期刊
JOURNAL OF MOLECULAR STRUCTURE
卷 1051, 期 -, 页码 23-29出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molstruc.2013.07.042
关键词
Carbazole derivatives; One and two-photon optical properties; Quinoline ring
资金
- National Natural Science Foundation of China [61137002]
- Research Fund of Heilongjiang Provincial Education Department [12511377]
The carbazole derivatives are suitable for two-photon absorption optical storage and photoluminescence material. Two carbazole derivatives, asymmetrical and symmetrical type molecules containing quinoline rings as electron acceptors and an N-ethylcarbazole group as electron donor, 9-ethyl-3-(2-quinolin)viny-carbazole (4) and 9-ethyl-3,6-bis(2-(quinolin)vinyl)-carbazole (5), had been synthesized by the Vilsmeier reaction of formylation and Knoevenagel condensation. The one-photon properties including absorption, fluorescence emission spectra, fluorescence quantum yields and fluorescence decay behaviors were investigated in N,N-dimethylformamide. Meanwhile, these compounds were theoretically surveyed by the density functional theory (DFT) and the time-dependent functional theory (TD-DFT). The two-photon excited fluorescence and two-photon absorption cross-sections were measured for the compounds by 120 fs pulse at 800 nm Ti: sapphire laser operating at 1 kHz repetition rate. The results showed that both of the two compounds 4 and 5 had higher fluorescence quantum yield (Phi) of 0.77 and 0.81 comparing with carbazole. Compounds 5 with symmetric pi conjugated structure possessed longer fluorescence lifetime (tau) of 21.4 ns and larger two-photon absorption cross-sections (delta(TPA)) of 364 x 10(-50) cm(4) s/photon than those of compounds 4 with asymmetric pi conjugated structure (tau = 10.03 ns and delta(TPA) = 81 x 10(-50) - cm(4) s/photon). It was indicated that the one and two-photon optical properties of carbazole derivatives are influenced strongly by the symmetry and length of pi conjugated structure. (C) 2013 Elsevier B.V. All rights reserved.
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