4.7 Article

The effect of TiO2 on phase separation and crystallization of glass-ceramics in CaO-MgO-Al2O3-SiO2-Na2O system

期刊

JOURNAL OF NON-CRYSTALLINE SOLIDS
卷 354, 期 52-54, 页码 5395-5401

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jnoncrysol.2008.09.019

关键词

Glass-ceramics; Nucleation; Phases and equilibria

向作者/读者索取更多资源

The experiments were carried out on studying the effect of phase separation on nucleation and crystallization in the glass based on the system of CaO-MgO-Al2O3-SiO2-Na2O, In the experiments, TiO2 Was chosen as nucleating agent. Three batches of 5, 8 and 10 wt% TiO2 substitution were investigated by the techniques of DSC, XRD, FTIR and FESEM equipped with EDS. XRD and FTIR analysis indicated that the Super cooled glasses were all amorphous, the heat treatment leading to nucleation would cause a disruption of silica network which followed phase separation. The phase separation followed the generation of crystal seeds Mg(Ti, Al)(2)O-6. FESEM observation and EDS analysis revealed that the more TiO2 content of glass, the more droplet separated phase and crystal seeds after nucleation heat treatment. The main crystal phase is clinopyroxene, Ca(Ti,Mg,Al)(Al,Si)O-6, of crystallized glass. Crown Copyright (C) 2008 Published by Elsevier B.V. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Materials Science, Multidisciplinary

Corrosion and discharge performance of a magnesium aluminum eutectic alloy as anode for magnesium-air batteries

Jingling Ma, Yi Zhang, Mingsheng Ma, Conghui Qin, Fengzhang Ren, Guangxin Wang

CORROSION SCIENCE (2020)

Article Chemistry, Analytical

MXene/SnO2 heterojunction based chemical gas sensors

Tingting He, Wei Liu, Tan Lv, Mingsheng Ma, Zhifu Liu, Alexey Vasiliev, Xiaogan Li

Summary: The 2D MXene/SnO2 heterojunction-based chemiresistive sensor shows excellent sensitivity and selectivity to NH3, with the sensing properties attributed to MXene's unique adsorption ability and conductivity, and the Fermi level difference between MXene and SnO2 driving charge transfer to enhance sensitivity. Additionally, a wireless sensor utilizing low-temperature cofired ceramic technique demonstrates fast response/recovery speeds and stable response to ammonia concentrations, showing promising practical application potential.

SENSORS AND ACTUATORS B-CHEMICAL (2021)

Article Chemistry, Physical

Machine learning approaches for permittivity prediction and rational design of microwave dielectric ceramics

Jincheng Qin, Zhifu Liu, Mingsheng Ma, Yongxiang Li

Summary: In this study, a high accuracy model for permittivity prediction of microwave dielectric ceramics was established using machine learning methods based on a dataset of 254 materials. The results provide insights into the quantitative chemistry/structure-property relationships in these materials.

JOURNAL OF MATERIOMICS (2021)

Article Nanoscience & Nanotechnology

Structure and Microwave Dielectric Properties of Gillespite-Type ACuSi4O10 (A = Ca, Sr, Ba) Ceramics and Quantitative Prediction of the Q x f Value via Machine Learning

Jincheng Qin, Zhifu Liu, Mingsheng Ma, Feng Liu, Ze-Ming Qi, Yongxiang Li

Summary: The structure and dielectric properties of gillespite-type ceramics were investigated, revealing that substitutions at the A-site have significant impacts on the crystal structure and dielectric values. The local structure changes suppress intermediate and low-frequency vibrational modes, while enhancing the contribution from electronic polarization to permittivity. Machine learning methods were introduced to explore decisive structural factors for the dielectric values, leading to the establishment of a prediction model for Q x f values.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Chemistry, Multidisciplinary

Wireless Microfluidic Sensor for Metal Ion Detection in Water

Yu Liang, Mingsheng Ma, Faqiang Zhang, Feng Liu, Tan Lu, Zhifu Liu, Yongxiang Li

Summary: The wireless microfluidic sensor based on LTCC technology allows real-time detection of metal ions in water, distinguishing between different ion species through reflection coefficient and resonance frequency. The detection limit can be as low as 5um, with a normalized sensitivity higher than reported sensors.

