4.5 Article

Structural and magnetic properties of CoTiO3 thin films on SrTiO3 (001)

期刊

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jmmm.2012.12.017

关键词

Cobalt titanate; Pulsed laser deposition; Antiferromagnetism

资金

  1. ERC Advanced Investigator (NOVOX) [247276]
  2. European Research Council (ERC) [247276] Funding Source: European Research Council (ERC)

向作者/读者索取更多资源

CoTiO3 (CTO) thin films were grown on single crystal SrTiO3 (STO) (001) substrates by pulsed laser deposition, with thicknesses ranging between 2.6 and 25 nm. Two-dimensional growth is observed up to a thickness of 2 unit cells, but then the film partially relaxes with CTO [100] oriented parallel to STO [110] and CTO [001] oriented parallel to the STO [001]. Magnetic characterization of our films revealed an enhancement of the antiferromagnetic Neel temperature (to similar to 53 K) when compared to the bulk (38 K). This is attributed to a tensile c-axis strain as evidenced from x-ray diffraction measurements. (C) 2012 Elsevier B.V. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.5
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Physics, Applied

Quenched Disorder-Controlled Resistive Relaxation in Near-Half-Doped Manganite Systems

M. Egilmez, S. T. Mahmud, H. S. Alagoz, I Zivkovic, J. A. Jung, K. H. Chow

Summary: The study investigated the influence of disorder on resistive relaxation effects in the Sm1-aSraMnO3 system, finding that different routes of disorder introduction lead to varied behaviors of Tc and T-MIT. The strength of disorder can be quantified by the difference in metal-insulator transition temperature. The observations revealed a clear relationship between quenched disorder and resistive metastability in manganites.

JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM (2022)

Article Materials Science, Multidisciplinary

Preparation of β-CuGaO2 thin films by ion-exchange of β-NaGaO2 film fabricated by a solgel method

T. Fix, J-L Rehspringer, S. Roques, A. Slaoui

Summary: In this study, attempts were made to grow beta-CuGaO2 films using different methods, and the potential of these films for photovoltaic applications was investigated. It was found that while beta-CuGaO2 is a suitable photon absorber, the discontinuity of the films is detrimental to electronic transport, requiring additional dopants to enhance its optoelectronic properties and charge carrier transport.

EMERGENT MATERIALS (2023)

Article Chemistry, Physical

Strange Metallicity and Magnetic Order in the CoNi(Cr/V) Medium-Entropy Alloy System

Faisal Mustafa, Mehmet Egilmez, Wael Abuzaid, Sami El-Khatib, Tahir Nawaz, Shahbaz Ahmad, Serhat Alagoz

Summary: CoNiCr is a prototype alloy with superior cryogenic and high-temperature mechanical strength, corrosion, oxidation resistance, and yet-to-be-explored magnetic and electronic functionalities. The remarkable properties of this ternary system result from atomic radii, electronic configurational mismatch, atomic volume misfit, and magnetically driven chemical short-range order. The study investigates the electric and magnetic properties of a single-phase CoNi(Cr/V) system, where V is introduced to fine-tune the volume misfit. The samples exhibit ultra-small magnetic moments and a strange metallicity revealed through the observation of linear temperature dependence of resistivity.

MATERIALS (2023)

Article Physics, Applied

The influence of thermal cycling on the activation energy of conduction electrons and filament temperature in Pt/NiOx/Pt ReRAMs

H. S. Alagoz, M. Egilmez, J. Jung, K. H. Chow

Summary: We studied the electrical and thermal conduction properties of Pt/NiOx/Pt based unipolar ReRAM devices in low- (ON) and high-resistance (OFF) states during cooling and warming cycles between 300 and 180 K. The activation energy of conduction electron-trap decreased upon warming. Thermal cycling didn't significantly affect the average resistance-temperature coefficient of the Pt diffused conductive filaments, but it increased the ON-state resistance fluctuations at high temperatures, indicating the influence of ambient temperature on the sizes of formed filaments. The mechanism behind these thermally activated changes is discussed.

APPLIED PHYSICS LETTERS (2023)

Article Chemistry, Physical

Tunability of silicon clathrate film properties by controlled guest-occupation of their cages

Romain Vollondat, Daniel Stoeffler, Daniele Preziosi, Stephane Roques, Abdelilah Slaoui, Thomas Fix

Summary: Type I and type II silicon clathrates are unique structures that can accommodate guest atoms while maintaining the integrity of the overall structure. This property has applications in batteries, storage, and tuning the properties of silicon clathrate films.

