Article
Biotechnology & Applied Microbiology
Paula Valeria Viotti, Wardleison Martins Moreira, Henrique Straioto, Rosangela Bergamasco, Mara Heloisa Neves Olsen Scaliante, Marcelo Fernandes Vieira
Summary: This study investigates the modification of natural zeolite to enhance its ability to remove drugs and pesticides from water. The hydrothermal treatment with surfactant (CTAB) results in a structural rearrangement of the zeolite, making it more hydrophobic with a smaller specific area and a higher porosity. The modified zeolite exhibits significantly increased removal of the evaluated contaminants. The study concludes that hydrothermal modification with CTAB is a promising technique for using natural zeolites in the removal of emerging contaminants.
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY
(2022)
Article
Chemistry, Multidisciplinary
Bhaskar Parida, Saemon Yoon, Dong-Won Kang
Summary: By using a bilayer TE consisting of ITO nanoparticles (ITO-NPs) and Ag nanowires (Ag-NWs) processed in ambient air at room temperature, superior characteristics and higher power conversion efficiency can be achieved compared to sputtered ITO. This new type of TE could pave the way for the development of low-cost, translucent solar cells with quick processing under ambient air at room temperature.
Article
Materials Science, Multidisciplinary
Brandon Ortiz-Casas, Andres Galdamez-Martinez, Jorge Gutierrez-Flores, Andres Baca Ibanez, Pritam Kumar Panda, Guillermo Santana, Horacio Astudillo de la Vega, Mrutyunjay Suar, Citlaly Gutierrez Rodelo, Ajeet Kaushik, Yogendra Kumar Mishra, Ateet Dutt
Summary: 0D and 1D zinc oxide (ZnO) show promise as bioapplications in the fields of cancer diagnosis and treatment, offering high performance, biological compatibility, and the ability to identify molecular features of cancer biomarkers. Their use as sensors and treatment tools has the potential to revolutionize cancer diagnostics and patient health monitoring.
Article
Chemistry, Multidisciplinary
Peng Li, Guojing Xu, Nannan Wang, Bo Guan, Shuiqing Zhu, Penglei Chen, Minghua Liu
Summary: The study demonstrates the fabrication of 0D, 1D, and 2D supramolecular nanostructures of porphyrin via a reprecipitation protocol, with spherical, fibrous, and sheetlike architectures respectively. These nanostructures show promising optoelectronic performances as photocatalysts for water remediation, with nanofibers exhibiting the highest catalytic reactivity.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Yogesh A. Sethi, Aniruddha K. Kulkarni, Anuradha A. Ambalkar, Supriya K. Khore, Aarti R. Gunjal, Suresh W. Gosavi, Bharat B. Kale
Summary: Constructing a CdS decorated MnWO4 nanoheterostructure via a facile hydrothermal method leads to efficient spatial separation of photogenerated electron-hole pairs and direct Z-scheme electron transfer, significantly enhancing photocatalytic hydrogen generation. The CdS@MnWO4 narrow band gap semiconductor exhibits a 21-fold increase in hydrogen production efficiency compared to pristine MnWO4, demonstrating great potential for solar to direct fuel conversion efficiency improvement.
NANOSCALE ADVANCES
(2021)
Article
Chemistry, Multidisciplinary
Aninamol Ani, P. Poornesh, Albin Antony, K. K. Nagaraja, Ashok Rao, Gopalkrishna Hegde, Evgeny Kolesnikov, Igor Shchetinin, Suresh D. Kulkarni, Vikash Chandra Petwal, Vijay Pal Verma, Jishnu Dwivedi
Summary: The study investigated the influence of electron beam on CO gas sensing properties of indium-doped zinc oxide (IZO) thin films, showing that the structural changes and grain boundary variations after irradiation significantly affect the sensing performance. The enhancement in sensor response post-irradiation is attributed to the increase in oxygen vacancies and well-defined grain boundaries, which serve as crucial adsorption sites for CO gas.
