Article
Chemistry, Multidisciplinary
Sara Gracia-Barberan, Alejandro Leal-Duaso, Elisabet Pires
Summary: This microreview explores the potential of Deep Eutectic Solvents (DES) as alternatives to Ionic Liquids (ILs) in metal-catalysed reactions. The results show that DES have shown promising results in various reactions, but further research is needed to explore their applicability in other reactions and understand the influence of the nature of the DES. The study also introduces bio-based ionic liquids as a complementary solvent to DES for fully replacing traditional ILs.
CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY
(2022)
Article
Polymer Science
Anna Sowinska, Magdalena Maciejewska, Laina Guo, Etienne Delebecq
Summary: Task-specific ionic liquids (TSILs) are designed for specific applications to improve the efficiency of vulcanization of rubber compounds while maintaining safe processing, characterized by satisfactory functional properties in EPDM vulcanizates.
Article
Engineering, Chemical
Chi-Linh Do-Thanh, Huimin Luo, James A. Gaugler, Sheng Dai
Summary: A 1,2-hydroxypyridinone (HOPO) grafted ionic liquid (HOPO-IL) was synthesized and investigated for its extraction performance in various ionic liquids (ILs) and organic solvents. The results showed that the extraction performance of this HOPO-IL extractant was enhanced by approximately 2 folds in IL solvents compared to organic solvents. The study also revealed a strong pH dependence and a dominant cation-exchange mechanism of lanthanide extraction.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Review
Chemistry, Multidisciplinary
Tao Zhang, Thomas Doert, Hui Wang, Suojiang Zhang, Michael Ruck
Summary: This review explores the application of ionic liquids and deep eutectic solvents in the synthesis of inorganic materials, covering various types of deep eutectic solvents and ionic liquids, as well as their chemical reactions. It also highlights the caution that needs to be taken regarding their chemical reactivity, and provides guidelines for their proper use.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Biochemistry & Molecular Biology
Wei-dong Zhang, Yan Li, Ke Wang, Ye Yue, Mei Tie, Xue-jun Gu, You-lin Xue
Summary: This study used ionic liquids to extract cellulose-protein complexes (CPCs) from Se-enriched peanut leaf residue and compared the effects of different ionic liquids and organic solvents on the properties of CPCs.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2022)
Review
Chemistry, Inorganic & Nuclear
Anandhu Mohan, Augustine Jaison, Young-Chul Lee
Summary: The regulation of a large amount of CO2 in the environment is crucial to prevent environmental catastrophes, and this can be achieved through efficient carbon capture and conversion into useful chemicals. Mesoporous silica nanoparticles (MSNs) are ideal support materials for heterogeneous catalysis due to their unique characteristics. This review discusses the functionalization of MSNs, the synthesis of MSN-based catalysts, and their potential applications in CO2 fixation reactions. It highlights the design of an ideal CO2 fixation catalyst, the addition of various functionalities to MSNs, and the effects of controlling particle size distribution, active species dispersion, and interactions between active species and supports. Furthermore, this review provides an overview of the key issues, current developments, and barriers in the field of MSN-based catalysts for CO2 fixation, along with proposed research goals and viable solutions for their implementation.
INORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Chemistry, Multidisciplinary
Andrew P. Abbott
Summary: This article introduces the characteristics, applications, and recent research progress of deep eutectic solvents, including electrodeposition, metal recycling, and the effects of mixing with water.
CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY
(2022)
Review
Agricultural Engineering
Yaoyao Zhang, Shangde Sun
Summary: The scarcity of fossil fuel and increasing environmental concerns have led to a growing need for the development of environmentally friendly and sustainable energy resources. Biodiesel, produced through transesterification of oils or fats with short-chain alcohol, is considered an optimal replacement for fossil-fuel based diesel due to its reproducible and eco-friendly properties. Among various catalysts, ionic liquids have shown potential as viable substitutes for conventional catalysts in biodiesel production. This paper provides a comprehensive review of the classification, synthetic schemes, and catalytic mechanism of basic ionic liquids, which have been less explored compared to acidic ionic liquids. The utilization of basic ionic liquids as catalysts for biodiesel preparation, along with the current challenges and prospects for future use, is also discussed.