ACS OMEGA (2021)

Article Materials Science, Ceramics

Crystal structure, lattice vibration and microwave dielectric properties of 3CaO•2SiO2•xCaF2 (0 ≤ x ≤ 1.5) ceramics

Jincheng Qin, Zhifu Liu, Mingsheng Ma, Yongxiang Li

Summary: This study investigated the crystal structure, lattice vibration, and microwave dielectric properties of 3CaO·2SiO(2)·xCaF(2) ceramics. The crystal structure of the ceramics changed from rankinite to cuspidine with increasing x value. The increase in vibration energy and shrinkage of the SiO4 tetrahedral unit resulted in a decrease in relative permittivity. The stable complex permittivity in the microwave frequency range suggests that these ceramics could be promising for microwave device applications.

CERAMICS INTERNATIONAL (2022)

Article Materials Science, Multidisciplinary

Low-temperature sintering of ZnAl2O4 ceramics with 4CuO-TiO2-2Nb2O5 composite oxide sintering aid

Yan Yang, Mingsheng Ma, Yongzhe Wang, Zhifu Liu, Faqiang Zhang, Yongxiang Li

Summary: The addition of CTN composite oxide can promote the low temperature sintering of ZnAl2O4 ceramics, increasing thermal conductivity and reducing microwave dielectric loss. However, with the increase of CTN content, the thermal conductivity of ZnAl2O4 ceramics decreases, while dielectric constant and loss increase.

FERROELECTRICS (2021)

Article Chemistry, Multidisciplinary

Machine Learning-Assisted Materials Design and Discovery of Low-Melting-Point Inorganic Oxides for Low-Temperature Cofired Ceramic Applications

Jincheng Qin, Zhifu Liu, Mingsheng Ma, Yongxiang Li

Summary: In this study, a machine learning approach was used to develop a melting point prediction model for inorganic oxides, aiming to efficiently screen for low-melting-point and high-performance LTCC materials. Through a two-stage modeling process, three key features, including formation energy, theoretical density, and number of atoms, were identified and their relationships with melting point were analyzed.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2022)

Article Engineering, Electrical & Electronic

Effects of organic binder on rheological behaviors and screen-printing performance of silver pastes for LTCC applications

Jingjing Feng, Yujun Gao, Faqiang Zhang, Mingsheng Ma, Yan Gu, Zhifu Liu, Kun Chen

Summary: This study explores the application of ethyl celluloses (ECs) organic binder in silver pastes for LTCC applications. The research reveals that higher molecular weight and content of ECs enhance the strength of the network structures inside the organic vehicles and pastes, resulting in increased viscosity and pseudoplasticity, which are beneficial for screen printing fine patterns. However, higher viscosity and shorter structure recovery time may hinder the printing of large area electrodes and lead to increased surface roughness.

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS (2022)

Article Physics, Applied

Enhanced linearity of CaCu3Ti4O12 by changing energy band structure induced by Fe3+ doping for high temperature thermistor application

Ruifeng Wu, Mingsheng Ma, Su Zhang, Pengjun Zhao, Kai Li, Qing Zhao, Aimin Chang, Bo Zhang

Summary: It was found that Fe3+ ions can change the grain energy band structure of CCTO materials, enhancing the linearization of the resistance-temperature curve. Fe3+ doping narrows the forbidden band and induces new impurity energy levels in the forbidden band, while also modulating the activation energy of CCTO materials by changing the activation energy of GBs.

APPLIED PHYSICS LETTERS (2022)

Article Materials Science, Ceramics

Optimizing the stability and electrical transport properties of CeNbO4+δ-based oxide ceramics by regulating oxygen ion content

Yafei Liu, Mingsheng Ma, Pengjun Zhao, Qing Zhao, Zhilong Fu, Donglin He, Aimin Chang, Bo Zhang

Summary: CeNbO4+Δ ceramics have unique mixed ion-electron transport characteristics and interesting structure-functional characteristics due to the difference in oxygen ion content, attracting extensive research interest. The directional regulation of oxygen ion content has been achieved by introducing Al2O3 and high temperature aging, resulting in stable structure and excellent electrical transport properties.

CERAMICS INTERNATIONAL (2022)

Article Materials Science, Ceramics

Excellent yellow emission of Si3N4:Eu nanorods derived from waster silicon with better thermal stability for white LEDs

Wanyin Ge, Honglei Yin, Chenhui Lu, Xinmeng Zhang, Panpan Song, Mingsheng Ma, Zhifu Liu, Ye Tian

Summary: In this study, Si3N4:Eu nanorods were synthesized from waste utilization and demonstrated excellent luminescent properties and thermal stability for LED applications. The synthesized Si3N4:Eu nanorods showed comparable performance to commercial YAG:Ce3+ and exhibited superior long-term thermal stability. This work not only provides a facile synthesis route for Si3N4:Eu nanorods from waste materials, but also offers enhanced service performance for high temperature LED applications.