JOURNAL OF CHEMICAL PHYSICS (2023)

Article Multidisciplinary Sciences

Moderate temperature deposition of RF magnetron sputtered SnO2-based electron transporting layer for triple cation perovskite solar cells

Y. Zakaria, B. Aissa, T. Fix, S. Ahzi, S. Mansour, A. Slaoui

Summary: Perovskite solar cells (PSCs) are currently facing challenges in terms of stability and scalability for potential commercialization. One solution is to develop a uniform, efficient, high quality, and cost-effective electron transport layer (ETL) thin film. In this study, we explore the composition, structure, chemical state, and electronic properties of SnO2 thin films deposited by reactive RF magnetron sputtering.

SCIENTIFIC REPORTS (2023)

Article Chemistry, Physical

Fabrication of High Surface Area TiO2-MoO3 Nanocomposite as a Photocatalyst for Organic Pollutants Removal from Water Bodies

Fatima Abla, Yehya Elsayed, Nedal Abu Farha, Khaled Obaideen, Ahmed A. Mohamed, Haesung Lee, Changseok Han, Mehmet Egilmez, Sofian Kanan

Summary: A nanocomposite of titanium (IV) oxide (TiO2) and molybdenum (VI) oxide (MoO3) was synthesized using a hydrothermal route. The successful formation of pure TiO2-MoO3 (Ti-Mo) nanocomposite was confirmed through detailed analyses. The Ti-Mo nanocomposite exhibited increased mesopores and enhanced water affinity compared to pure metal oxides. Photocatalytic degradation experiments showed that the Ti-Mo nanocomposite significantly enhanced the degradation of MB under both white LED and 302 nm UV light irradiation.

CATALYSTS (2023)

Article Chemistry, Physical

Insights on CaTiS3 films grown by pulsed laser deposition

T. Fix, S. Raissi, D. Muller, C. Bouillet, D. Preziosi, A. Slaoui

Summary: We attempted to grow perovskite CaTiS3 using pulsed laser deposition (PLD) on various substrates with a CaS:TiS2 target. The results showed the transfer of sulfur from the target to the film when grown in vacuum at moderate temperature. However, the desired CaTiS3 phase could not be obtained, suggesting a phase governed by van der Waals interactions. The films exhibited highly doped n-type semiconductor behavior without a surface photovoltage signal. This work should inspire further experimental efforts in PLD growth of chalcogenides and chalcogenide perovskites.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Article Multidisciplinary Sciences

Simultaneous bright- and dark-field X-ray microscopy at X-ray free electron lasers

Leora E. Dresselhaus-Marais, Bernard Kozioziemski, Theodor S. Holstad, Trygve Magnus Raeder, Matthew Seaberg, Daewoong Nam, Sangsoo Kim, Sean Breckling, Sungwook Choi, Matthieu Chollet, Philip K. Cook, Eric Folsom, Eric Galtier, Arnulfo Gonzalez, Tais Gorkhover, Serge Guillet, Kristoffer Haldrup, Marylesa Howard, Kento Katagiri, Seonghan Kim, Sunam Kim, Sungwon Kim, Hyunjung Kim, Erik Bergbaeck Knudsen, Stephan Kuschel, Hae Ja Lee, Chuanlong Lin, R. Stewart Mcwilliams, Bob Nagler, Martin Meedom Nielsen, Norimasa Ozaki, Dayeeta Pal, Ricardo Pablo Pedro, Alison M. Saunders, Frank Schoofs, Toshimori Sekine, Hugh Simons, Tim van Driel, Bihan Wang, Wenge Yang, Can Yildirim, Henning Friis Poulsen, Jon H. Eggert

Summary: The structures, strain fields, and defect distributions in solid materials significantly influence their mechanical and physical properties. Modern microstructural microscopy tools are limited to studying the near surface, while synchrotron X-ray diffraction and dark field X-ray microscopy (DFXM) can map internal structures but are time-consuming. This research extends DFXM to X-ray free electron lasers (XFELs), achieving higher resolution and faster imaging, and provides a comprehensive guide to the multi-modal ultrafast high-resolution X-ray microscope.

