Article
Chemistry, Physical
Ting Hu, Zhi Xing, Lu Huang, Dengxue Li, Xiangchuan Meng, Xiaotian Hu, Yiwang Chen
Summary: To address the limitations of two-dimensional perovskites in photovoltaic applications, a strategy for developing high-quality patterned 2D perovskites was proposed. The patterned films showed improved light absorption and interfacial contact, leading to enhanced efficiencies and stability of the solar cells.
CHEMISTRY OF MATERIALS
(2022)
Article
Environmental Sciences
Punika Maneewan, Warayuth Sajomsang, Sudkanueng Singto, Jenyuk Lohwacharin, Benjaporn Boonchayaanant Suwannasilp
Summary: This study modified the surface of PVDF ultrafiltration membranes with tannic acid (TA) and Cu (II) to reduce membrane fouling in AnMBRs, showing that modifying membranes with a certain antibacterial property could improve performance and reduce irreversible fouling.
ENVIRONMENTAL POLLUTION
(2021)
Article
Chemistry, Multidisciplinary
Dong Hyun Kim, Jin Young Oh, Da-Bin Yang, Dong Wook Lee, Jonghoon Won, Jong In Jang, Hae-Chang Jeong, Dae-Shik Seo
Summary: A nanostructured composite of UV-curable polymer and TaO was successfully fabricated and analyzed using AFM, XRD, FTIR, and XPS. Increasing the content of UV-curable polymers in the composite enabled successful networking with TaO and transfer. The composite films showed excellent nanostructure transfer and thermal stability, as well as improved C-V characteristics compared to rubbed polyimide LC cells. Therefore, these nanostructured composites have great potential for LC devices.
JOURNAL OF NANOPARTICLE RESEARCH
(2023)
Review
Engineering, Environmental
Mona Dehghankar, Romina HMTShirazi, Toraj Mohammadi, Maryam Ahmadzadeh Tofighy
Summary: Metal-organic frameworks (MOFs) with highly flexible structures and extraordinary surface area are considered as promising materials for separation processes. However, the challenge lies in improving MOFs' stability and recyclability in membranes and overcoming membrane fouling. This article presents an overview of current progress in the combination of MOFs with polymeric membranes to address these issues.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Engineering, Chemical
Min Hu, Lina Zhao, Ningbo Yu, Ziqi Tian, Zhonglong Yin, Zhen Yang, Weiben Yang, Nigel J. D. Graham
Summary: The study introduced a strategy for fouling mitigation in ultrafiltration (UF) water treatment by applying an ultra-low concentration of moderately-hydrophobic chitosan (MHC) and using a mildly elevated backwash temperature. The MHC-based UF system showed superior performance under optimal conditions, reducing reversible fouling by approximately 55% and irreversible fouling by about 80%, while also improving effluent quality. The additional cost of MHC dosing and backwash water heating was estimated to be low, making the MHC-based process a potential feasible and cost-effective approach for UF fouling control.
JOURNAL OF MEMBRANE SCIENCE
(2021)
Article
Chemistry, Physical
Zheng Nie, Caihong Liu, Xihui Jiang, Yifan Zhou, Xu Lin, Xiaoqing Zhao, Qiang He, Hongxiang Chai, Xueling Pang, Jun Ma
Summary: This study reports a membrane modification strategy using polydopamine and a zwitterionic surfactant to enhance the anti-fouling properties of a polyethersulfone membrane. The modified membrane showed significantly reduced flux decline and fouling resistance compared to the pristine membrane. The optimal anti-fouling performance was achieved when the concentration of the zwitterionic surfactant was low.
APPLIED SURFACE SCIENCE
(2022)
Review
Chemistry, Analytical
Mingjie Li, Yulong Chen, Wenxin Luo, Xing Cheng
Summary: This article reviews the application of nanoimprint lithography (NIL) in demolding processes, including NIL technology introduction, process simulation, demolding difficulties analysis, and demolding solutions. The authors propose feasible methods to alleviate demolding difficulties, reduce defect rates, and maximize the throughput of nanoimprint lithography.
Article
Nanoscience & Nanotechnology
Alejandra Jacobo-Martin, Jaime J. Hernandez, Patricia Pedraz, Eduardo Solano, Ivan Navarro-Baena, Isabel Rodriguez
Summary: The thermal stability of antireflective moth-eye topographical features fabricated by nanoimprint lithography on PMMA incorporating TiO2 nanoparticles is greatly improved, delaying pattern relaxation and enhancing pattern stability even at high temperatures. This enhancement in thermal behavior will significantly improve the functionality and performance of the antireflective films, especially in light-trapping applications where temperatures typically rise.