CERAMICS INTERNATIONAL (2023)

Article Engineering, Electrical & Electronic

Integrated wireless microfluidic liquid sensors based on low temperature co-fired ceramic (LTCC) technology

Tingting He, Mingsheng Ma, Haogeng Li, Faqiang Zhang, Feng Liu, Zhifu Liu, Xiaogan Li

Summary: This work introduces a wireless microfluidic sensor based on microwave reflection principle for liquid detection. The sensor consists of a slot antenna and a substrate integrated waveguide (SIW) resonator integrated with a microchannel using low temperature co-fired ceramic (LTCC) technology. The structure of the sensor was optimized through electromagnetic simulation. Experimental results demonstrate the liquid sensing performance of the sensor using ethanol aqueous solution and glucose aqueous solution.

SENSORS AND ACTUATORS A-PHYSICAL (2022)

Article Engineering, Environmental

Reduced plastic film mulching under zero tillage boosts water use efficiency and soil health in semiarid rainfed maize field

Ai-Tian Ren, Ji-Yuan Li, Ling Zhao, Rui Zhou, Jian-Sheng Ye, Yi-Bo Wang, Xu-Cheng Zhang, Kiprotich Wesly, Ming-Sheng Ma, You-Cai Xiong

Summary: Reducing the use of plastic film while maintaining high water use efficiency and soil health is a significant global challenge. A two-year field investigation showed that under no-tillage conditions, both full and half plastic film mulching improved rainfall infiltration, grain yield, and water use efficiency compared to tillage conditions. Among the no-tillage treatments, half plastic film mulching resulted in significantly higher soil organic carbon and enhanced nutrient uptake due to increased root biomass and arbuscular mycorrhizal fungi. Therefore, it is feasible and efficient to reduce plastic mulching but improve water use efficiency and soil health in semi-arid environments.

RESOURCES CONSERVATION AND RECYCLING (2023)

Review Materials Science, Ceramics

Current Status and Development Trend of Cold Sintering Process

Feng Jingjing, Zhang Youran, Ma Mingsheng, Lu Yiqing, Liu Zhifu

Summary: The conventional sintering process for ceramic materials requires high temperatures over 1000℃, which is energy-consuming and poses challenges in phase stability, grain boundary control, and co-firing. The cold sintering process (CSP) is an extremely low-temperature sintering technique introduced in recent years, which utilizes transient solvent in liquid phase and uniaxial pressure to achieve rapid densification of ceramics at temperatures below 400℃. CSP has attracted extensive attention due to its advantages such as low temperature and short sintering time. It has been successfully applied to sinter nearly 100 kinds of ceramics and ceramic-matrix composites, including dielectric materials, semiconductor materials, pressure-sensitive materials, and solid-state electrolyte materials.

JOURNAL OF INORGANIC MATERIALS (2023)

Article Materials Science, Ceramics

Comparison of the effect of free volume fraction on the dielectric properties of polyethylene oxide bulk and thin film

Deniz Bozoglu, Sahin Yakut, Kemal Ulutas, Deniz Deger

Summary: Thin film polyethylene oxide, produced by the thermal evaporation technique, exhibits structural and property differences compared to bulk polyethylene oxide. The dielectric constant of polyethylene oxide thin film is 10 times greater than that of bulk polyethylene oxide. There is consistency among dielectric constants, activation energies, and free volume fractions for both thin film and bulk samples. Polyethylene oxide thin film is observed to be more brittle than bulk polyethylene oxide.

JOURNAL OF NON-CRYSTALLINE SOLIDS (2024)

Article Materials Science, Ceramics

Orientation dependence of the nanocrystallization and magnetic behavior during annealing of the FINEMET alloy

Xiaozhen Fan, Zhuo Wang, Zheng Fang, Huiqun Ye, Jinju Zheng, Jianqiang Zhang, Yanjun Qin, Yao Zhai, Yanlong Miao, Zixiang Zhao, Can Yang, Jiajun He, Zhenghang Wei, Yunzhang Fang

Summary: The microscopic strain evolution and microstructural of FeCuNbSiB amorphous alloy samples were studied under both free and tensile stress annealing conditions. It was found that an amorphous-nanocrystalline structure was developed in both samples after annealing at 813 K, and the size of nanocrystals was limited by the applied stress.

