Article
Environmental Sciences
Qing Wu, Qiannan Li, Ying Zhang, Ruihan Wan, Sen Peng
Summary: This study isolated two novel Cr(VI)-reducing bacteria from a Cr salt plant and optimized their reduction conditions. It was found that Agrobacterium sp. Cr-1 showed a high capacity for Cr(VI) reduction, making it a promising candidate for the remediation of Cr(VI)-contaminated sites.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Polymer Science
Hartina Mohd Yusop, Annur Isma Husna Mohd Ismail, Wan Norfazilah Wan Ismail
Summary: A new biopolymer-silica hybrid material composed of inulin and TEOS was successfully synthesized via sol-gel method for use as an adsorbent. Analysis using FTIR, EDX, FESEM, XRD, BET, and TGA confirmed the strong interaction between inulin and TEOS, optimal morphology and characteristics for absorption properties, mesoporous structure, and thermal stability of the composite material.
Article
Chemistry, Multidisciplinary
Nidhi Verma, Tejpal S. Chundawat, Praveen K. Surolia, Dipti Vaya
Summary: TiO2/GO nanocomposite was successfully fabricated and used for reduction of Cr-VI under simulated solar light illumination. Characterization results showed that the nanocomposite had small crystallite size and good photocatalytic activity.
Article
Chemistry, Multidisciplinary
Qian Wu, Feng Jiang, Guo Feng, Sanhai Wang, Lifeng Miao, Weihui Jiang, Jian Liang, Jianmin Liu
Summary: MgAl2O4/C composite was synthesized using a low-temperature non-hydrolytic sol-gel method with Mg powder, Al wire, and isopropanol as raw materials. The influence of different magnesium sources and heat treatment temperature on the synthesis and adsorption properties of the composite was investigated. The results showed that amorphous MgAl2O4 had better adsorption capacity for Congo red compared to its crystalline counterpart, which could be attributed to the bimetallic alkoxides structure and the Lewis acid-base reaction between the anionic dye and the composite surface.
ARABIAN JOURNAL OF CHEMISTRY
(2023)
Article
Nanoscience & Nanotechnology
Soad Z. Alsheheri, Ahmed Shawky, Wejdan T. Alsaggaf, Z. Zaki
Summary: The accumulation of Cr(VI) ions can have serious impacts on the environment and human health. This study presents a simple synthesis of ZnSe nanoparticles anchored to TiO2 for visible-light-driven photocatalytic reduction of Cr(VI) ions. The introduction of ZnSe enhances the light absorption and significantly improves the photocatalytic activity, while the nanocomposite exhibits good stability.
Article
Environmental Sciences
Jia Chen, Xiaoguang Li, Longzhan Gan, Guangyang Jiang, Ruoshi Zhang, Zhe Xu, Yongqiang Tian
Summary: The isolated strain Lysinibacillus HST-98 shows promising results in reducing Cr(VI) pollution, even at high concentrations. Optimal growth conditions for the strain include a pH of 8-9, a temperature of 36 degrees Celsius, and sodium lactate as an electron donor. Coexisting metal ions like Cu2+, Co2+, and Mn2+ enhance Cr(VI) reduction, while Zn2+, Ni2+, and Cd2+ have the opposite effect. The reduction mechanism of strain HST-98 is primarily mediated by intracellular enzymes, and the genes and enzymes related to chromium metabolism in this strain have been annotated to further understand its mechanism.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Article
Chemistry, Physical
S. Habi Ben Hariz, H. Lahmar, G. Rekhila, A. Bouhala, M. Trari, M. Benamira
Summary: MgCr2O4 prepared by the sol-gel route exhibits good photoelectrochemical activity under visible light. It can effectively reduce hexavalent chromate to trivalent chromium under optimal conditions.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2022)
Article
Biochemistry & Molecular Biology
Yi Wei, Wei Chen, Chuanfu Liu, Huihui Wang
Summary: This study involved the preparation of two Cr(VI) adsorbents using hemicelluloses, with the HTC-NH2 showing higher adsorption capacity. The results suggest that the green hydrothermal treatment with ammonia solution offers a simple and feasible method for preparing Cr(VI) adsorbents.
