期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 21, 期 48, 页码 19249-19256出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1jm14029a
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资金
- National Science Council [98-2119-M-002-007-MY3, NSC 100-2112-M-019-002-MY3]
- Ministry of Economic Affairs of Taiwan [99-EC-17-A-08-S1-042]
A novel bipolar molecule CNBzIm comprised of electron-donating carbazole and electron-accepting phenylbenzimidazole is designed, synthesized and characterized for RGB phosphorescent organic light emitting diodes (PhOLEDs). CNBzIm exhibits promising properties such as high triplet energy (E-T = 2.71 eV) due to disrupted pi-conjugation, bipolar and balanced charge transport ability (mu(h) approximate to mu(e) approximate to 10(-5) cm(2) V-1 s(-1)), and high morphological stability (T-g = 185 degrees C). PhOLEDs adopted CNBzIm as a host respectively doped with Os(bpftz)(2)(PPh2Me)(2), (PPy)(2)Ir(acac) and FIrpic under the same device structure show excellent performance with external quantum efficiencies (eta(ext)) as high as 19.1% for red, 17.8% for green, and 12.7% for blue. A two-color, all-phosphor and single-emitting-layer WOLED hosted by CNBzIm was achieved with a maximum eta(ext) of 15.7%, current efficiency (eta(c)) of 35 cd A(-1), and power efficiency (eta(p)) of 36.6 lm W-1. Utilizing a bipolar host with balanced mobilities, WOLED can effectively broaden its recombination zone and show high color stability. The Commission Internationale de L'Eclairage (CIE) coordinates of the WOLED remain almost constant when the brightness goes from 1700 cd m(-2) (0.32, 0.41) to 49 900 cd m(-2) (0.31, 0.41).
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