Article
Polymer Science
Dong Hyun Kim, Jin Young Oh, Da-Bin Yang, Dong Wook Lee, Jonghoon Won, Dai-Hyun Kim, Se-Hoon Choi, Jin-Ah Kim, Hong-Gyu Park, Dae-Shik Seo
Summary: In this paper, a thin film was prepared using the UV-NIL method, which showed good liquid crystal alignment properties and thermal stability. Excellent electro-optical properties were also confirmed.
POLYMERS FOR ADVANCED TECHNOLOGIES
(2023)
Article
Environmental Sciences
Lauren M. Ward, Rushabh M. Shah, Jessica D. Schiffman, Steven T. Weinman
Summary: This contribution discusses a method to reduce bacteria fouling on ultrafiltration membranes by applying nano-scale line-and-groove patterns on the membrane surface. The study demonstrates that the patterned membranes have a lower attachment of microbes and a higher flux recovery ratio compared to the non-patterned membranes.
Article
Polymer Science
Tatiana Plisko, Katsiaryna Burts, Anastasia Penkova, Mariia Dmitrenko, Anna Kuzminova, Sergey Ermakov, Alexandr Bildyukevich
Summary: Membrane fouling is a serious issue in membrane technology that can be reduced by the technique of membrane modification through the addition of hydrophilic polymers or polyelectrolytes. This study systematically investigated the effect of different molecular weights of polyacrylic acid (PAA) on the structure and properties of polysulfone membranes. It was found that higher molecular weight PAA resulted in membranes with smaller pore size, higher hydrophilicity, and better antifouling performance. The addition of PAA also led to a decrease in water contact angle and an increase in rejection for humic acid solutions.
Article
Engineering, Environmental
Eunjoo Koh, Nahyun Cho, Hee Min Park, Yong Taek Lee
Summary: In this study, chemically modified polyvinylidene fluoride (PVDF) hollow fiber membranes with anionic-hydrophilic and hydrophobic materials exhibited excellent properties for separating bacteria and particles. The modified membranes showed high fouling resistance and a higher protein recovery ratio compared to the pristine membrane. The developed membranes can be applied in biopharmaceutical production and removal of proteins, retro viruses, and bacteria.
JOURNAL OF WATER PROCESS ENGINEERING
(2023)
Article
Engineering, Biomedical
Mahya Ganjian, Khashayar Modaresifar, Dionysios Rompolas, Lidy E. E. Fratila-Apachitei, Amir A. A. Zadpoor
Summary: Developing a high-throughput nanopatterning technique with precise control over feature dimensions is crucial for studying cell-nanopattern interactions. This study presents a process that fulfills these criteria by using electron-beam lithography to fabricate controlled arrays of submicron pillars and developing etching procedures to create the desired height. The study demonstrates the significance of the fabricated pillars in inducing osteogenic differentiation and utilizes replication techniques to pattern bio-instructive surfaces. Overall, the method enables the precise fabrication of submicron and nanopatterns for systematic cell studies.
ACTA BIOMATERIALIA
(2022)
Article
Engineering, Chemical
Liu Zuodong, Wang Yuchen, Zhao Bo, Jiang Xin, Xu Zhiming
Summary: In this study, a modified surface technology was used to suppress and reduce microbial fouling on heat exchange surfaces. The results showed that the Ni-Cu-P modified surface had excellent antifouling performance, with a reduction of 92.0% in microbial fouling compared to carbon steel. By adjusting the operating conditions, such as temperature and flow rate, the accumulation of microbial fouling on the Ni-Cu-P modified surface can be further reduced, allowing for long-term cleaning and effective heat transfer.
ADVANCED POWDER TECHNOLOGY
(2023)
Article
Polymer Science
Mingwei Tang, Xueren Fang, Bowen Li, Meng Xu, Haiyan Wang, Shuang Cai
Summary: A facile strategy for fabricating hydrophobic and anti-fouling surfaces on wood substrates is developed in this work. The modified wood shows good hydrophobicity and anti-fouling properties, as well as UV resistance and durability against tape peel test and finger wiping.
