Zheng, Yan Cheng, Maohai Xie, Feng Ding, Chuanhong Jin
Summary: This study investigates the nucleation and growth behaviors of monolayer molybdenum disulfide (MoS2) and molybdenum diselenide (MoSe2) on a gold substrate using cross-sectional scanning transmission electron microscopy. It is found that most domains nucleate on surface terraces, and higher surface steps affect the integrity and thickness of the films. The study also confirms the existence of significant compressive residual strain on the gold substrate.
Article
Chemistry, Physical
Chuan Deng, Junbo Wang, Huaming Zhu, Chaojie Xu, Xing Fan, Yinglai Wen, Peipei Huang, Haiping Lin, Qing Li, Lifeng Chi
Summary: This study successfully synthesized chiral distorted Kagome lattice and found that it is formed by multiple intermolecular hydrogen bonds. The network structures can be rationally tuned by adjusting the stoichiometric ratio of the reaction precursors, providing new strategies for synthesizing complex low-dimensional nanostructures on metal surfaces.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2023)
Article
Chemistry, Physical
Bharti, Debabrata Deb
Summary: We investigated the ordering phenomena in two-dimensional liquid crystals over a one-dimensional periodic substrate using molecular dynamics simulations. The periodicity of the substrate plays a crucial role in the phase transitions of the liquid crystal system, with small periodicity stabilizing a disordered phase, intermediate periodicity leading to a modulated smectic phase, and larger periodicity causing the system to return to a nematic phase similar to a free system without substrate.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Article
Crystallography
Yingnan Huang, Jianxun Liu, Xiujian Sun, Xiaoning Zhan, Qian Sun, Hongwei Gao, Meixin Feng, Yu Zhou, Hui Yang
Summary: We report on the epitaxial lateral overgrowth (ELO) of high-quality AlN on stripe-patterned Si(111) substrates with various trench widths. By narrowing down the trench and ridge widths of patterned Si substrates, crack-free, 6-micrometer-thick, high-quality AlN films on Si substrates were produced. This work paves the way for the fabrication of high-performance Al(Ga)N-based thin-film devices on Si.
Article
Physics, Applied
Katrin Pingen, Stefan Neuhaus, Niklas Wolff, Lorenz Kienle, Agne Zukauskaite, Elizabeth von Hauff, Alexander M. Hinz
Summary: The increasing demand for More than Moore devices requires epitaxy technology to keep up with the discovery and deployment of new semiconductors. An emerging technology for cost-effective, device-quality growth is magnetron sputter epitaxy, though detailed studies on the process itself remain scarce.
JOURNAL OF APPLIED PHYSICS
(2023)
Article
Chemistry, Multidisciplinary
Roberto Rosati, Frank Lengers, Christian Carmesin, Matthias Florian, Tilmann Kuhn, Frank Jahnke, Michael Lorke, Doris E. Reiter
Summary: Nanobubbles formed in monolayers of transition metal dichalcogenides can capture electrons and exhibit complex spatiotemporal dynamics of electronic density. By controlling multiple electronic wave packets, the electronic states can be fully manipulated, providing a foundation for novel implementations of quantum circuits.
Article
Chemistry, Physical
Andrey A. Kistanov, Vladimir R. Nikitenko, Oleg Prezhdo
Summary: This study investigated seven kinds of point defects in a two-dimensional phosphorus carbide gamma allotrope, finding that these defects have a significant impact on the electronic structure of the material, with slightly higher formation energies compared to other materials.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2021)
Article
Chemistry, Physical
Jiaduo Zhu, Kai Su, Zeyang Ren, Yao Li, Jinfeng Zhang, Jincheng Zhang, Lixin Guo, Yue Hao
Summary: The difficulty in activating ambipolar doping in diamond has limited its performance for electronic devices. Surface conduction by two-dimensional carriers has been the main focus, but generating ambipolar carriers, particularly 2DEG, remains a challenge. The diamond/cBN(111) interfaces can induce 2D ambipolar carriers, providing potential for complementary logic applications and quantum information processing.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)
Article
Chemistry, Multidisciplinary
Lukas Hormann, Andreas Jeindl, Oliver T. Hofmann
Summary: Virtually all organic (opto)electronic devices rely on organic/inorganic interfaces with specific properties. A study found that a change in interface structure can introduce a shift in function. Researchers achieved this by using tetrachloropyrazine on Pt(111), which created switchable interface structures with significantly different adsorption geometries. These structures facilitated different work function changes and coherent fractions, making them ideal for reading out the interface state. The possibility of reversible switching between different classes of structures was demonstrated, creating a dynamic interface for potential applications in organic electronics.
