期刊
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
卷 11, 期 11, 页码 9543-9549出版社
AMER SCIENTIFIC PUBLISHERS
DOI: 10.1166/jnn.2011.5229
关键词
Near Infrared; Downconversion; Cooperative Energy Transfer; CaMoO4:Yb3+
类别
资金
- National Natural Science Foundation of China [10774140, 10904139]
- Chinese Academy of Sciences [KJCX2-YW-M11]
- Specialized Research for Talents of Anhui Province, China [2007Z021]
An efficient near-infrared (NIR) dowmconversion (DC) has been demonstrated in the CaMoO4:Yb3+ phosphors. Very strong NIR emission around 998 nm from the F-2(5/2) -> F-2(5/2) transition of the Yb3+ has been observed under ultraviolet excitation. A similar broad excitation band due to the absorption of the host CaMoO4 has been recorded when the NIR emission of Yb3+ and the visible molybdate (MoO42-) emission are monitored, which suggests an efficient energy transfer (ET) from the host to the Yb3+. The Yb3+ concentration-dependent luminescence properties and lifetimes of both the visible and NIR emissions have also been studied. The lifetime of the molybdate emission decreases rapidly with the increasing Yb3+ concentration, further verifying the efficient ET from the host to the Yb3+. Moreover, the low temperature measurements have also been carried out to investigate the ET mechanism in the phosphors. A cooperative energy transfer (CET) mechanism has been proposed to rationalize the DC effect. The newly studied CaMoO4:Yb3+ DC phosphors, which can convert the broadband emission of the MoO42- into NIR emission of Yb3+ with a twofold increase in the photon number will have potential application in greatly enhancing the response of silicon-based solar cells with a relatively higher Yb3+ quenching concentration.
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