Article
Engineering, Chemical
Masoud Aghajani, Alan R. Greenberg, Yifu Ding
JOURNAL OF MEMBRANE SCIENCE
(2020)
Article
Nanoscience & Nanotechnology
Thien Tran, Shiwei Pan, Xiaoyi Chen, Xiao-Ci Lin, Adrienne K. Blevins, Yifu Ding, Haiqing Lin
ACS APPLIED MATERIALS & INTERFACES
(2020)
Article
Nanoscience & Nanotechnology
Mengyuan Wang, Sujan K. Ghosh, Christopher M. Stafford, Adrienne K. Blevins, Sijia Huang, Jaylene Martinez, Rong Long, Christopher N. Bowman, Jason P. Killgore, Min Zou, Yifu Ding
ACS APPLIED MATERIALS & INTERFACES
(2020)
Article
Engineering, Chemical
Danielle J. Park, Omkar D. Supekar, Alan R. Greenberg, Juliet T. Gopinath, Victor M. Bright
Summary: Chemical characterization and real-time monitoring of scaling and removal processes in a bench-scale RO system were conducted using Raman spectroscopy. The results showed that changes in Raman intensity were a more sensitive indicator of scale removal on the membrane surface, providing crucial chemical composition and spatial distribution information.
Article
Polymer Science
Adrienne K. Blevins, Lewis M. Cox, Leiqing Hu, Jasper A. Drisko, Haiqing Lin, Christopher N. Bowman, Jason P. Killgore, Yifu Ding
Summary: The study investigated the effects of pattern geometry on CO2 permeability and mechanical properties by controlling line and square patterns through photopatterning. It was found that materials with lower cross-linking density in 10 μm square patterns exhibited synergistically enhanced barrier properties.
Article
Chemistry, Multidisciplinary
Lingxiang Zhu, Liang Huang, Surendar R. Venna, Adrienne K. Blevins, Yifu Ding, David P. Hopkinson, Mark T. Swihart, Haiqing Lin
Summary: By rapidly fabricating ultrathin silica-like membranes at 20 degrees C, excellent H-2/CO2 separation properties can be achieved, showing great potential for economic hydrogen production and minimal carbon emissions.
Article
Engineering, Chemical
Gengyi Zhang, Thien N. N. Tran, Liang Huang, Erda Deng, Adrienne Blevins, Wenji Guo, Yifu Ding, Haiqing Lin
Summary: Cross-linked amorphous poly(ethylene oxide) (XLPEO) is a leading membrane material for post-combustion CO2 capture. In this study, high molecular weight yet soluble HPEO was synthesized via atom transfer radical polymerization (ATRP) and fabricated into defect-free thin-film composite (TFC) membranes with excellent performance. The membranes showed stable CO2 permeance and CO2/N-2 selectivity under simulated challenge.
JOURNAL OF MEMBRANE SCIENCE
(2022)
Article
Polymer Science
Liang Huang, Wenji Guo, Himangshu Mondal, Skye Schaefer, Thien N. Tran, Shouhong Fan, Yifu Ding, Haiqing Lin
Summary: Amorphous PDXL-based hyperbranched polymers with varied branch length show attractive CO2/N-2 and CO2/CH4 separation properties.
Article
Multidisciplinary Sciences
Leiqing Hu, Vinh T. Bui, Ajay Krishnamurthy, Shouhong Fan, Wenji Guo, Sankhajit Pal, Xiaoyi Chen, Gengyi Zhang, Yifu Ding, Rajinder P. Singh, Monica Lupion, Haiqing Lin
Summary: By doping polymers with thermolabile cross-linkers before low-temperature carbonization, the processability of the polymers can be retained and superior hydrogen/carbon dioxide separation properties can be achieved.
Article
Polymer Science
Leiqing Hu, Shouhong Fan, Liang Huang, Vinh T. Bui, Thien Tran, Kaiwen Chen, Yifu Ding, Mark T. Swihart, Haiqing Lin
Summary: This study demonstrates a method to break the permeability/selectivity tradeoff using supramolecular polymer networks (SPNs) comprising polybenzimidazole (PBI) and dissociable metal salts. By coordinating metal ions and plasticizing with trifluoroacetate anions, the SPNs achieve higher fractional free volumes and lower d-spacing, resulting in increased H-2 permeability and H-2/CO2 selectivity. The SPNs also exhibit superior mechanical properties and stable performance in the presence of water vapor.
Article
Chemistry, Physical
Jared Beshai, Thomas DiSorbo, Jacob Hutfles, Jacob Segil, Richard F. ff Weir, John Pellegrino
Summary: This study presents the key characteristics of implementing cellulose acetate (CA) coatings on carbon cloth used as a fuel diffusion layer in aqueous fuel-fed cells, and demonstrates their functionality. The results show that these coatings enhance aqueous solution permeation and adhesion properties, leading to a two-fold increase in maximum power generation in alkaline DGFCs.
