期刊
JOURNAL OF MATHEMATICAL CHEMISTRY
卷 50, 期 1, 页码 220-232出版社
SPRINGER
DOI: 10.1007/s10910-011-9907-3
关键词
Chemical topology; Higher-order topology; Brunnian links; Hopf links; DNA
资金
- National Institute of General Medical Sciences [NCS:GM-29554]
- National Science Foundation [CTS-0608889, CCF-0726378]
- Army Research Office [48681-EL, W911NF-07-1-0439]
- Office of Naval Research [N000140910181, N000140911118]
The construction of chemical species with topological properties is an area of increasing interest. Numerous such structures have been synthesized in recent years, particularly from DNA, which is a natural synthon for these molecules. Recently, higher-order topological structures have been introduced. These hyper-structures consist of combinations of simple structures, such as a Brunnian Link of Brunnian Links or a Hopf Ring of Hopf Rings, or combinations thereof. In this article, we discuss the possibilities of constructing these hyper-structures with real molecules, particularly emphasizing the tools that result from the double helical structure of DNA.
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