INDUSTRIAL CROPS AND PRODUCTS
(2023)
Article
Chemistry, Multidisciplinary
Fabrizio Vetica, Martina Bortolami, Rita Petrucci, Daniele Rocco, Marta Feroci
Summary: N-heterocyclic carbenes (NHCs) have been extensively studied for their application as organocatalysts and ligands for transition metals in organic synthesis. The generation of NHCs through deprotonation or reduction methods, including chemical or electrochemical processes, shows different reactivity in ionic liquids compared to classic organic solvents.
Article
Chemistry, Physical
Geeta Durga, Pooja Kalra, Vinay Kumar Verma, Kanjur Wangdi, Anuradha Mishra
Summary: Ionic liquids have established themselves as a preferred solvent in synthetic chemistry, particularly in polymer chemistry. They are versatile solvents used for polymeric reactions and can also be polymerized to enhance their inherent properties, finding applications in various fields such as electrochemical devices, nanocomposites, optoelectronics, and more. This comprehensive review covers both aspects of ILs as a solvent in polymeric reactions and their polymeric form, poly(ionic liquids), presenting their diverse potential applications.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Multidisciplinary
Zonghua Wang, Congyi Wu, Ze Wang, Shaoze Zhang, Dezhong Yang
Summary: In this study, DESs were used for CO2 capture, and the results showed that the strength of hydrogen bonds plays a significant role in the absorption and desorption of CO2.
CHEMICAL COMMUNICATIONS
(2022)
Article
Energy & Fuels
Jian Chen, Hongyan Wang, Lili Deng, Hui Wang, Zengxi Li
Summary: By studying different ionic liquid catalysts, it was found that [TENBs][CF3SO3] exhibited the best performance, and composite ILs could significantly improve catalytic activity and selectivity. The catalytic behaviors of these ILs were characterized by spectroscopic analysis and Gaussian simulation, demonstrating the importance of bond dissociation enthalpy and binding energy for efficient isobutene oligomerization.
Article
Chemistry, Physical
Jean-Pierre Mbakidi, Florica Lazar, Luc Marchal, Eric Leroy, Sandrine Bouquillon
Summary: Paramylon is a water insoluble linear glucan produced by Euglena gracilis microalgae. It has a stable triple helix conformation and high crystallinity due to its macromolecular structure containing only b(1-3) linkages. The solubility of paramylon was evaluated using eco-friendly ionic liquids as solvents, and the structure and thermal properties of the biopolymer before and after solubilization and regeneration were discussed. (C) 2022 Elsevier B.V. All rights reserved.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Chemistry, Physical
Xiao-Qiang Li, Guo-Yi Duan, Rui Wang, Li-Jun Han, Yao-Feng Wang, Bao-Hua Xu
Summary: Poly(ionic liquid)-metal (PIL-metal) hybrids were developed for constructing tandem catalysts to achieve efficient electrocatalytic reduction of CO2. The introduction of metal with distinct CO2RR response can optimize the reaction performance, and the presence of PIL layer can adjust the reactivity.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
Article
Chemistry, Physical
Shurui Miao, Silvia Imberti, Rob Atkin, Gregory Warr
Summary: The nanostructure of choline amino acid ionic liquids (ILs) can be engineered by mixing with primary alcohols, and the abundance of hydrogen-bond donors is a critical determinant of the overall liquid structure. This finding provides a new strategy for designing application-specific and biofriendly hybrid solvent systems.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Nanoscience & Nanotechnology
Ze-Xiao Lei, Feng-Yi Yang, Cong Yuan, Lang Tai, Chang-Yu Yao, Dong Fang
Summary: The study successfully synthesized In2O3-SnS2 (IOS) core-shell heterojunction photocatalyst for efficient reduction of hexavalent chromium (Cr(VI)) under visible light, showing superior removal performance compared to pure In2O3 and SnS2. The IOS samples also demonstrated excellent stability with 90% removal efficiency maintained after five cycles.