Article
Chemistry, Multidisciplinary
Djuro Bikaljevic, Carmen Gonzalez-Orellana, Marina Pena-Diaz, Dominik Steiner, Jan Dreiser, Pierluigi Gargiani, Michael Foerster, Miguel Angel Nino, Lucia Aballe, Sandra Ruiz-Gomez, Niklas Friedrich, Jeremy Hieulle, Li Jingcheng, Maxim Ilyn, Celia Rogero, Jose Ignacio Pascual
Summary: Metal dihalides, such as NiBr2, exhibit promising semiconducting and magnetic behavior on Au(111) substrates, showing potential for applications in tunneling junctions and low-dimensional devices. Experiments using various techniques revealed competing layer structures of NiBr2 at the interface, with a magnetically ordered state below 27K attributed to a non-collinear magnetic structure in the single layer.
Article
Materials Science, Multidisciplinary
Qikun Tian, Puxuan Li, Jinghui Wei, Ziyu Xing, Guangzhao Qin, Zhenzhen Qin
Summary: In this study, SiSnSb2 and GeSnSb2 monolayers with inverse Janus structures are predicted to have isolated spin-splitting bands near the Fermi level, and the Rashba effect in these monolayers can be more efficiently modulated by the external electric field.
Article
Multidisciplinary Sciences
Myungjae Lee, Hanyu Hong, Jaehyung Yu, Fauzia Mujid, Andrew Ye, Ce Liang, Jiwoong Park
Summary: This paper reports three-atom-thick waveguides, called delta waveguides, based on wafer-scale molybdenum disulfide (MoS2) monolayers, which can guide visible and near-infrared light over millimeter-scale distances with low loss and efficient in-coupling. The extreme thinness of the waveguides enables a light-trapping mechanism similar to a delta-potential well in quantum mechanics, allowing for guided waves that propagate freely along the in-plane direction but are confined along the out-of-plane direction. The integration of thin-film optical components with delta waveguides demonstrates key functionalities essential for two-dimensional photonics.
Article
Chemistry, Multidisciplinary
Jintong Guan, Cong Sun, Conglin Zhang, Qingfeng Guan, Erjun Kan
Summary: By using density functional theory, researchers have discovered a two-dimensional crystal Al2Te5 monolayer with a small adjustable indirect band gap, which exhibits strong light absorption performance in the visible light spectrum, with an absorption coefficient of 10(8) cm(-1). In addition, the indirect band gap can be converted to a direct one under biaxial strain. These advantages provide important possibilities for future applications in photovoltaic devices.
Article
Chemistry, Physical
You Li, Xing Cheng, Yibin Zhao, Mingyan Liu, Fang Li, Chengxi Huang, Lun Dai, Yi Wan, Erjun Kan
Summary: A one-step chemical vapor deposition method was proposed to prepare Mn-substituted MoS2 monolayers, which exhibit robust magnetism. The microscopic origin of magnetism in Mn-MoS2 was revealed through first-principles calculations, demonstrating potential applications in spintronic devices and next-generation memory components.
JOURNAL OF PHYSICAL CHEMISTRY C
(2023)
Article
Microbiology
Qing He, Shaohua Lu, Yun Lin, Lihui Xu, Zhen Chen, Quanxi Wang
Summary: In this study, it was found that FAdV-4 evaded innate immune response by degrading PKR protein in host cells, thus enhancing viral replication.
VETERINARY MICROBIOLOGY
(2023)
Article
Multidisciplinary Sciences
Xiaoyang Wang, Zhenyu Wang, Pengyue Gao, Chengqian Zhang, Jian Lv, Han Wang, Haifeng Liu, Yanchao Wang, Yanming Ma
Summary: This study reported an extensive exploration of the energy landscape of lithium (Li) using an advanced crystal structure search method and a machine learning approach. Four complex Li crystal structures containing up to 192 atoms in the unit cell were predicted, and they were found to be energetically competitive with known Li structures. These findings offer a viable solution to the yet unidentified crystalline phases of Li and demonstrate the predictive power of the global structure search method in conjunction with accurate machine learning potentials for discovering complex crystal structures.