Article
Engineering, Environmental
Lele Wang, Guogang Tang, Song Liu, Huilong Dong, Qinqin Liu, Jingfang Sun, Hua Tang
Summary: The hydrogen evolution activity of photocatalysts was optimized by constructing a 0D/1D Co3O4/TiO2 heterojunction, which exhibited excellent performance due to the porous outer-walls, favorable interface contact, built-in electric field, and cocatalytic effect leading to rapid charge carrier migration. This study provides an important guideline for designing surface-engineered heterostructures in photocatalytic applications.
CHEMICAL ENGINEERING JOURNAL
(2022)
Review
Chemistry, Physical
Tingting Zhou, Tong Zhang
Summary: With the advancement of nanoscience and nanotechnology, nanomaterials with unique properties have gained more attention in the field of electronic sensors, especially in gas sensing devices. Recent achievements have led to a new wave of research in designing advanced sensing materials with different dimensional structures. The sensitivity and performance of these materials are closely related to their structure, electronic properties, and surface chemistry, influencing various gas sensing applications such as environmental monitoring and flexible wearable electronics.
Article
Chemistry, Physical
Zhe Zou, Mingqiang Ning, Zhenkuang Lei, Xueheng Zhuang, Guoguo Tan, Jianhua Hou, Hui Xu, Qikui Man, Jingbo Li, Run-Wei Li
Summary: Co@C/MXene-based composite materials with 0D/1D/2D architectures were fabricated to enhance microwave attenuation performance and optimize impedance matching properties. The Co@C/M-10 absorber exhibited excellent microwave attenuation performance and wide absorption bandwidth under specific thickness.
Article
Materials Science, Multidisciplinary
Junnian Chen, Xingfu Xiao, Yue Chen, Mingkai Li, Wenyu Fang, Zixian Yu, Biqi He, Tianyou Zhai, Yunbin He
Summary: This study reports a method of modulating the structural distortion by steric hindrance effects to change the morphology of bismuth bromide chains. By interacting with bismuth bromide, N,N,N & PRIME;,N & PRIME;-tetramethyl-1,4-phenylenediammonium (TMPD)(2+) is used to template regular BiBr5 chains, resulting in a narrow-bandgap mixed 0D/1D (TMPD)(2)(Bi2Br10H2O)-H-. This finding offers new insights into developing narrow-bandgap perovskite hydrates for practical optoelectronic applications.
ADVANCED OPTICAL MATERIALS
(2023)
Article
Chemistry, Physical
Yuanyuan Sun, Minghao Zhang, Xiaoming Mou, Caixia Song, Debao Wang
Summary: Metal chalcogenides face challenges in their application as visible-light-responsive photocatalysts due to fast recombination of charges and photo-corrosion. This study presents a rational design strategy to overcome these challenges by constructing S-scheme 1D/0D MCS/W heterojunction cauliflower-shaped assemblies. The resulting heterojunction showed enhanced visible light absorption, improved charge separation efficiency, and higher redox ability and long-term durability. The photocatalytic H-2 generation rate of the heterojunction assemblies was 25 times higher than that of the pristine MCS. This work provides deep insights into the rational construction of heterojunction assemblies for improved photocatalytic performance.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Engineering, Environmental
Jiahuan He, Ziwei Huang, Wenzheng Chen, Xuezhang Xiao, Zhendong Yao, Zhaoqing Liang, Liujun Zhan, Ling Lv, Jiacheng Qi, Xiulin Fan, Lixin Chen
Summary: A novel non-noble metal catalyst Co@Co2Mo3O8 with outstanding catalytic performance in the hydrolysis of ammonia borane (AB) has been proposed. The catalyst possesses a unique 0D/1D/2D spatial structure and abundant oxygen vacancies, which contribute to its excellent catalytic activity.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Inorganic & Nuclear
Liu De-Zheng, Yang Gao-Yuan, Xiang Wen-Hao, Wang Song, Li Wang-Nan, Zhong Jie, Huang Fu-Zhi, Chen Mei-Hua, Liang Gui-Jie
Summary: A novel 1D/0D ordered composite SnO2 nanocrystal electron transport layer (ETL) for pervoskite solar cells was prepared by adjusting the density of one-dimensional (1D) nanorod arrays and depositing zero-dimensional (0D) nanoparticles. The composite ETL showed excellent charge recombination inhibition and efficient electron extraction performance, contributing to improved photoelectric performance of the device.