JOURNAL OF POWER SOURCES
(2022)
Article
Chemistry, Physical
Leiqing Hu, Vinh T. Bui, Shouhong Fan, Wenji Guo, Sankhajit Pal, Yifu Ding, Haiqing Lin
Summary: This study demonstrates the formation of supramolecular assemblies by complexation between aromatic polycarboxylic acids and imidazoles, and shows their attractive H2/CO2 separation performance. It also investigates the correlation between the molar ratio of protons to polybenzimidazole repeating units and the performance, as well as the effect of temperature on selectivity.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Polymer Science
Adrienne K. Blevins, Mengyuan Wang, Michelle L. Lehmann, Leiqing Hu, Shouhong Fan, Christopher M. Stafford, Jason P. Killgore, Haiqing Lin, Tomonori Saito, Yifu Ding
Summary: This study demonstrates the ability to program heterogeneity in two stage reactive polymer networks (TSRP), and investigates the effect of this heterogeneity on CO2/N-2 selectivity. A novel TSRP formulation with poly(ethylene oxide) (PEO) and polydimethylsiloxane (PDMS) groups is designed, showing higher permeability, selectivity, and improved mechanical toughness compared to unpatterned materials. This highly customizable material system has the potential to simultaneously improve permselective performance and mechanical properties.
Article
Materials Science, Multidisciplinary
Kimberly K. Childress, Marvin D. Alim, Sudheendran Mavila, Vikina Martinez, Yifu Ding, Christopher N. Bowman, Jeffrey W. Stansbury
Summary: This study explores the potential of photopolymerizable thermoplastics and investigates the relationship between monomer structure and material properties. These materials exhibit rapid photopolymerization and distinctive mechanical properties, providing a basic framework for applications such as 3D printing.
ACS APPLIED POLYMER MATERIALS
(2021)
Article
Nanoscience & Nanotechnology
Simone Murchio, Yifu Ding, Giorgio Speranza, Gian Domenico Soraru, Devid Maniglio
ACS APPLIED MATERIALS & INTERFACES
(2020)
Article
Engineering, Chemical
Jiawei Hou, Shixuan Guo, Nigel Graham, Wenzheng Yu, Kening Sun, Ting Liu
Summary: A novel 2D composite membrane based on r-HGO and MXene materials was developed, demonstrating exceptional performance for water treatment in terms of permeability, pollutant rejection, and physical stability. The optimization of preparation conditions and material proportions can result in high water flux and efficient removal of pollutants.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Retraction
Engineering, Chemical
Chang Liu, Jinghong Liu, Liang Zhu, Shanfu Tang, Huixin Xiong
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Rui Gao, Caihong Liu, Andreia F. Faria, Qiang He, Chun Yang, Jun Ma
Summary: A novel copolymer architecture has been developed to address biofouling concerns in thin-film composite (TFC) membranes by integrating anti-fouling, bactericidal, and fouling-release functions. The multifunctional membrane demonstrates promising anti-adhesive properties, self-cleaning ability, and high flux recovery rate.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Alexander T. Bridge, Noah P. Wamble, Matthew S. Santoso, Joan F. Brennecke, Benny D. Freeman
Summary: This study demonstrates the reproducible preparation of high-flux defect-free asymmetric gas separation membranes using Cyrene(TM) as a majority dope formulation component. By adjusting the volume ratios of Cyrene(TM) and THF, as well as the concentrations of Matrimid(R) and the dry step time, optimal membrane performance is achieved.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Alessandra Imbrogno, Han Ya Lin, Babak Minofar, Andrea Iris Schaefer
Summary: In this study, a composite nanofiber membrane containing cross-linked beta-cyclodextrin-epichlorohydrin was prepared and evaluated for the removal of steroid hormones. The results showed that the membrane had high adsorption capacity and the ability to form a specific inclusion complex interaction with the hormones, indicating its potential application in hormone removal.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Bora Shin, Jaewon Shin, Yanuar Chandra Wirasembada, Ki Young Park, Jinwoo Cho
Summary: This study develops a mathematical model to estimate the initial flux of volatile fatty acids in the direct contact membrane distillation process. It identifies the parameters affecting the flux and their relationship with pH.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Yi-Jui Yeh, Jr Rong Liou, Wei Lin, Kuo-Lun Tung, Wei-Hung Chiang