NATURE COMMUNICATIONS
(2023)
Article
Chemistry, Physical
Hanwen Jian, Tongyu Wang, Kaiming Deng, Ang Li, Zikun Liang, Erjun Kan, Bo Ouyang
Summary: Extensive research has been conducted on the development of high-rate and cyclic stability anodes for lithium batteries (LIBs) due to their high energy density. In this study, a free-standing carbon nanotubes-graphene (CGF) foam was designed and synthesized, and a facile strategy to fabricate the MoS2-coated CGF self-assembly anodes with different MoS2 distributions was presented. The MoS2-coated CGF with uniformly distributed MoS2 exhibits a nano pinecone-squama-like structure that can accommodate the large volume change during the cycle process, thereby significantly enhancing the cycling stability, ideal rate performance, and high pseudocapacitive behavior.
Article
Chemistry, Multidisciplinary
Fang Li, Hui Zhang, You Li, Yibin Zhao, Mingyan Liu, Yunwei Yang, Jiamin Yao, Shaolong Min, Erjun Kan, Yi Wan
Summary: Modulating valley pseudospin with interface engineering is crucial for the fabrication of conceptual devices in microelectronics.
Article
Chemistry, Physical
Zikun Liang, Ang Li, Kaiming Deng, Bo Ouyang, Erjun Kan
Summary: By modulating the carbonization temperatures, porous carbon nanospheres (PCSs) with different microstructures can be obtained. The PCSs carbonized at 850℃ show increased surface area, electrical conductivity, and enhanced specific capacity, leading to excellent performances in lithium-ion batteries.
Article
Chemistry, Physical
Haiping Wu, Yuelin Li, Yan Qian, Erjun Kan
Summary: In this study, a series of C4N3 compounds were designed using first-principles calculations. The ABC-stacked compound exhibits antiferromagnetic ordering and has a hardness of 54.0 GPa, while being a semiconductor. This work opens a potential way to design magnetic superhard materials and has attracted attention in the field of spintronics.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)
Article
Chemistry, Physical
Zhengwei Du, Kaiming Deng, Erjun Kan, Cheng Zhan
Summary: This study systematically investigates the oxygen reduction reaction (ORR) activity of 40 different 3d transition metal single-atom catalysts (SACs) supported on nitrogen-doped graphene supports using density functional theory (DFT) calculations. It is found that partial C substitution can effectively improve the ORR performance of Mn, Co, Ni, and Zn-based SACs, and this coordination-tuned ORR activity can be explained by the shift of the d-band center due to the coordination effect. Four candidates with optimal ORR activity and dynamic stability were proposed. This work provides a feasible designing strategy to improve the ORR activity of graphene-based TM-N-4 SACs by tuning the coordination environment, which may have potential implication in the high-performance fuel cell development.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)
Article
Chemistry, Multidisciplinary
Huasheng Sun, Kaiming Deng, Erjun Kan, Yongping Du
Summary: Based on first-principles calculations, we studied the ferroelectric properties of 2D materials NbO2X (X = I, Br). The results show that exfoliating NbO2I monolayer is feasible, and both NbO2I and NbO2Br monolayers exhibit dynamic and thermal stability. The ground state of both materials is the ferroelectric phase, with high in-plane ferroelectric polarizations and Curie temperatures. The origin of ferroelectricity in NbO2X is revealed to be the second-order Jahn-Teller effect. Our findings suggest that these monolayers are promising for practical ferroelectric applications.
NANOSCALE ADVANCES
(2023)
Article
Materials Science, Multidisciplinary
Xin-Ling He, Peiyu Zhang, Yuan Ma, Hefei Li, Xin Zhong, Yanchao Wang, Hanyu Liu, Yanming Ma
Summary: Researchers predict a ternary hydride, YSrH22, by introducing an additional metal element into the binary hydride. The H electron density of states at the Fermi level in YSrH22 is significantly enhanced compared to the parent hydride, which could lead to higher superconductivity.
Article
Chemistry, Physical
Zeying Zhou, Cheng Zhan, Erjun Kan
Summary: This study used first-principles Density Functional Theory (DFT) to investigate the piezocatalytic properties of the BaTiO3 (001) surface. The simulation results showed that the thickness of BTO significantly affected the band structure, polarization charge distribution, and surface work function of both the positively and negatively polarized sides. The changes in the band structure under applied strain determined the theoretical catalytic activity of BaTiO3 (001) for water splitting. Furthermore, the study revealed the effects of piezoelectricity on the surface adsorption energy of H and OH species. These findings provide new insights into the fundamental mechanism of piezocatalysis.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)
Article
Chemistry, Physical
Zeying Zhou, Erjun Kan, Kaiming Deng, Tadashi Ogitsu, Tuan Anh Pham, Cheng Zhan
Summary: This study investigates the OER behavior and mechanism on the IrO2(110) surface using first-principles calculations and a microkinetics model. The research finds that the surface hydrogen coverage has a significant effect on OER kinetics and transition states. A continuous evolution model related to the applied potential is developed, leading to significant improvement in the simulated Tafel plot compared to available experiments.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Hailing Huo, Hua He, Chengxi Huang, Xin Guan, Fang Wu, Yongping Du, Hongbin Xing, Erjun Kan, Ang Li
Summary: In this study, a mesoporous superhydrophobic Cu2O hollow structure was developed for efficient gas transport and utilization of CO2 in photocatalytic reduction reactions. The structure prevents water infiltration and accumulates CO2, allowing continuous delivery of CO2 to the reactive sites and achieving the highest ethanol formation rate.