Review
Chemistry, Applied
Baole Guan, Si-Yu Qi, Ying Li, Ting Sun, Yan-Guo Liu, Ting-Feng Yi
Summary: Sodium-ion batteries are gaining importance due to the low cost and abundance of sodium, with cobalt-based sulfides being extensively studied as anode materials. However, their application is hindered by capacity degradation and cycling instability, requiring a comprehensive understanding and modification from various perspectives. Recent advancements on different cobalt-based sulfides, along with strategies to improve their sodium storage performance, are outlined in this review.
JOURNAL OF ENERGY CHEMISTRY
(2021)
Article
Materials Science, Ceramics
Liying Qiu, Xue-Qi Lai, Fanfan Wang, Jingjing Pan, Yan-Rong Zhu, Ping Cui, Ting-Feng Yi
Summary: A reasonable strategy was employed to construct Li2ZnTi3O8@Na2WO4 composite, enhancing the Li storage performances of Li2ZnTi3O8. The introduction of Na2WO4 effectively improved the electrochemical performance, with 10 wt% Na2WO4 composite showing the highest reversible capacities and improved cycling stabilities. The Na2WO4 shell with excellent electronic conductivity played a significant role in reducing electrode polarization, decreasing charge transfer resistance, and enhancing Li-ion diffusion coefficient of Li2ZnTi3O8.
CERAMICS INTERNATIONAL
(2021)
Article
Materials Science, Multidisciplinary
Dan Wang, Kang-Hui Tian, Jie Wang, Zhi-Yuan Wang, Shao-Hua Luo, Yan-Guo Liu, Qing Wang, Ya-Hui Zhang, Ai-Min Hao, Ting-Feng Yi
Summary: In this study, sulfur-doped porous carbons were prepared and showed improved performance for potassium-ion batteries, with higher specific capacity, better rate capability, and enhanced cycling stability. The excellent electrochemical performance is attributed to the abundant porous structure and sulfur doping, which provide sufficient reaction sites and fast ion/electron transport paths. Additionally, density functional theory calculations confirm that sulfur doping can enhance potassium-ion adsorption and storage, and kinetic analyses suggest that surface-induced capacitive mechanism dominates the potassium-ion storage process in sulfur-doped porous carbons, enabling ultrafast charge storage.
Article
Chemistry, Physical
Ting-Feng Yi, Hui Chang, Ting-Ting Wei, Si-Yu Qi, Yanmei Li, Yan-Rong Zhu
Summary: In this study, CNTs-wrapped ZnCo2S4 composites were prepared via hydrothermal process, showing excellent electrochemical properties and outstanding cycling stability at high current density.
JOURNAL OF MATERIOMICS
(2021)
Article
Nanoscience & Nanotechnology
Hui Chang, Ying Li, Zi-Kui Fang, Jin-Peng Qu, Yan-Rong Zhu, Ting-Feng Yi
Summary: The study successfully prepared carbon-coated LiMn0.5Fe0.5PO4@Li0.33La0.56TiO3 nanorod composites, with LLTO coating facilitating charge transfer to improve rate performance and cycle stability.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Multidisciplinary
Ying Li, Hong-Yan Liu, Ling-Na Shi, Yan-Rong Zhu, Ting-Feng Yi
Summary: CeO2-decorated SrLi2Ti6O14 anode prepared via solid-state process shows excellent electrochemical performance with high reversible capacities, good cycle performance, and outstanding rate performance. Among them, CeO2 (5 wt%)-decorated SrLi2Ti6O14 exhibits the best performance and is a promising candidate for Li-ion battery electrode material.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2021)
Review
Materials Science, Multidisciplinary
Pan-Pan Peng, Yu-Rong Wu, Xue-Zhong Li, Jun-Hong Zhang, Yan-Wei Li, Ping Cui, Ting-Feng Yi
Summary: TiO2-based materials have many advantages but also face some bottlenecks, and significant progress has been made with various efficient ways to improve their performance. Constructing novel porous heterogeneous core-shell structures is considered as an effective approach to overcome these challenges.
