Review
Chemistry, Physical
Claire A. L. Lidston, Sarah M. Severson, Brooks A. Abel, Geoffrey W. Coates
Summary: The ring-opening copolymerization (ROCOP) of epoxides with CO2 or cyclic anhydrides using multifunctional catalysts has been explored as a versatile route for synthesizing a wide range of polycarbonate and polyester copolymers. Covalently tethering the Lewis acid catalyst and cocatalyst together has been shown to increase both catalyst activity and selectivity in epoxide ROCOP. This review examines the development of multifunctional catalysts for copolymerization of epoxides with CO2, cyclic anhydrides, carbonyl sulfide (COS), and cyclic thioanhydrides, and evaluates how the mechanisms of these catalysts lead to improved activity and selectivity in ROCOP.
Article
Polymer Science
Felipe De La Cruz-Martinez, Marc Martinez de Sarasa Buchaca, Almudena Del Campo-Balguerias, Juan Fernandez-Baeza, Luis F. Sanchez-Barba, Andres Garces, Carlos Alonso-Moreno, Jose A. Castro-Osma, Agustin Lara-Sanchez
Summary: Bimetallic heteroscorpionate acetate zinc complexes exhibited high catalytic activity and selectivity in ring-opening copolymerization reactions, particularly in copolymerization of cyclohexene oxide and cyclic anhydrides.
Article
Chemistry, Organic
Lea Grefe, Esteban Mejia
Summary: This review discusses the development of catalytic systems for the ring-opening copolymerization of epoxides and CO2 to produce polycarbonates, focusing on systems made from earth-abundant metals. It emphasizes on bi- and multimetallic heterogeneous catalytic systems developed since 1985 and homogeneous catalysts reported after 2015, with a focus on the structural features of these complexes and their corresponding reactivities.
Review
Chemistry, Multidisciplinary
Alex J. Plajer, Charlotte K. Williams
Summary: Heteroatom-containing polymers have potential as sustainable replacements for petrochemicals, offering a wide range of properties for various applications. Catalysed ring-opening copolymerisation (ROCOP) provides a route to create precise new polymer structures, leading to a renaissance in research and commercial products.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Multidisciplinary
Harin Kim, Hyo-Jeong Lee, Jiwon Hwang, Su Min Jung, Jun Dong Park, Joon Hyun Baik
Summary: This study successfully synthesized poly(propylene carbonate) polyols with varying carbonate contents using Zn/Co double metal cyanide catalysts. By controlling the calcination temperature and CO2 pressure, polyols with high carbonate content and desirable properties were achieved.
Article
Polymer Science
Ying Wang, Yanni Xia, Zhengjiang Hua, Chengjian Zhang, Xinghong Zhang
Summary: This work presents the copolymerization of propylene carbonate with carbonyl sulfide to prepare poly(thioether)s, which provides a new approach for the application of cyclic carbonates and the synthesis of thioether-based polymers.
Article
Chemistry, Inorganic & Nuclear
Mu-Jia Li, Yu-Chia Su, Guan-Lin Liu, Bao-Tsan Ko
Summary: This study presents the utilization of hexadentate benzothiazole-based diamine-bisphenolate ligands to synthesize dinickel dicarboxylate complexes for copolymerization of carbon dioxide with epoxides. The dinickel carboxylate complexes exhibit high catalytic performance in the alternating copolymerization of CO2 and cyclohexene oxide, with notable selectivity and molecular weight controllability.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Yu-Chia Su, Guan-Lin Liu, Bao-Tsan Ko
Summary: This study reported the synthesis of novel structurally well-defined dihalide bimetallic nickel complexes containing benzotriazole-based 1,3-diamine-linked bisphenolate ligands, which showed high-performance catalytic activity for ring-opening copolymerization of cyclohexene oxide (CHO) with carbon dioxide (CO2) or phthalic anhydride (PA). The most active complex, dinickel diiodo complex 3, demonstrated excellent CO2/CHO copolymerization activity with a high turnover frequency of up to 2250 h(-1). It also effectively catalyzed the copolymerization of CHO with PA, showing broad substrate scope and good activity.