Article
Chemistry, Physical
You Li, Yi Wan, Jiamin Yao, Hongqian Zheng, Xi Wang, Xuan Liu, Bo Ouyang, Chengxi Huang, Kaiming Deng, Erjun Kan
Summary: This study explores the hydrogen evolution catalytic activity of nitrogen-doped nanostructured MoS2 powder through experiments and theoretical calculations. The results show that the hydrogen evolution catalytic activity of MoS2 can be regulated by nitrogen doping, and the mechanism of the formation of strong magnetism in N-doped MoS2 is revealed.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)
Article
Chemistry, Physical
Sergey Yu. Ketkov, Sheng-Yuan Tzeng, Elena A. Rychagova, Anton N. Lukoyanov, Wen-Bih Tzeng
Summary: Metallocenes, including methylcobaltocene, play important roles in various fields of chemistry. The ionization energy and vibrational structure of (Cp ')(Cp)Co can be influenced by introducing methyl substituents. The mass-analyzed threshold ionization spectrum and DFT calculations provide accurate information about the properties and transformations of (Cp ')(Cp)Co.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Review
Chemistry, Physical
Qifeng Mu, Jian Hu
Summary: Polymer mechanochemistry has experienced a renaissance due to the rapid development of mechanophores and principles governing mechanochemical transduction or material strengthening. It has not only provided fundamental guidelines for converting mechanical energy into chemical output, but also found applications in engineering and smart devices.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Da Hye Yang, Francesco Ricci, Fredrik L. Nordstrom, Na Li
Summary: Through systematic evaluation of the oiling-out behavior of procaine, we identified both stable and metastable liquid-liquid phase separation, and established phase diagrams to assist in rational selection of crystallization strategies.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Vikki Anand Varma, Simmie Jaglan, Mohd Yasir Khan, Sujin B. Babu
Summary: Designing engineering structures like nanocages, shells, and containers through self-assembly of colloids is a challenging problem. This work proposes a simple model for the subunit, which leads to the formation of monodispersed spherical cages or containers. The model with only one control parameter can be used to design cages with the desired radius.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Hainan Jiang, Yaolong He, Xiaolin Li, Zhiyao Jin, Huijie Yu, Dawei Li
Summary: The cycling lifespan and coulombic efficiency of lithium-ion batteries are crucial for high C-rate applications. The Li-ion concentration plays a crucial role in determining the mechanical integrity and structural stability of electrodes. This study focuses on graphite as the working electrode and establishes an experimental system to investigate the mechanical properties of composite graphite electrode at different C-rates. Considering the effect of Li-ion concentration in stress analysis is found to be significant.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Zhiye Wang, Yunchuan Li, Mingjun Sun
Summary: This study investigates the influence of intramolecular pi-pi interactions on the electronic transport capabilities of molecules. By designing and analyzing three pi-conjugated molecules, the researchers observe that different pi-conjugated structures have varying effects on electron transport. The findings provide a theoretical foundation for designing single-molecule electronic devices with multiple electron channels based on intramolecular pi-pi interactions.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Yuandong Xu, Haoyang Feng, Chaoyang Dong, Yuqing Yang, Meng Zhou, Yajun Wei, Hui Guo, Yaqing Wei, Jishan Su, Yingying Ben, Xia Zhang
Summary: Hollow MoS2 cubes and spheres were successfully synthesized using a one-step hydrothermal method with the hard template method. The hollow MoS2 cubes exhibited higher specific capacitance and energy density compared to the hollow MoS2 spheres. The symmetrical supercapacitors assembled with these hollow structures showed good performance and high capacity retention after multiple cycles. These findings suggest that controlling the pore structure and surface characteristics of MoS2 is crucial for enhancing its electrochemical properties.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Ainhoa Oliden-Sanchez, Rebeca Sola-Llano, Joaquin Perez-Pariente, Luis Gomez-Hortiguela, Virginia Martinez-Martinez
Summary: The combination of photoactive molecules and inorganic structures is important for the development of advanced materials in optics. In this study, bulky dyes were successfully encapsulated in a zeolitic framework, resulting in emission throughout the visible spectrum.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Miaomiao Zhang, Cunyuan Pei, Qiqi Xiang, Lintao Liu, Zhongxu Dai, Huijuan Ma, Shibing Ni