Article
Engineering, Chemical
Wei Li, Lanfang Chai, Boyu Du, Xiaohong Chen, Run-Cang Sun
Summary: In this study, a high hydroxyl content demethylated alkaline lignin (DAL) was successfully prepared as a full-lignin-based adsorbent for the efficient removal of Cr(VI) ions from wastewater. The adsorption capacity for Cr(VI) was up to 703.6 mg/g at 30 degrees C, and the adsorption process was determined to be endothermic and spontaneous. The spent adsorbents revealed that the adsorption may be driven by the reduction of negatively charged Cr2O72- or HCrO4- ions to positively charged Cr3+, which could interact with the oxygen-containing groups in lignin.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Article
Environmental Sciences
Liyin Li, Gang Cao, Rongshu Zhu
Summary: In this study, a modified magnetic litchi shell adsorbent (MMLS) was synthesized for removing Cr(VI) from industrial effluents, showing good adsorption performance and reusability. The research also revealed the competitive adsorption between Cr(VI) and coexisting ions, with negligible interaction in actual chrome-plated rinse water. The study confirmed chemisorption as a rate-limiting step and the complexity of the adsorption behavior of MMLS according to Sips model.
ENVIRONMENTAL RESEARCH
(2021)
Article
Chemistry, Applied
Mojtaba Safaviyan, Mehdi Faramarzi, Seyed Aboutaleb Mousavi Parsa, Hajir Karimi
Summary: In this study, a novel Cr(VI) adsorbent, TEPA-enriched MGO, was developed and characterized. The optimal parameters for Cr(VI) sorption, including Cr(VI)/MGOT ratio, temperature, and pH, were determined through Box-Behnken Design. The maximum adsorption capacity was found to be 287.15 mg/g. The Lagergren kinetic and Langmuir isotherm models accurately represented the adsorption process on MGOT. Based on the obtained results, MGOT was identified as an excellent reusable adsorbent for selective Cr(VI) sorption and magnetic separation from wastewater.
REACTIVE & FUNCTIONAL POLYMERS
(2022)
Article
Environmental Sciences
Yi Fang, Ke Yang, Yipeng Zhang, Changsheng Peng, Aurora Robledo-Cabrera, Alejandro Lopez-Valdivieso
Summary: The efficiency of Cr(VI) removal by ballmilled highly activated carbon (HAC) under neutral conditions was significantly improved due to the increased content of surface acid functional groups. Two mechanisms for Cr(VI) removal were proposed, involving reduction of Cr(VI) to Cr(III) and formation of chromium hydroxides on the surface of HAC, as well as bonding of CrO42- on the surface COOH groups.
ENVIRONMENTAL RESEARCH
(2021)
Article
Engineering, Environmental
Shan Liu, Lei Cao, Xincheng Tian, Xuanni Li, Lei Liao, Chunpeng Zhao
Summary: The modified chitosan compound CS-Fe-SLS showed excellent adsorption capacity for Cr(VI), with optimal pH at 3.0 and equilibrium reached in 120 minutes. Both physical and chemical processes were involved in the adsorption, with single-layer and multi-layer adsorption observed.
WATER SCIENCE AND TECHNOLOGY
(2021)
Article
Materials Science, Multidisciplinary
Hang Zhang, Rong Ma, Yuhang Yang, Lili Huang, Nanchun Chen, Qinglin Xie
Summary: This study successfully synthesized a diatom-based Cr(VI) ion-imprinted adsorbent material, which showed promising results in removing Cr(VI) ions from wastewater.
Article
Green & Sustainable Science & Technology
Yingnan He, Jianbing Chen, Jiapei Lv, Yimin Huang, Shuxing Zhou, Wenyan Li, Yongtao Li, Fengqin Chang, Hucai Zhang, Thomas Wagberg, Guangzhi Hu
Summary: The study of composite alginate gel beads with Eichhornia crassipes biochar and polyethyleneimine as a surface modifier for adsorbing Cr(VI) showed promising results, indicating high adsorption capacity and potential for wastewater treatment.
JOURNAL OF CLEANER PRODUCTION
(2022)
Article
Biotechnology & Applied Microbiology
Juan Manuel Galdoporpora, Sofia Municoy, Fatima Ibarra, Virginia Puente, Pablo Edmundo Antezana, Maria Ines Alvarez Echazu, Martin F. Desimone
Summary: This study successfully obtained copper and zinc nanostructures using yerba mate extract as a reducing and capping agent. By adjusting salt concentration and temperature, the morphology of the nanostructures was tuned. The nanomaterials exhibited antimicrobial and antioxidant activities, highlighting their potential applications in various fields.
