Raman light scattering on ultra-thin films of LaNiO3 under compressive strain

In order to investigate the lattice dynamics of very thin films, we have carried out a series of depth-resolved Raman scattering measurements. Combining the narrow depth-of-field of confocal Raman spectroscopy with vertical scans of the sample, we have obtained high quality phonon spectra of fully strained LaNiO3 films with thickness as low as 4 pseudocubic unit cells. With increasing film thickness a large softening of a LaNiO3 E-g-bending mode is observed, indicating the relaxation of biaxial compressive strain imposed by the LaAlO3 substrate. (C) 2014 Elsevier B.V. All rights reserved,