期刊
JOURNAL OF MATERIALS SCIENCE
卷 48, 期 11, 页码 3894-3903出版社
SPRINGER
DOI: 10.1007/s10853-013-7191-2
关键词
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资金
- Tunisian Ministry of Higher Education and Scientific Research
- Ministry of Science and Higher Education of Poland
- CePT Project [POIG.02.02.00-14-024/08-00]
A systematic investigation of structural, magnetic, and magnetocaloric properties is reported for a series of monovalent sodium-doped manganites Pr0.6Sr0.4-x Na (x) MnO3 (x = 0, 0.05, 0.1, 0.15, and 0.2). Rietveld refinements of the X-ray diffraction patterns show that all powder samples are single-phased and crystallized in the orthorhombic structure with Pnma space group. Magnetic characterization and Arrott plot confirm the second-order phase transition at Curie temperature T (C) decreasing from 310 K for x = 0 down to 272 K for x = 0.2. Magnetic entropy change is largest for x = 0 reaching 1.95 J kg(-1) K-1 at 2 T field. This corresponds to a large relative cooling power of 102 J kg(-1) . Magnetic field sensitivity of magnetic entropy change and relative cooling power are analyzed and discussed.
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