期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 21, 期 4, 页码 1058-1063出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0jm02799e
关键词
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资金
- MICINN of Spain [CTQ2009-07881/BQU]
- Consolider Ingenio [CSD2007-00006]
- Generalitat de Catalunya [SGR2009-01441]
- CNANO
- CNRS
Hollow or dense silica spheres were synthesized by the hydrolysis-condensation of tetraethoxysilane templated by an ionic liquid crystal. A hydrolysable silylated analog of these ionic liquid crystals was also submitted to a sol-gel reaction in a binary toluene-water mixture, yielding hybrid vesicles. All the materials were fully characterized by solid state NMR, FTIR, electron microscopies, N-2 adsorption-desorption measurements, and their mechanism of formation was assessed thanks to in situ optical microscopy studies.
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