JOURNAL OF NON-CRYSTALLINE SOLIDS (2024)

Article Materials Science, Ceramics

Large-scale DFT calculations of multi-component glass systems (SiO2)0.70(Al2O3)0.13(XO)0.17 (X = Mg, Ca, Sr, Ba) : Accuracy of classical force fields

Atsushi Tanaka, Atsuki Saito, Takashi Murata, Ayako Nakata, Tsuyoshi Miyazaki

Summary: Although molecular dynamics (MD) simulation is a powerful tool for investigating the atomic-scale structures of complex materials, its reliable and accurate application to multi-component glass systems faces challenges due to limited force fields (FFs) and the complexity of chemical environments. This study demonstrates the feasibility of efficient and accurate large-scale density functional theory (DFT) calculations for multi-component glass systems. The evaluation of classical FFs based on the results of large-scale DFT calculations reveals low accuracy for non-bridging oxygen atoms, and differences in Si-O-Si angle distribution and electronic structure for X = Mg.

JOURNAL OF NON-CRYSTALLINE SOLIDS (2024)

Article Materials Science, Ceramics

In situ XRD and Raman study of the phase transition in V2O5 xerogels

Petr Shvets, Ksenia Maksimova, Aleksandr Goikhman

Summary: In this study, vanadium oxide xerogel samples were successfully synthesized through a liquid phase reaction and the interaction of films with water. The samples were thoroughly analyzed using X-ray diffraction and Raman spectroscopy, revealing the existence of two distinct phases. It was also discovered that previous misinterpretations regarding the high-pressure polymorph structure were due to the formation of a high-temperature phase. These findings highlight the potential for further refining and expanding the current structural models of vanadium oxide xerogel in future research efforts.

JOURNAL OF NON-CRYSTALLINE SOLIDS (2024)

Article Materials Science, Ceramics

The effect of the volume fraction of nanocrystals on the brittleness of Fe-based amorphous/nanocrystalline alloys simulated by molecular dynamics

Yiran Zhang, Jing Pang, Qingchun Xiang, Dong Yang, Yinglei Ren, Xiaoyu Li, Keqiang Qiu

Summary: The effect of the volume fraction of body-centered cubic (BCC) crystal on the room temperature brittleness of Fe-based amorphous nanocrystalline alloys was investigated. Molecular dynamics simulations were conducted to obtain seven model samples with different embedded BCC nanocrystal contents. The results showed a gradient decrease in the plasticity of the alloys with different nanocrystal contents.

JOURNAL OF NON-CRYSTALLINE SOLIDS (2024)

Article Materials Science, Ceramics

A micromechanical nested machine learning model for characterizing materials behaviors of bulk metallic glasses

Moustafa Sahnoune Chaouche, Hani K. Al-Mohair, Shavan Askar, Barno Sayfutdinovna Abdullaeva, Naseer Ali Hussien, Ahmed Hussien Alawadi

Summary: In this work, a novel micromechanical data-driven machine learning framework was proposed to characterize material parameters in bulk metallic glasses. The framework utilized nanoindentation simulations with Berkovich and spherical tips to compile a vast collection of data on material behavior in BMGs. The developed machine learning model efficiently predicted critical material properties and highlighted the importance of input feature weight functions.

JOURNAL OF NON-CRYSTALLINE SOLIDS (2024)

Article Materials Science, Ceramics

Crystallization in Ga-Sb-Se glasses and influence of the Se content

Louisiane Verger, Vinuyan Ganesaratnam, Virginie Nazabal, Sebastien Chenu, Christophe Calers, David Le Coq, Laurent Calvez, Olivier Hernandez, Xiang-Hua Zhang

Summary: Crystallization in Ga, Sb, and Se glasses was studied, and a correlation between Se content, crystalline phases, and electrical conductivity was observed. The resulting glass-ceramics exhibited significantly higher conductivity compared to other Se-based glass-ceramics.