CHINESE JOURNAL OF INORGANIC CHEMISTRY
(2021)
Article
Chemistry, Physical
Katarzyna Skibinska, Karolina Kolczyk-Siedlecka, Dawid Kutyla, Marta Gajewska, Piotr Zabinski
Summary: Copper and cobalt-iron 1D nanocones were successfully obtained using AAO templates through electrodeposition method. The Co-Fe nanostructures exhibited homogeneous pore distribution and were characterized for their electrocatalytic activity in 1 M NaOH solution. These materials can potentially serve as catalysts in water-splitting reaction, showing promising results when compared with bulk materials.
Article
Chemistry, Physical
Zhiwen Huang, Maria Luisa Ceron, Kehuai Feng, Dan Wang, Maria Belan Camarada, Xiaoning Liao
Summary: This study successfully constructs an efficient electrochemical sensor for ochratoxin A (OTA) detection by preparing a novel 0D/1D nanohybrid. The sensor shows high electrochemical activity and good antifouling effect, allowing for quantitative determination of OTA in a wide concentration range. It also demonstrates high reproducibility and satisfactory anti-interference ability, showing promise for trace-level analysis of OTA in agricultural crops.
APPLIED SURFACE SCIENCE
(2022)
Article
Chemistry, Physical
Pengfei Cao, Pengyi Tang, Maged F. Bekheet, Hongchu Du, Luyan Yang, Leander Haug, Albert Gili, Benjamin Bischoff, Aleksander Gurlo, Martin Kunz, Rafal E. Dunin-Borkowski, Simon Penner, Marc Heggen
Summary: By using a combination of in situ characterization techniques, we investigated the surface and bulk dynamics of LaNiO3 material during heating in vacuo, revealing the Ni exsolution dynamics on both local and global scales. The remaining perovskite grains exhibited a drastic shrinkage and compression of structure after the Ni exsolution, mainly occurring at grain boundaries and stacking faults.
JOURNAL OF PHYSICAL CHEMISTRY C
(2022)
Article
Chemistry, Multidisciplinary
Laura M. Henning, Ulla Simon, Amanmyrat Abdullayev, Bertram Schmidt, Carsten Pohl, Tamara Nunez Guitar, Cekdar Vakifahmetoglu, Vera Meyer, Maged F. Bekheet, Aleksander Gurlo
Summary: In this study, lab-cultivated mycelia and naturally grown fruiting bodies of Fomes fomentarius were investigated as biosorbents for the removal of organic dyes. The chemical and microstructural differences were revealed, showing the superiority of lab-cultivated mycelia. The results suggest that F. fomentarius can be considered as an attractive biosorbent in industrial wastewater treatment.
Article
Biochemistry & Molecular Biology
Qirong Chen, Franziska Schmidt, Oliver Goerke, Anila Asif, Joachim Weinhold, Erfan Aghaei, Ihtesham Ur Rehman, Aleksander Gurlo, Asma Tufail Shah
Summary: In this study, a photocurable resin based on bioactive glass (BAG) was prepared for additive manufacturing of BAG scaffolds. The influence of BAG on the physical properties of the resin and resulting 3D structures was investigated. The rheology and photocuring behavior of the resin, as well as the tomography of the resulting structures, were studied by varying the concentration of monomers, reactive diluent, light absorber, photoinitiator, non-reactive diluent, and BAG fillers. The optimal resin composition was found to be 55-60% BAG, 10% PEG-200, 1% PI, and 0.015% dye. The resulting green bodies exhibited dense glass scaffolds with good interlayer connection and surface finishing, indicating promising mechanical behavior. This study provides valuable insights for the preparation and optimization of high density glass/ceramic slurries for printing applications.
