期刊
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
卷 381, 期 -, 页码 161-170出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molcata.2013.10.021
关键词
Carbonates; Epoxides; Carbon dioxide; Chromium catalysts; N4 Schiff ligands
资金
- Generalitat de Catalunya [SGR116]
- Ministerio de Ciencia e Innovacion [CTQ2010-16676]
New neutral and cationic chromium(III) complexes with N4 Schiff base ligands have been prepared and characterized. These complexes are active catalysts for the cycloaddition of CO2 and styrene oxide in CH2Cl2 solutions, affording epoxide conversions in a 39-92% range, with encouraging cyclic carbonate yields (up to 63%). It is to notice that the cationic species were significantly more active than their neutral analogs. Addition of tetrabutylammonium halides improved the selectivity toward styrene carbonate (87% yield). Dichloromethane could be avoided using solvent free or supercritical carbon dioxide as a solvent (scCO(2)) and, moreover, this improved the catalytic activity of the cationic complexes (TOF up to 652h(-1)). Using scCO(2), these chromium catalysts afforded the rapid and selective formation of cyclic carbonates from the coupling of CO2 to various linear terminal epoxides, such as epichlorydrin, propylene oxide and long chain terminal oxiranes. Coupling of cyclohexene oxide and carbon dioxide led to mixtures of poly(cyclohexene) carbonate and cyclic carbonate depending on the conditions (pressure and co-catalyst/catalyst ratio). Poly(cyclohexene) carbonate was isolated with a productivity 388 g/g Cr. Selective formation of the cyclic cyclohexene carbonate was obtained working under scCO(2) conditions. (C) 2013 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据