INORGANIC CHEMISTRY
(2023)
Article
Polymer Science
Huining Ding, Xianmin Wu, Bing Han, Ning Liu, Binyuan Liu, Il Kim
Summary: Highly regioselective ring-opening copolymerizations of 5-norbornene-2,3-dicarboxylic anhydride (NA) and epoxide monomers have been achieved using Cr-III catalysts and specific ligands, allowing for the control of cis/trans regioselectivity in the resulting polyesters by adjusting feed ratio and monomer structure. The resulting polyesters from the copolymerization of NA and epichlorohydrin provide a robust platform for post-modification, with the ring-strained C=C double bonds in the norbornene units facilitating further functionalization through azide-alkene 1,3-dipolar cycloaddition reactions based on desired targets.
Review
Chemistry, Multidisciplinary
Guan-Wen Yang, Yao-Yao Zhang, Guang-Peng Wu
Summary: Organoboron catalysts play a significant role in chemical transformations. This study summarizes recent advances in developing organoboron catalysts that combine high efficiency and easy preparation through modular design, optimizing the catalysts for various chemical reactions.
ACCOUNTS OF CHEMICAL RESEARCH
(2021)
Article
Polymer Science
Oliver J. Driscoll, Jack A. Stewart, Paul McKeown, Matthew D. Jones
Summary: A simple and organic catalytic system utilizing 14 Fe(III) complexes as catalysts for ROCOP was developed, leading to the successful synthesis of high-quality polymers and investigation of structure-activity relationships. The discovery that organic catalysts outperformed their Lewis acidic Fe(III) analogues provides hope for future sustainable polymerization research.
Review
Polymer Science
Eduard Gloeckler, Swarup Ghosh, Stephan Schulz
Summary: This review highlights the ongoing developments in the ring-opening polymerization of lactide and caprolactone using beta-diketiminate and beta-ketoiminate metal complexes. The resulting aliphatic polyesters could serve as sustainable replacements to petrochemicals-based polymers, with potential applications in tissue engineering, bio-medical, and agricultural sciences.
Article
Chemistry, Physical
Zhexi Lin, Siddharth Deshpande, Steven R. Denny, William N. Porter, Cong Wang, Justin Marlowe, Phillip Christopher, Weiqing Zheng, Stavros Caratzoulas, Dionisios G. Vlachos, Jingguang G. Chen
Summary: This study investigates the reaction mechanism and active sites of THFA ring-opening on a WOx/Pt inverse oxide catalyst using model surface experiments, first-principles calculations, and catalyst characterization. The results demonstrate that the introduction of WOx can modulate the interaction strength between THFA and the surface, facilitating the desorption of the desired product. This study provides insights into catalyst design for the selective ring-opening of biomass-derived oxygenates.
Article
Chemistry, Multidisciplinary
Dmitry S. Belov, Logesh Mathivathanan, Melanie J. Beazley, William Blake Martin, Konstantin V. Bukhryakov
Summary: The study explores the capability of an iron-based catalyst in performing ring-opening metathesis polymerization of olefins, demonstrating that the use of in situ prepared heteroleptic iron catalysts significantly enhances polymerization rate and selectivity.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Inorganic & Nuclear
Diego Jaraba Cabrera, Ryan D. Lewis, Carlos Diez-Poza, Lucia Alvarez-Miguel, Marta E. G. Mosquera, Alex Hamilton, Christopher J. Whiteoak
Summary: This study investigates the synthesis of aluminum, gallium, and indium compounds supported by a readily prepared salphen ligand and explores their structures and potential as catalysts for the synthesis of cyclic carbonates. It is demonstrated that the indium compounds are the most active catalysts, despite their lower Lewis acidity compared to aluminum compounds. A Density Functional Theory (DFT) study provides important insights into the reasons for the high activity of the indium catalyst.
DALTON TRANSACTIONS
(2023)
Article
Biochemistry & Molecular Biology
Jeerapat Doungchawee, Chadin Kulsing, Naruemon Suekaew, Sarisa Na Pombejra, Warinthorn Chavasiri, Napasawan Plabutong, Arsa Thammahong, Tanatorn Khotavivattana
CHEMISTRY & BIODIVERSITY
(2019)
Article
Biochemistry & Molecular Biology
Kanyani Sangpheak, Lueacha Tabtimmai, Supaphorn Seetaha, Chompoonut Rungnim, Warinthorn Chavasiri, Peter Wolschann, Kiattawee Choowongkomon, Thanyada Rungrotmongkol
Article
Oncology
Panupong Mahalapbutr, Piyanuch Wonganan, Warinthorn Chavasiri, Thanyada Rungrotmongkol
Article
Chemistry, Applied
Van-Kieu Nguyen, Jirapast Sichaem, Huu-Hung Nguyen, Xuan Hieu Nguyen, Thi-Thu-Loi Huynh, Thi-Phuong Nguyen, Nakorn Niamnont, Dinh-Hung Mac, Duc-Dung Pham, Warinthorn Chavasiri, Kim-Phi-Phung Nguyen, Thuc-Huy Duong
Summary: A series of usnic acid benzylidene derivatives were synthesized and evaluated for their anticancer activity, with compound 2e showing potent cytotoxicity against K562 leukemia cells without affecting HEK293 normal cells.
