期刊
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
卷 340, 期 1-2, 页码 60-64出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molcata.2011.03.010
关键词
Catalysis behavior; Metalloporphyrin; Cyclohexane oxidation; Air
资金
- National Natural Science Foundation of China [51063001]
- Natural Science Foundation of Guangxi province [2010GXNSFD013014]
- Experimental Innovation Project Foundation of Guangxi University, PR China
In this work, boehmite-supported iron tetraphenylporphyrins with p-substituted nitro and methoxyl groups on the phenyl ring were prepared and characterized by UV-vis, FT-IR and XRD techniques. The catalytic activity and efficiency of the two supported catalysts for the aerobic oxidation of cyclohexane were investigated and compared. From the experimental evidence we conclude that the differences in the catalysis behavior should be mainly attributed to the effect of the different p-substituents on the redox potential, and the differences in the promotion of activity by the boehmite support. (C) 2011 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据