Review
Chemistry, Physical
Ting-Feng Yi, Hirbod Maleki Kheimeh Sari, Xuezhong Li, Fanfan Wang, Yan-Rong Zhu, Junhua Hu, Jiujun Zhang, Xifei Li
Summary: Niobium oxides and their composites have attracted great attention for applications in batteries and supercapacitors due to their unique properties, but they face challenges such as poor conductivity and limited active sites. Strategies such as morphology control and surface engineering are being used to improve their electrochemical performance.
Article
Chemistry, Multidisciplinary
Y. -R. Zhu, X. -Z. Li, X. -Q. Lai, Y. Xie, Y. -M. Li, T. -F. Yi
Summary: NiCo2S4 microspheres consisting of nanoparticles were synthesized and reshaped into NiCo2S4@CeO2 microspheres with nanosheet or nanoneedle-like structures. The introduction of CeO2 changed the morphology of NiCo2S4, forming porous structures with enhanced specific surface areas. NiCo2S4@CeO2 microspheres showed outstanding electrochemical performances for pseudocapacitors, promising high-performance electrode materials.
MATERIALS TODAY CHEMISTRY
(2021)
Review
Engineering, Environmental
Hui Chang, Xuezhong Li, Lingna Shi, Yan-Rong Zhu, Ting-Feng Yi
Summary: Photocatalytic and electrocatalytic water splitting are important in solving energy and environmental issues, and MXenes are considered promising nanomaterials in this application space. Despite their excellent properties, challenges such as poor environmental stability and limited catalytic activities need to be addressed. Recent reviews summarize advances in MXenes synthesis, technical challenges, and performance improvement, offering insights into future research directions for their extensive application in electrocatalysts and photocatalysts.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Materials Science, Ceramics
Ying Li, Ting-Feng Yi, Xuezhong Li, Xueqi Lai, Jingjing Pan, Ping Cui, Yan-Rong Zhu, Ying Xie
Summary: Li2ZnTi3O8/alpha-Fe2O3 composites, prepared via hydrothermal process, exhibit excellent electrochemical properties with high reversible charge capacity and stability, showing potential as anode materials for next-generation rechargeable Li-ion batteries. The formation of strong covalent bonds between Li2ZnTi3O8 and alpha-Fe2O3 contributes to the improved performance of the composites.
CERAMICS INTERNATIONAL
(2021)
Review
Chemistry, Applied
Ting-Ting Wei, Panpan Peng, Si-Yu Qi, Yan-Rong Zhu, Ting-Feng Yi
Summary: Aluminum-ion batteries show promise as an energy storage system, but face challenges such as oxide film formation and hydrogen side reactions; Nonaqueous AIBs are considered as a hopeful alternative for high-powered energy storage devices, yet various technical obstacles need to be addressed.
JOURNAL OF ENERGY CHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
Ying Li, Fanfan Wang, Xue-Zhong Li, Xuan Gui, Yan-Rong Zhu, Ping Cui, Ting-Feng Yi
Summary: Na2Li2Ti6O14 particles were prepared by a simple solid-state process, and then g-C3N4-coated Na2Li2Ti6O14 composites were constructed by a facile solution route for the first time. The multicomponent composites showed improved cycling stability and reversible capacity, attributed to the unique architecture as negative materials for Li-ion batteries.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Multidisciplinary
T-F Yi, J-P Qu, X. Lai, X. Han, H. Chang, Y-R Zhu
Summary: CoNiO2@C composites with porous microsphere structure consisting of nanoparticles were designed for the first time, showing improved electronic conductivity, charge transfer, reversible capacity, rate capability, and cycle performance, especially at high rates. The elaborate design of architecture and composition contributed to the enhanced rate performance, excellent cycle performance, and high kinetic performances of the material, making it a promising candidate for anode materials in lithium-ion batteries.