Review
Energy & Fuels
Xue Li, Ulla Simon, Maged F. Bekheet, Aleksander Gurlo
Summary: This review article discusses the progress and applications of various minerals in photocatalysis. Natural minerals, such as silicate and non-silicate minerals, offer cost-efficiency and can be hybridized with photocatalysts to produce synergistic effects. Silicate minerals, due to their unique structures and properties, can enhance adsorption capacity and photocatalytic activity. Non-silicate minerals can serve as catalyst supports and photocatalysts after modification. Dye-sensitized minerals have been proven to be superior photocatalysts. This work provides an overview of mineral-supported photocatalysts and explores the synergistic effects between different mineral substrates and photocatalysts, as well as the potential applications of natural minerals in photocatalysis.
Article
Chemistry, Inorganic & Nuclear
Franz Kamutzki, Maged F. Bekheet, Soren Selve, Felix Kampmann, Konrad Siemensmeyer, Delf Kober, Roland Gillen, Markus Wagner, Janina Maultzsch, Aleksander Gurlo, Dorian A. H. Hanaor
Summary: A novel sodium gadolinium pyroxene (NaGdSi2O6) was successfully synthesized and its crystal structure was determined. The sodium gadolinium pyroxene showed weak antiferromagnetic coupling, but no long-range magnetic order was observed above 2 K.
JOURNAL OF SOLID STATE CHEMISTRY
(2023)
Article
Engineering, Biomedical
Shumin Pang, Dongwei Wu, Aleksander Gurlo, Jens Kurreck, Dorian A. H. Hanaor
Summary: Additively manufactured hollow-strut bioceramic scaffolds offer a promising strategy for patient-tailored bone tissue engineering, providing pathways for nutrient and cell transport and promoting osseointegration and vascularization. This study presents a slurry based additive manufacturing approach for modified diopside bioceramics, producing hollow-strut scaffolds with diverse cross-sectional forms. Mechanical characterization showed that square outer cross-sections for hollow struts in woodpile scaffolds result in higher compressive strength compared to solid cylindrical strut scaffolds, despite lower density. Hollow struts in bioceramic scaffolds significantly enhance cell attachment and proliferation and have potential for new bone tissue formation. This work provides a controlled method for extrusion-based 3D printing of hollow strut scaffolds, enhancing functional and mechanical performance in bone tissue engineering scaffolds.
Article
Chemistry, Multidisciplinary
Aidin Nejadsalim, Najmeh Bashiri, Hamid Reza Godini, Rafael L. Oliveira, Asma Tufail Shah, Maged F. Bekheet, Arne Thomas, Reinhard Schomaecker, Aleksander Gurlo, Oliver Goerke
Summary: One-dimensional core-sheath nanofibers consisting of platinum-loaded ceria sheath on mesoporous silica core were successfully synthesized and used as catalysts for the reverse water gas shift reaction. The core-sheath nanofibers had a core diameter of 100-300 nm and a sheath thickness of 40-100 nm with a Pt loading of 0.5 wt.%. The impregnated catalyst, Pt-CeO2 NF@mesoporous SiO2, showed the best catalytic performance with a CO2 conversion of 8.9% at 350 degrees C.
Review
Chemistry, Physical
Celal Avcloglu, Suna Avcloglu, Maged F. Bekheet, Aleksander Gurlo
Summary: This critical review summarizes the recent progress in modifying strontium titanate (SrTiO3) photocatalyst for overall water splitting applications. Different modification techniques, including cocatalyst loading, crystal-facet engineering, reduction of bulk defects, heteroatom doping, and constructing Z-Scheme water splitting systems, are discussed. The development of photocatalyst sheets and panel reactors for large-scale hydrogen generation and current challenges in solar hydrogen generation by SrTiO3 photocatalyst are also addressed.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Chemistry, Physical
Oleksandr Ovsianytskyi, Maged F. Bekheet, Albert Gili, Aleksander Gurlo
Summary: The sensing response of metal oxides activated with noble metal nanoparticles is affected by changes in the chemical state of the elements. In this study, a PdO/rh-In2O3 gas sensor was investigated for H2 gas detection. The composition and chemical state of elements were examined during operation. It was found that the sensor showed a series of structural and chemical transformations, leading to a decrease in sensing response.