NATURAL PRODUCT RESEARCH
(2021)
Article
Chemistry, Applied
Thanh-Nha Tran, Jirapast Sichaem, Van-Kieu Nguyen, Warinthorn Chayasiri, Nakorn Niamnont, Jongkolnee Jongaramruong, Thuc-Huy Duong
Summary: A new ent-atisane diterpenoid, ent-3 alpha-acetoxy-1 beta,16 beta,17-trihydroxyatisane (1), was isolated from the aerial parts of Euphorbia antiquorum L, along with four known compounds. The structure of compound 1 was identified through interpretation of spectroscopic data and comparison with literature reports.
NATURAL PRODUCT RESEARCH
(2021)
Article
Biochemistry & Molecular Biology
Panupong Mahalapbutr, Piyanuch Wonganan, Thanapon Charoenwongpaiboon, Manchumas Prousoontorn, Warinthorn Chavasiri, Thanyada Rungrotmongkol
Article
Microbiology
Nawaporn Vinayavekhin, Wimonsiri Kongchai, Jittra Piapukiew, Warinthorn Chavasiri
Article
Chemistry, Medicinal
Van-Kieu Nguyen, Gregory Genta-Jouve, Thuc-Huy Duong, Mehdi A. Beniddir, Jean-Francois Gallard, Solenn Ferron, Joel Boustie, Elisabeth Mouray, Philippe Grellier, Warinthorn Chavasiri, Pierre Le Pogam
Article
Biotechnology & Applied Microbiology
Jumpol Sopanaporn, Sirinporn Suksawatamnuay, Amanulia Sardikin, Rittirat Lengwittaya, Warinthorn Chavasiri, Tokichi Miyakawa, Chulee Yompakdee
FEMS YEAST RESEARCH
(2020)
Article
Biotechnology & Applied Microbiology
Anyaporn Sangkaew, Nawara Samritsakulchai, Kamonpan Sanachai, Thanyada Rungrotmongkol, Warinthorn Chavasiri, Chulee Yompakdee
JOURNAL OF MICROBIOLOGY AND BIOTECHNOLOGY
(2020)
Article
Biochemistry & Molecular Biology
Kowit Hengphasatporn, Kitiporn Plaimas, Apichat Suratanee, Peemapat Wongsriphisant, Jinn-Moon Yang, Yasuteru Shigeta, Warinthorn Chavasiri, Siwaporn Boonyasuppayakorn, Thanyada Rungrotmongkol
Article
Chemistry, Applied
Thi-Minh-Dinh Tran, Van-Kieu Nguyen, Thuc-Huy Duong, Thanh-Nha Tran, Ngoc-Hong Nguyen, Asshaima Paramita Devi, Warinthorn Chavasiri, Minh-Hiep Dinh, Nguyen-Minh-An Tran, Jirapast Sichaem
Summary: A novel oxime polyketide, maydisone, along with two known compounds, was isolated from Bipolaris maydis cultures. Maydisone showed the most powerful inhibition of alpha-glucosidase.
NATURAL PRODUCT RESEARCH
(2022)
Article
Pharmacology & Pharmacy
Kowit Hengphasatporn, Arthur Garon, Peter Wolschann, Thierry Langer, Shigeta Yasuteru, Thao N. T. Huynh, Warinthorn Chavasiri, Thanaphon Saelee, Siwaporn Boonyasuppayakorn, Thanyada Rungrotmongkol
SCIENTIA PHARMACEUTICA
(2020)
Article
Multidisciplinary Sciences
Anne Frances Murray, Hiroki Satooka, Kuniyoshi Shimizu, Warinthorn Chavasiri, Isao Kubo
Article
Multidisciplinary Sciences
Adisak Chaitanee, Banja Junhasavasdikul, Warinthorn Chavasiri
CHIANG MAI JOURNAL OF SCIENCE
(2019)