JOURNAL OF NON-CRYSTALLINE SOLIDS (2024)

Article Materials Science, Ceramics

Silver tungstate-tellurite glass for radioactive iodine immobilization

Seong-Sik Shin, Ga-Yeong Kim, Byeonggwan Lee, Jae-Hwan Yang, Yeon-Su Son, Jung-Hoon Choi, Jae-Young Pyo, Ki Rak Lee, Hwan-Seo Park, Hyun Woo Kang

Summary: In this study, silver tungstate-tellurite glass with different loading of AgI was developed for immobilization of radioactive iodine. The effects of increasing the amount of AgI on the glass matrix were investigated. The leaching properties of all samples were evaluated, and it was found that the release of all elements satisfied the US regulation.

JOURNAL OF NON-CRYSTALLINE SOLIDS (2024)

Article Materials Science, Ceramics

Magnetocaloric properties predicted by deep learning with compositional features for bulk metallic glasses

Chunghee Nam

Summary: This study demonstrates the prediction performance of a CNN regression model for the magnetic entropy changes and transition temperatures of bulk metallic glasses with magnetocaloric effects. The model achieved high prediction performance, as measured by the determination coefficient and root mean square error. The results showed good agreement with experimental values and reported results.

JOURNAL OF NON-CRYSTALLINE SOLIDS (2024)

Article Materials Science, Ceramics

Structural study and physical properties of tellurite glasses containing lead bromide

A. Hosny, Y. M. Moustafa, G. El-Damrawi

Summary: In this study, crystalline glass ceramics were obtained directly from glasses using an ion exchange process between lead bromide and oxygen ions. The addition of lead bromide caused significant changes in the glass structure and the formation of specific crystalline phases.

JOURNAL OF NON-CRYSTALLINE SOLIDS (2024)

Article Materials Science, Ceramics

Study of the influence of calcium fluoride on the bioactivity of boron-based glass

Luana Cristina Feitosa Alves, Jheimison Ferreira Gomes, Natacya Fontes Dantas, Maria Nayane Queiroz, Pablo Nabuco Portes, Francielle Sato, Nilma de Souza Fernandes, Karina Miyuki, Celso Vataru Nakamura, Alysson Steimacher, Franciana Pedrochi

Summary: This study evaluated the influence of CaF2 addition on the bioactivity of the samples. The results showed that the samples exhibited good bioactivity and cytocompatibility, making them suitable for biomedical applications.

JOURNAL OF NON-CRYSTALLINE SOLIDS (2024)

Article Materials Science, Ceramics

Application of topological constraint theory to alkali borate and silicate glass systems

N. Keninger, S. Feller

Summary: The principles of Topological Constraint Theory (TCT) were used to study alkali borate and silicate glass systems. Structural models were developed based on experimental data and used to predict properties of the glass.

JOURNAL OF NON-CRYSTALLINE SOLIDS (2024)

Article Materials Science, Ceramics

Stress-annealing induced quasistatic creep recovery in ZrCuAlNi metallic glass

Hao Wang, Chengliang Zhao, Chuntao Chang, Shengli Zhu, Zhankui Zhao

Summary: The relationship between the heterogeneous structure and structural relaxation in metallic glasses was explored by investigating the quasielastic and viscoelastic behavior of a Zr55Cu30Ni5Al10 metallic glass. Stress-annealing treatment was used to retain elastic strain energy, and a unique creep recovery phenomenon was observed during the reheating process. The Maxwell model was employed to qualitatively describe the mechanisms of elastic strain energy retention and release.

JOURNAL OF NON-CRYSTALLINE SOLIDS (2024)

Article Materials Science, Ceramics

Mechanical property evaluation of thin film metallic glasses via molecular dynamics and finite element analyses

Sihyung Lee, Giyeol Han, Karuppasamy Pandian Marimuthu, Hyungyil Lee

Summary: This study presents a method for extracting FVM parameters of Zr-based TFMG using MD and FEA, and validates the method through simulation and experiments.

JOURNAL OF NON-CRYSTALLINE SOLIDS (2024)

Article Materials Science, Ceramics

Effect of excitation and doping concentration on the emission color of a fluorophosphate glass doped with Tb3+and Eu3+

Nedra Saad, Mohamed Haouari, Mayssa Ibrahim, Noura Amamou

Summary: In this work, we investigated the optical properties of a fluorophosphate glass system doped with Tb3+ and Eu3+ ions. We found that the emitted light can be tuned by changing the doping concentration, excitation wavelength, or excitation power, which is important for the design of solid-state lighting sources.

JOURNAL OF NON-CRYSTALLINE SOLIDS (2024)