CURRENT NANOSCIENCE
(2023)
Article
Polymer Science
Maria I. Alvarez Echazu, Maria E. Antona, Oriana Perna, Christian E. Olivetti, Gisela S. Alvarez, Elisa V. Macri, Claudio J. Perez, Marina Czerner, Silvia M. Friedman, Martin F. Desimone
Summary: Chitosan hydrogels modified by DDSA exhibit improved mechanical properties and cytotoxicity. Incorporation of thymol shows antimicrobial and antioxidant activities. The study suggests that DDSA-chitosan hydrogels could be promising for the sustained local delivery of hydrophobic drugs.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Review
Biochemistry & Molecular Biology
Maria I. Alvarez Echazu, Oriana Perna, Christian E. Olivetti, Pablo E. Antezana, Sofia Municoy, Maria V. Tuttolomondo, Juan M. Galdoporpora, Gisela S. Alvarez, Daniel G. Olmedo, Martin F. Desimone
Summary: Synthetic and natural biomaterials show promise as alternatives for treating critical-sized bone defects by mimicking the bone microenvironment. This review discusses recent advances in mimicking the native structure of bone and manufacturing biomaterial candidates using synthetic and natural biomaterials.
MACROMOLECULAR BIOSCIENCE
(2022)
Article
Pharmacology & Pharmacy
Pablo Edmundo Antezana, Sofia Municoy, Maria Ines Alvarez-Echazu, Pablo Luis Santo-Orihuela, Paolo Nicolas Catalano, Taleb H. Al-Tel, Firoz Babu Kadumudi, Alireza Dolatshahi-Pirouz, Gorka Orive, Martin Federico Desimone
Summary: This review discusses the latest developments in skin tissue engineering using 3D bioprinting as a new tool. It provides an overview of current bioprinting methods and summarizes bioink formulations, parameters, and properties. Representative examples and advances in the field, as well as limitations and future needs, are also discussed.
Article
Chemistry, Multidisciplinary
Prashant B. Chouke, Ajay K. Potbhare, Nitin P. Meshram, Manoj M. Rai, Kanhaiya M. Dadure, Karan Chaudhary, Alok R. Rai, Martin F. Desimone, Ratiram G. Chaudhary, Dhanraj T. Masram
Summary: This study demonstrates the green fabrication of nickel oxide nanoparticles using Cleome simplicifolia and investigates their in vitro toxicity in Bm-17 and Labeo rohita liver cells. The bioinspired NiO NPs were characterized and shown to have a crystalline structure. The toxic effects of NiO NPs were evaluated in cells, and it was found that higher concentrations resulted in more severe toxicity. Similar effects were observed in Labeo rohita liver cells.
Article
Chemistry, Physical
Chetna C. Chauhan, Tanuj Gupta, Sher Singh Meena, Martin F. Desimone, Avik Das, Charanjeet Singh Sandhu, Kanti R. Jotania, Rajshree B. Jotania
Summary: SrFe12O19 and NiFe2O4 nano ferrite powders were synthesized using Calotropis gigantea flower extract, and SrFe12O19/NiFe2O4 nanocomposites were prepared. The effects of different weight ratios on the structural, magnetic, and electrical properties were investigated. The results showed that as the amount of spinel phase increased, the crystallite size decreased, and the saturation magnetization and coercivity decreased.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Review
Medicine, Research & Experimental
Saman Sargazi, Zahra Ahmadi, Mahmood Barani, Abbas Rahdar, Soheil Amani, Martin F. Desimone, Sadanand Pandey, George Z. Kyzas
Summary: Infertility is a widespread disorder that affects both male and female reproductive systems. Advances in nanomedicine have greatly contributed to the diagnosis and treatment of infertility. Nanoscience has been utilized to improve the detection of infertility-related biomarkers and various nanostructures have shown promising outcomes in the treatment of infertility. However, some nanostructures may have toxic effects on cells, especially germ cells, and thus require optimization.
Review
Pharmacology & Pharmacy
Izeia Lukin, Itsasne Erezuma, Lidia Maeso, Jon Zarate, Martin Federico Desimone, Taleb H. Al-Tel, Alireza Dolatshahi-Pirouz, Gorka Orive
Summary: Tissue engineering has become a viable medical alternative in response to the increasing lifespan of society. This review focuses on gelatin, a widely used biomaterial in tissue engineering, and discusses ongoing concerns and the latest developments in this field. Advancements in technology, such as 3D bioprinting and gelatin functionalization, have allowed for better replication of native tissue in gelatin-based systems. This breakthrough has implications for both the manufacturing process, making it more practical and cost-effective, and the future use of gelatin in disease detection and diagnosis rather than treatment.