Summary: The design of a solid electrolyte interphase (SEI) plays a crucial role in improving the electrochemical performance of anode materials. In this study, lithium difluoro(oxalate)borate (LiDFOB) is used as an electrolyte additive to form a protective SEI film on Li3VO4 (LVO) anodes. The addition of LiDFOB results in a dense, uniform, stable, and LiF-richer SEI, which enhances the Li-ion storage kinetics. The generated SEI also prevents further decomposition of the electrolyte and maintains the morphology of LVO anodes during charge/discharge processes. This work demonstrates the effectiveness of LiDFOB as a multi-functional additive for LiPF6 electrolytes and provides insights into SEI construction for high-performance LVO anodes.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
B. V. Andryushechkin, T. V. Pavlova, V. M. Shevlyuga
Summary: The atomic structure of the Ag(111)-p(4 x 4)-O phase was reexamined and two phases with the same periodicity were discovered. It was demonstrated that the accepted Ag6 model is incompatible with high-resolution oxygen-sensitive STM images.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
S. L. Romo-Avila, D. Marquez-Ruiz, R. A. Guirado-Lopez
Summary: In this study, we used density functional theory (DFT) calculations to investigate the interaction between model graphene oxide (GO) nanostructures and chlorine monoxide ClO. We aimed to understand the role of this highly oxidizing species in breaking C-C bonds and forming significant holes on GO sheets. Our results showed that C-C bonds in a single graphene oxide sheet can be broken through a simple mechanism involving the dissociation of two chemically attached ClO molecules. The formation of carbonyl groups and holes on the GO surface was also observed. This study provides important insights into the degradation of carbon nanotubes and the stability of GO during the myeloperoxidase (MPO) catalytic cycle.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Alberto Garcia-Fernandez, Birgit Kammlander, Stefania Riva, Hakan Rensmo, Ute B. Cappel
Summary: In this study, the X-ray stability of five different lead halide perovskite compositions (MAPbI3, MAPbCl3, MAPbBr3, FAPbBr3, CsPbBr3) was investigated using photoelectron spectroscopy. Different degradation mechanisms and resistance to X-ray were observed depending on the crystal composition. Overall, perovskite compositions based on the MA+ cation were found to be less stable than those based on FA+ or Cs+. Metallic lead formation was most easily observed in the chloride perovskite, followed by bromide, and very little in MAPbI3. Multiple degradation processes were identified for the bromide compositions, including ion migration, formation of volatile and solid products, as well as metallic lead. CsBr was formed as a solid degradation product on the surface of CsPbBr3.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Timofei Rostilov, Vadim Ziborov, Alexander Dolgoborodov, Mikhail Kuskov
Summary: The shock-loading behavior of nanomaterials is investigated in this study. It is found that shock compaction waves exhibit a distinct two-step structure, with the formation of faster precursor waves that travel ahead of the main compaction waves. The complexity of the shock Hugoniot curve of the tested nanomaterial is described, and the effect of initial porosity on the compressed states is demonstrated.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Sergey S. Nikitin, Alexander D. Koryakov, Elizaveta A. Antipinskaya, Alexey A. Markov, Mikhail V. Patrakeev
Summary: The stability of La1/3Sr2/3Fe1-xMnxO3-delta, a perovskite-type oxide, under reducing conditions is dependent on the manganese content. Increasing the manganese content leads to a decrease in stability. The behavior of iron and manganese in the oxide shows distinct differences, which can be attributed to the difference in the enthalpy of oxidation reactions. Additionally, the change in the La/Sr ratio affects the concentration of iron and manganese ions.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)
Article
Chemistry, Physical
Mosayeb Naseri, Shirin Amirian, Mehrdad Faraji, Mohammad Abdur Rashid, Maicon Pierre Lourenco, Venkataraman Thangadurai, D. R. Salahub
Summary: Inspired by the successful transfer of freestanding ultrathin films of SrTiO3 and BiFeO3, this study assessed the structural stability and investigated the electronic, optical, and thermoelectric properties of a group of two-dimensional perovskite-type materials called perovskenes. The findings revealed that these materials are wide bandgap semiconductors with potential application in UV shielding. Moreover, they exhibit better electrical and thermal conductivity at high temperatures, enabling efficient power generation in thermoelectric devices.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2024)