4.3 Article

Facile Hg2+ detection in water using fluorescent self-assembled monolayers of a rhodamine-based turn-on chemodosimeter formed via a click reaction

期刊

JOURNAL OF MATERIALS CHEMISTRY
卷 21, 期 29, 页码 10878-10882

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1jm11319d

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资金

  1. National Natural Science Foundation of China [20971066, 20721002, 20705012]
  2. Program for New Century Excellent Talents in University [NCET-08-0272]
  3. Major State Basic Research Development Program [2011CB808704, 2007CB925103]
  4. Japanese Ministry of Education, Culture, Sports, Science, and Technology (MEXT) [20108007]

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A 'click reaction' is used to synthesise a fluorescent self-assembled monolayer, which can be used to detect Hg2+ in both water and organic solutions. The resulting fluorescence sensor exhibits a rapid response and high sensitivity to Hg2+ due to the synergy effect between the nitrogens of a triazole group and a rhodamine moiety. The sensing properties are stable over a wide pH range in aqueous solutions.

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