MATERIALS TODAY CHEMISTRY
(2021)
Article
Chemistry, Physical
Rajalaxmi Sahoo, C. Reshma, D. S. Shankar Rao, C. V. Yelamaggad, S. Krishna Prasad
Summary: This study investigates the influence of the flexible spacer parity of a guest photoactive liquid crystalline dimer on the photonic bandgap features of the cholesteric and twist grain boundary smectic C phases of the host molecule. The results show that the parity of the photoactive dimer affects the width of the photonic bandgap and the blue-shift of the cholesteric phase. Additionally, the parity of the dimer also affects the layer spacing and two-dimensional periodicity of the liquid crystalline phases.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Sara Rozas, Alberto Gutierrez, Mert Atilhan, Alfredo Bol, Santiago Aparicio
Summary: This study presents a multiscale theoretical investigation on the use of bifunctional hydrophobic Deep Eutectic Solvent for carbon capture using tetrapropylammonium chloride, acetic acid, and ethanolamine. The characterization includes nanoscale analysis of CO2 absorption mechanisms and changes in liquid phase properties during gas capture.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Tabouli Eric Da-yang, Alhadji Malloum, Jean Jules Fifen, Mama Nsangou, Jeanet Conradie
Summary: In this study, the potential energy of different glycine tautomers and their interaction with Cu2+ cations was investigated. The results showed that the solvation medium and the presence of Cu2+ cations influenced the stability of glycine tautomers.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Xiaoliang Gou, Nan Ye, Qingqing Han, Junjie Cui, Long Yi Jin
Summary: In this study, amphiphilic rod-coil molecules with rigid DSA parts and flexible oligoether chains were designed and their assembly capacities were investigated. The morphology of the molecular aggregates was influenced by the pH of the solution and UV light, and the aggregates showed adsorption capacity for nitroaromatic compounds.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Shuang Liu, Liyan Shan, Cong Qi, Wenhui Zhang, Guannan Li, Bei Wang, Wei Wei
Summary: Optimizing the design of styrene-butadiene-styrene copolymer (SBS) is crucial for producing cost-effective SBS modifiers and improving road quality. This study examined the influence of SBS content and molecular structure on viscosity and compatibility. The results showed that the viscosity contribution of SBS is determined by its molecular structure and phase morphology.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Artem A. Petrov, Ekaterina A. Titova, Aydar A. Akhmadiyarov, Ilnaz T. Rakipov, Boris N. Solomonov
Summary: This work focuses on the thermochemistry of solvation of azeotropes. The enthalpies of dissolution of azeotropes in different mediums were determined, and the impact of the structure of the azeotropes on their properties in solution was discussed. A correlation between enthalpies of solvation and molar refraction was used to determine the vaporization enthalpies of azeotropes for the first time. The results were found to be consistent with literature data, obtained using direct and calculated methods. These findings contribute to the analysis of the structure-property relationships of azeotropes.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
L. V. Kamaeva, E. N. Tsiok, N. M. Chtchelkatchev
Summary: Understanding the correlations between liquids and solids allows us to predict the thermodynamic parameter range favorable for the formation of intriguing solid phases by studying liquids. In this study, we experimentally and theoretically investigated an Al-Cu-Co system within different composition ranges, and identified high-temperature solid phases. Our findings demonstrated the correlation between the boundaries of different solid phases and undercooling and viscosity in the concentration area.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
R. Aneesh Kumar, S. Jamelah Al-Otaibi, Y. Sheena Mary, Y. Shyma Mary, Nivedita Acharjee, Renjith Thomas, Renjith Raveendran Pillai, T. L. Leena
Summary: In this study, the interactions between doped and pristine coronenes and adenine nucleobases were investigated using Density Functional Theory. The optimal configurations, adsorption energies, charge transfer, and electrical properties of each complex were calculated. It was found that doped coronene had stronger adsorption strength and charge transfer compared to pristine coronene. The stability of the complexes was attributed to non-covalent interactions in the interactive region. The change in electrical conductivity of coronenes after adsorption suggested their sensitivity towards DNA bases. The predicted energy gap and prolonged recovery time for adenine-coronene configurations indicated the potential application of pristine/doped coronene in DNA detection.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Gang Zhou, Yongwei Liu, Biao Sun, Zengxin Liu, Cuicui Xu, Rulin Liu, Qi Zhang, Yongmei Wang