SCIENTIFIC REPORTS (2023)

Article Nanoscience & Nanotechnology

Low-temperature enhanced OFF-state telegraph noise in defect engineered ReRAMs

H. S. Alagoz, M. Egilmez, J. Jung, K. H. Chow

Summary: The off-state retention characteristics of Pt/NiOx-(Ar)/NiOx-(Ar + O-2)/Pt stacking resistive random access memory structures were investigated. The study found that the noise amplitude increases as the temperature decreases, and the application of forward and reverse biases leads to resistance jumps. These findings provide important insights into the thermally activated charge trapping/de-trapping phenomenon responsible for resistance fluctuations.

APL MATERIALS (2023)

Article Chemistry, Physical

Electrochemical Hydrogen Evolution Reaction Evaluation of CoNi(Cr/V) Medium-Entropy Alloys in an Acidic Environment

Shahbaz Ahmad, Mehmet Egilmez, Ramasamy Shanmugam, Wael Abuzaid, Shuchi Sharma, Ranga Rao Gangavarapu, Faisal Mustafa, Sami El-Khatib, Hussain Alawadhi, Arunachala M. Kannan

Summary: Developing nonprecious metal-based electrocatalysts with outstanding performance has been a major focus in the scientific community for the past decade. In this study, the electrocatalytic properties of equiatomic single-phase medium-entropy alloy electrodes with various compositions were investigated for the hydrogen evolution reaction. The results showed that the CoNi-(Cr/V) alloy exhibited the lowest overpotential and highest electrocatalytic activity, and all samples exhibited good stability.

ACS APPLIED ENERGY MATERIALS (2023)

Article Chemistry, Multidisciplinary

Intrinsic giant magnetoresistance due to exchange-bias-type effects at the surface of single-crystalline NiS2 nanoflakes

Roman Hartmann, Michael Hogen, Daphne Lignon, Anthony K. C. Tan, Mario Amado, Sami El-Khatib, Mehmet Egilmez, Bhaskar Das, Chris Leighton, Mete Atature, Elke Scheer, Angelo Di Bernardo

Summary: The coexistence of different properties in NiS2 nanoflakes, such as antiferromagnetic and weak ferromagnetic orders, along with surface metallicity, leads to strongly field-asymmetric magnetotransport features at low temperatures. These features are related to exchange-bias-type effects between ferromagnetic and antiferromagnetic regions forming near step edges at the nanoflake surface, which can be characterized using nitrogen vacancy magnetometry. The findings suggest that NiS2 nanoflakes have potential applications in van der Waals heterostructures for low-temperature spintronics and superconducting spintronics.

NANOSCALE (2023)

Article Materials Science, Multidisciplinary

Concurrent weak localization and double Schottky barrier across a grain boundary in bicrystal SrTiO3

M. Egilmez, S. El-Khatib, F. Mustafa, S. Ahmad, A. Di Bernardo, J. W. A. Robinson

Summary: Weak ferromagnetic and metallic transport phenomena were observed in oxygen-deficient bicrystal of Stoichiometric SrTiO3 (STO), and a disorder-induced metal-insulator transition was observed in magnetotransport across the grain boundary. This experimental study highlights the importance of structural defects in the interpretation of magnetotransport in SrTiO3.

PHYSICAL REVIEW B (2023)

Article Thermodynamics

New structure-performance relationships for surface-based lattice heat sinks

D. Padrao, D. Hancock, J. Paterson, F. Schoofs, C. Tuck, I. Maskery

Summary: This study numerically analyzed the hydraulic and thermal performance of five surface-based lattice structures and developed predictive models for pressure drop and volumetric heat transfer coefficients. The research found that the thermal performance of the surface-based lattices is dependent on the internal geometry, with structures capable of distributing thermal energy across the entire fluid volume having higher heat transfer coefficients.

APPLIED THERMAL ENGINEERING (2024)

Article Chemistry, Physical

Utilizing aluminum sheets with FeCu deposits as cheap water cleaning electrodes

Abdullah Abu Hawili, Mehdi Ghommem, Abdul Hai Alami, Shamma Alasad, Mehmet Egilmez, Wael Abu Zaid

Summary: This work investigates the synthesis and deposition of Fe-Cu bimetallic alloy on aluminum substrates for iron contaminants elimination in aqueous solutions. The coated aluminum electrodes showed promising magnetic and electrical transport properties. The transmission of the solution significantly increased from 20% to around 40% after the insertion of the electrodes, indicating the potential of this electrode as a cheap and recyclable paramagnet.