Review
Biotechnology & Applied Microbiology
Ilaria Corsi, Martin Federico Desimone, Jimena Cazenave
Summary: Nanotechnologies have rapidly developed and are considered the new industrial revolution. The production and applications of engineered nanomaterials (ENMs) and nanoparticles (NPs) have led to environmental exposure with health consequences. This article reviews the critical characteristics of ENM/Ps and highlights the importance of safety by design in reducing potential toxicological risks.
FRONTIERS IN BIOENGINEERING AND BIOTECHNOLOGY
(2022)
Article
Materials Science, Ceramics
Chetna C. Chauhan, Abhishek A. Gor, Tanuj Gupta, Martin F. Desimone, Neha Patni, Rajshree B. Jotania
Summary: M-type calcium hexaferrite (CaM) was synthesized using extracts from Azadirachta indica and Murraya koenigii leaves, and the presence of phytochemicals in the extracts was found to significantly influence the properties of CaM hexaferrites. The study provides insights into the structural, optical, magnetic, and dielectric characteristics of CaM hexaferrites synthesized via a greener route.
CERAMICS INTERNATIONAL
(2022)
Review
Pharmacology & Pharmacy
Fresia Melina Silva Sofras, Martin Federico Desimone
Summary: Cannabis sativa L. has a long history of being used as medicine. The medicinal properties of this plant are attributed to cannabinoids, terpenes, and flavonoids. The full-spectrum plant extracts, which contain a combination of these compounds, have shown superior medicinal effects compared to isolated compounds like CBD or THC. Chromatography methods, such as HPLC and GC, are widely used for the analysis of cannabis components. Standardized protocols and quality control policies are necessary for a comprehensive analysis of cannabis extracts and derivatives.
CURRENT PHARMACEUTICAL DESIGN
(2023)
Article
Pharmacology & Pharmacy
Luis A. Villarruel, Belen Brie, Sofia Municoy, Damasia Becu-Villalobos, Martin F. Desimone, Paolo N. Catalano
Summary: The study evaluated silica nanoparticles and silica-collagen nanocomposites for the loading and release of recombinant human growth hormone (hGH). The results showed that bare nanoparticles had higher hGH adsorption capacity compared to thiol- and isobutyl-bearing particles of similar sizes. Incorporating the protein-loaded particles into collagen matrices resulted in a progressive and prolonged hGH release profile, suggesting the potential use of biocompatible silica-collagen nanocomposites for reducing the number of periodic hGH administrations.
INTERNATIONAL JOURNAL OF PHARMACEUTICS
(2023)
Article
Infectious Diseases
Sofia Municoy, Pablo Edmundo Antezana, Martin Gonzalo Bellino, Martin Federico Desimone
Summary: UV irradiation method was used to in situ synthesize silver nanoparticles (AgNPs) within 3D-printed collagen-based scaffolds. The size and shape of AgNPs were controlled by modifying the concentration of AgNO3 and UV irradiation time. The results showed that AgNPs stabilized the scaffolds and improved the swelling capacity of collagen, and exhibited high bactericidal efficiency against both Gram-negative and Gram-positive bacteria.
Article
Pharmacology & Pharmacy
Fresia Melina Silva Sofras, Rosario Alonso, Daiana Sabrina Retta, Paola Di Leo Lira, Martin Federico Desimone, Catalina Maria van Baren
Summary: This study developed and validated a simple and rapid HPLC-UV method for the identification and quantification of principal cannabinoids in cannabis products. The method was found to have comparable performance to more sophisticated analytical instruments for cannabinoid analysis. The method exhibited linear concentration-response relationship with R^2 values greater than 0.99 for all 7 cannabinoids.
CURRENT PHARMACEUTICAL DESIGN
(2023)
Review
Materials Science, Biomaterials
Romina Mitarotonda, Exequiel Giorgi, Tatiane Eufrasio-da-Silva, Alireza Dolatshahi-Pirouz, Yogendra Kumar Mishra, Ali Khademhosseini, Martin F. Desimone, Mauricio De Marzi, Gorka Orive
Summary: The development of nanoparticles for therapeutic purposes, especially vaccines, has shown significant progress in recent years. Targeted delivery of vaccines through nanotechnology is expected to increase the immune response potential in the future. Ultimately, nanotechnology will be the foundation for future immunotherapy.
BIOMATERIALS ADVANCES
(2022)