Summary: This study demonstrates an effective plasma engineering method to create nitrogen-doped graphene quantum dot (NGQD)-inorganic nanocomposites for tunable molecular separation. The composite materials show high separation efficiency and controllable nanopore structures, making them potentially valuable for various applications.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Horacio Lopez-Marques, Kristofer L. Gleason, Manuel Aguilar-Vega, Rita Sulub-Sulub, J. Ehren Eichler, Hyeonji Oh, C. Buddie Mullins, Benny D. Freeman, Manish Kumar
Summary: In this study, water transport properties in Carbon Molecular Sieve (CMS) membranes were investigated. It was found that membranes synthesized at different pyrolysis temperatures exhibited varying water permeabilities. Compared to other polymeric materials, CMS membranes showed high water permeability, indicating potential for dehydration applications.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Dmitry A. Alentiev, Roman Yu. Nikiforov, Marina A. Rudakova, Danil P. Zarezin, Maxim A. Topchiy, Andrey F. Asachenko, Nikolay A. Belov, Maxim Bermeshev
Summary: A series of new norbornene-type monomers containing linear and branched substituents were synthesized, and robust thin membranes were prepared by vinyl-addition polymerization. Gas separation performance for the synthesized polymers was evaluated, and the structure of substituent side chains was found to significantly affect gas permeability and CO2 facilitated transport.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Lei Yan, Qi Zhang, Ze Zhang, Gui-Jie Li, Yi Jin, Xin-Lin Zhang, Yan-Yun Sun
Summary: In this study, a continuous, stable and fast ion transport channel was established through in-situ guided cross-linking of zinc alginate hydrogels on a porous membrane, overcoming the negative pore effect and effectively inhibiting the dendrite growth of zinc anodes and interfacial side reactions.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Yuqing Zhang, Ailing Zhang, Huiyang He, Yuting Fan, Yongjiang Li, Song Wang, Sanxi Li
Summary: The Langmuir-Blodgett self-assembly process is used to create an ordered SPEEK membrane, which enhances the proton conductivity by three times compared to conventional solution casting method.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Hasan Ismaeel, David Gibson, Eleonora Ricci, Maria Grazia De Angelis
Summary: In this study, a machine learning-based group contribution method (ML-GC) was developed to predict pure polymer parameters and successfully applied to predict gas solubility and gas solubility isotherms in glassy polymeric membranes. The model showed satisfactory performance on a small dataset, but has the potential to provide more accurate predictions for a wider range of polymers as more data becomes available.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Yi Ji, Yu Sun, Huilin Li, Qiang Fu, Yan Zhang
Summary: Previous studies have shown that vibration- or rotation-based techniques can effectively mitigate fouling during membrane filtration. However, it is difficult to incorporate these techniques with spiral wound modules (SWMs) widely used in water and wastewater treatment. This study developed a prototype membrane system to accommodate angular vibrations with a modified SWM, and experimental results showed that applying angular vibrations can effectively control algal fouling in an SWM with lower energy consumption compared to traditional methods.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Lakshmeesha Upadhayaya, Abaynesh Yihdego Gebreyohannes, Muhammad Wakil Shahzad, Usman T. Syed, Sandra L. Aristizabal, Radoslaw Gorecki, Suzana P. Nunes
Summary: Increasing temperatures worldwide pose a significant health risk, exacerbated by high humidity. Conventional air conditioners contribute heavily to carbon dioxide emissions, with dehumidification being a major factor. Membrane-based dehumidification system offers energy efficiency and non-toxic water vapor removal. This study demonstrates a membrane dehumidification system with polymeric hollow fibers coated with a green polyphenol coating, showing remarkable water vapor transport rate and selectivity. Long-term testing reveals minimal decline in vapor transport and a 4-5 times higher coefficient of performance (COP) compared to conventional dehumidifiers, making it a highly competitive, energy-saving device with reduced emissions and a smaller footprint.
JOURNAL OF MEMBRANE SCIENCE
(2024)
Article
Engineering, Chemical
Zhengzhong Zhou, Xue Zhu, Yi Yuan, Shaoqiang Wang, Xiaoshan Meng, Taoli Huhe, Qian Wang
Summary: In this study, lignin, a biomass material, was chemically modified and utilized in the interfacial polymerization process to improve the performance of nanofiltration membranes. The modified membranes showed enhanced hydrophilicity and anti-fouling properties, and the optimization of membrane pore size increased permeability. The study also demonstrated the potential application of the membranes in biogas slurry valorization.
JOURNAL OF MEMBRANE SCIENCE
(2024)