APPLIED SURFACE SCIENCE ADVANCES (2022)

Article Materials Science, Multidisciplinary

Remote detection of bovine serum albumin (BSA) using cantilever beam magnetometer

Bibhutibhusan Nayak, S. Narayana Jammalamadaka

Summary: This article presents a method for remote detection of bovine serum albumin (BSA) using modified cantilever beam magnetometry (CBM). By combining a magnetostrictive Fe70Ga30 cantilever with optical detection technique, researchers were able to detect high concentrations of BSA remotely. The results of this study demonstrate the potential of this method in estimating the magnetostriction of thin films.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

Influence of magnetic external field and particle size on the formation of a single domain state

Yu Hao, R. E. Camley, Z. Celinski

Summary: Magnetic particles have various applications and their magnetic state is determined by their size and the strength of an applied magnetic field. Numerical simulations were performed to study the effect of an applied field on the critical size of single-domain magnetic particles, and the critical field at which a particle becomes single-domain was determined.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

Smart nanocomposite SrFe12O19/α or γ - Fe2O3 thin films with adaptive magnetic properties

Nitesh Singh, Naresh Kumar, Dharohar Sahadot, Anil Annadi, Vidyadhar Singh, Murtaza Bohra

Summary: The unique magnetic properties of FM/AFM and hard-FM/soft-FM nanocomposite thin films have significant relevance for numerous applications. The composition and performance of different magnetic phases in the nanocomposite films can be significantly affected by the laser ablation conditions and annealing temperature.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

A symmetric T-H shape wideband negative index metamaterial for 28-GHz millimeter-wave applications

Alya Ali Musaed, Samir Salem Al-Bawri, Khaled Aljaloud, Wazie M. Abdulkawi, Mohammad Tariqul Islam, Mandeep Jit Singh, Zaini Sakawi, Husam Hamid Ibrahim

Summary: This research presents a wideband tunable metamaterial for body-centric applications in the millimeter-wave frequency band. The proposed metamaterial has a wide operating frequency range and enhanced gain, making it suitable for improving the antenna performance in 5G wireless communication systems.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

Structure and properties of NdCuGa3 single crystals

Binod K. Rai, Boris Maiorov, Krzysztof Gofryk, Patrick O'Rourke, Catherine Housley, Henry Ajo, Asraf Sawon, Arjun K. Pathak, Narayan Poudel, Qiang Zhang, Travis J. Williams, Matthias Frontzek

Summary: This manuscript reports on the structural and magnetic properties of NdCuGa3. The study confirmed the crystal structure and magnetic phase transition of NdCuGa3 using XRD, neutron diffraction, magnetization, and specific heat measurements. The neutron diffraction data further confirmed the antiferromagnetic phase of NdCuGa3.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

A multiferroic coupling mechanism in the polar interface region of GaN-ZnO heterojunction: A first-principle study

Haonan Li, Cong Li, Hailiang Huang, Guodong Hao, Fei Wang

Summary: The electronic structure and ferroelectric-ferromagnetic coupling properties of Y-doped and vacancy-containing GaN-ZnO heterojunctions are systematically investigated. The magnetism in vacancy-containing systems is generated by the spin polarization of unpaired electrons induced by cationic vacancies, while in Y-doped systems, bound magnetic polarons are formed by the orbital hybridization of s-state and d-state electrons of Y-doped elements.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

Co-precipitation method followed by ultrafast sonochemical synthesis of aluminium doped M type BaFe11.4-xAlxCo0.6O19 hexaferrites for various applications

Muhammad Ijaz, Hafeez Ullah, Bandar Ali Al-Asbahi, Mati Ullah Khan, Zaheer Abbas, Sana Ullah Asif

Summary: M-type BaFe11.4-xAlxCo0.6O19 hexaferrites with Al3+ substitutions were synthesized using the co-precipitation method followed by Sonochemical process. The synthesized materials were characterized using XRD, FTIR, UV-vis spectroscopy, VSM, SEM, and LCR meter. The results showed that aluminum doping decreased the band gap and enhanced the magnetic and dielectric properties of the hexaferrites, making them suitable for various applications.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