Summary: The CFD-DEM method was used to simulate the dust deposition pattern in the bronchus of anchor digging drivers, revealing the highest dust concentration in the vortex region of the working face. The study also found a positive correlation between dust particle diameter and bronchial deposition rate, and a negative correlation with alveolar deposition rate.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Yan Zhang, Yafei Luo, Lingkai Tang, Mingyan E, Jianping Hu
Summary: This study investigates the effects of different transition metal decorations on B12N12 nanocages on the adsorption properties of nitrosourea drugs using computational methods. The results reveal the presence of weak non-covalent interactions between metals and nanocages, and the interaction between drugs and nanocages plays a significant role in drug adsorption. Compared to free drugs, the adsorption of drugs on nanocages can facilitate electron transfer, reduce energy gaps and chemical hardness, indicating activity at the target site.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
C. I. Alcolado, J. Poblete, L. Garcia-Rio, E. Jimenez, F. J. Poblete
Summary: In this study, the selective oxidation of aromatic aldehydes was investigated using Ru(VI) as a catalyst and hexacyanoferrate (III) as a cooxidant in an alkaline medium. The reaction mechanism involves complex reaction orders for the oxidant and the aromatic aldehyde, while the reaction order for Ru(VI) is one. The proposed mechanism includes two catalytic cycles and the formation and decomposition of complexes. Quantitative structure-activity relationship analysis showed that deactivating groups in the para-position enhance the process.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Inez A. Barbieri, Marcos L. S. Oliveira, Franciele S. Bruckmann, Theodoro R. Salles, Leonardo Zancanaro, Luis F. O. Silva, Guilherme L. Dotto, Eder C. Lima, Mu. Naushad, Cristiano R. Bohn Rhoden
Summary: This study evaluated the adsorption of zolpidem on magnetic graphene oxide and synthesized magnetic graphene oxide adsorbents for zolpidem removal. The best magnetic nanoadsorbent was found to have a removal percentage of 87.07% at specific pH and temperature conditions. The results suggest that the removal of zolpidem is related to the surface chemistry of the adsorbent rather than the surface area of graphene oxide. The adsorbent showed excellent adsorption efficiency and magnetic behavior, making it a promising material for removing zolpidem from aqueous solutions.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Hongyan Huang, Chunquan Li, Siyuan Huang, Yuling Shang
Summary: This study examines the sensitivity of the thermal conductivity of water-based alumina nanofluids to changes in concentration, sphericity, and temperature. The results show that volume fraction and temperature have a significant impact on the thermal conductivity, while sphericity also needs to be considered. A support vector machine regression model was created to analyze the sensitivity of the thermal conductivity to different parameters. The findings indicate that temperature, sphericity, and volume fraction are the most sensitive variables.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Correction
Chemistry, Physical
V. M. Pergamenshchik, T. Bryk, A. Trokhymchuk
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Valentyn Rudenko, Anatolii Tolochko, Svitlana Bugaychuk, Dmytro Zhulai, Gertruda Klimusheva, Galina Yaremchuk, Tatyana Mirnaya, Yuriy Garbovskiy
Summary: This paper reports on the synthesis, structural characterization, spectral and nonlinear-optical properties of glass nanocomposites made of glass forming ionic liquid crystals and nanoparticles. The study reveals that by exciting the nanocomposites within their absorption band, a control over effective optical nonlinearities can be achieved, allowing the modification of the magnitude and sign of the effective nonlinear absorption coefficient. The proposed strategy using metal-alkanoates based glass-forming ionic liquid crystals and nanoparticles shows great potential for the development of nanophotonics and plasmonics technologies.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