Article
Chemistry, Physical
Leander Haug, Christoph Thurner, Maged F. Bekheet, Kevin Ploner, Benjamin Bischoff, Aleksander Gurlo, Martin Kunz, Bernhard Sartory, Simon Penner, Bernhard Kloetzer
Summary: To investigate the synergistic action of differently prepared Ni-ZrO2 phase boundaries in methane dry reforming, three catalyst systems including an inverse near-surface intermetallic NiZr catalyst precursor, bulk-intermetallic NixZry material, and a supported Ni-ZrO2 catalyst were compared. All three catalysts exhibit stable and highly efficient methane dry reforming activity with improved resistance to coke deposition due to the presence of extended Ni-ZrO2 phase boundaries formed by in situ activation. Methane is decomposed to carbon at metallic Ni-0 surface sites, while CO2 is converted to CO at reduced Zr centers at the phase boundaries. The surface-ZrO2 modified bulk Ni-0 catalyst shows the best decoking and carbon conversion conditions, attributed to the dispersed ZrO2 islands and short diffusion pathways for carbon.
Article
Polymer Science
Fabian Zemke, Julien Gonthier, Ernesto Scoppola, Ulla Simon, Maged F. F. Bekheet, Wolfgang Wagermaier, Aleksander Gurlo
Summary: Ambient pressure drying (APD) has the potential to reduce the cost of aerogel fabrication. This study investigates the effect of different silylation agents on the re-expansion of SiO2 aerogels after drying. The results show that while some physical properties were significantly affected by re-expansion, silylation did not always result in full re-expansion. The impact of silylation in tailoring the re-expansion behavior is crucial for APD of monolithic aerogels.
Article
Chemistry, Multidisciplinary
Wuqi Guo, Oyku Icin, Cekdar Vakifahmetoglu, Delf Kober, Aleksander Gurlo, Maged F. Bekheet
Summary: Tin-containing silicon oxycarbide nanobeads are synthesized and tested as anode for magnesium-ion batteries. The battery performance is influenced by surface area and tin content of the nanobeads. The silicon oxycarbide nanobeads enhance cycling stability and capacity, while higher tin content improves rate performances.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Pharmacology & Pharmacy
Veli Cengiz Ozalp, Samet Ucak, Ali D. Dursun, Mert Sudagidan, Oyku Icin, Cekdar Vakifahmetoglu, Laura M. Henning, Ulla Simon, Aleksander Gurlo
Summary: Different types of ordered mesoporous silica (OMS) nanoparticles, including COK-12 and modified COK-12, have been used as drug carriers for controlled drug adsorption and release. Cytotoxicity analysis showed that regular COK-12 particles had lower harm to mammalian cultured cells compared to other OMS nanoparticles. Regular COK-12 was further used as a carrier for a dual antibiotic-loaded drug delivery material, which showed enhanced antibiotic treatments against methicillin-resistant Staphylococcus strains through aptamer targeting.
JOURNAL OF DRUG DELIVERY SCIENCE AND TECHNOLOGY
(2023)
Article
Materials Science, Ceramics
Haotian Yang, Sophie Klemm, Julian Mueller, Maged F. Bakheet, Aleksander Gurlo, Dorian A. H. Hanaor
Summary: Three compositions of high-entropy carbides were synthesized using a modified Pechini process and citric acid as a cation chelating agent and carbon source. Single phase high-entropy carbides were formed through pyrolysis and spark plasma sintering at a relatively low temperature of 1800 degrees C. The dispersion of cations in the polymer precursor resulted in improved compositional homogeneity and a finer microstructure in the polymer-derived materials, leading to enhanced fracture toughness with a K-IC value of 4.29 MPa.m(1/2) achieved for (TiHfVNbTa)C.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Laura M. Henning, Julian T. Mueller, Glen J. Smales, Brian R. Pauw, Johannes Schmidt, Maged F. Bekheet, Aleksander Gurlo, Ulla Simon
Summary: This study investigates the effects of different sintering techniques on the preparation of lightweight micro-/meso-/macroporous monoliths from ordered mesoporous silica. The results show that spark plasma sintered monoliths exhibit higher mechanical properties and good permeability, making them suitable for various filtration and separation applications.
NANOSCALE ADVANCES
(2022)