Magnons in the fan phase of anisotropic frustrated antiferromagnets

Oleg I. Utesov

Summary: The elementary excitations spectrum of anisotropic frustrated antiferromagnets in the fan phase is discussed. It is found that the low-energy part of the spectrum consists of a gapless phason branch with linear dispersion and a gapped optical branch corresponding to the fan structure amplitude oscillations. In the high-energy part of the spectrum, the excitations are similar to the magnons of the fully polarized phase.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

Vapor bubbles departure frequency at ferrofluid boiling on a single nucleation site in a uniform horizontal magnetic field

Alexander Ya. Simonovskii, Alexander A. Yanovskii, Arthur R. Zakinyan

Summary: In this study, the departure frequency of vapor bubbles during boiling of ferrofluid in a horizontal magnetic field is experimentally investigated. Two methods, visual and inductive, are used to measure the frequency of bubble departure. The results show that the bubble departure frequency can decrease with increasing magnetic field strength and increase with increasing temperature of the heat-emitting surface. A linear stability analysis is conducted to analyze the influence of the magnetic field on the frequency of bubble formation during ferrofluid boiling.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

Magnetic and transformation properties of Ni2MnGa combinatorically substituted with 5 at.% of transition elements from Cr to Cu - Experimental insight

Oleg Heczko, Michal Rames, Vit Kopecky, Petr Vertat, Michal Varga, Ladislav Straka

Summary: Heusler Ni-Mn-Ga alloys are multiferroic materials that exhibit magnetic shape memory (MSM) phenomena. By doping transition elements into Ni2MnGa alloys, the transformation temperatures can be modified and complex behaviors can be observed, such as the variation in saturation magnetization and the effects of elemental substitution on compound properties.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

DFT calculations for electronic and magnetic properties of full Heusler Fe2MnAs alloy in perfect and defect structures

Carlos Ariel Samudio Perez, Ariel Flaig de Marchi

Summary: This study investigates the electronic and magnetic properties of the Full-Heusler Fe2MnAs alloy using first-principles calculations. The alloy may form spontaneously and exhibits a ferromagnetic order and high spin-polarization. It can be transformed into a half-metal by contracting the lattice constant. Additionally, certain defects contribute to the spin-polarization of the alloy, making it a fully half-metallic material.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

Enhancing electromagnetic properties through carbon Nanotube-Based polymer composites

Satish Geeri, Aditya Kolakoti, Prasadarao Bobbili

Summary: In this study, an electromagnetic wave-absorbing material was fabricated using a polymer composite material with fiber orientation and Multiwall Carbon Nanotubes as filler materials, along with a Perfect Electric Conducting material. The experiments demonstrated strong electromagnetic absorbing properties for the composites with PEC-coated and non-PEC-coated materials. Mechanical, thermal, and morphological analysis confirmed the similar trend in properties. CRITIC analysis helped identify the sequence order of sustaining properties for the fabricated composites.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

First-principles prediction of intrinsic piezoelectricity, spin-valley splitting and magneto-crystal anisotropy in 2H-VS2 magnetic semiconductor

Yankai Chen, Ruoxue Zhang, Yukai An

Summary: The piezoelectricity, valley character, and magnetic properties of 2H-VS2 monolayer were studied, revealing its potential applications in spintronics and valleytronics due to its bipolar magnetic semiconductor characteristics and superior physical properties.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

Thermodynamic, entanglement and spin Hall conductivity on kagome-honeycomb lattice system

Leonardo S. Lima

Summary: This study investigates the thermodynamic quantities, such as entropy, specific heat, and magnetic susceptibility, in the next-nearest-neighbors Heisenberg model on a honeycomb-kagome lattice. The linear spin-wave approach is applied to obtain the temperature-dependent behavior of these quantities. Additionally, the entanglement negativity, a quantifier of quantum entanglement, and the spin Hall conductivity are also studied. The results show that all the thermodynamic quantities, as well as the entanglement negativity and spin Hall conductivity, exhibit an increasing trend with temperature. Furthermore, it is found that all the analyzed quantities approach zero in the low-temperature limit, consistent with experimental observations.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

Large conventional and inverse magnetocaloric effects in RE2Ga2Mg (RE = Tm, Er, Ho) compounds

Zhaoxing Wang, Maximilian Kai Reimann, Wang Chen, Yikun Zhang, Rainer Poettgen

Summary: The Mo2FeB2-type compounds RE2Ga2Mg (RE = Tm, Er, Ho) exhibit a large magnetocaloric effect, making them promising for cryogenic magnetic cooling applications.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)