4.5 Article

Magnetic, optical and relaxometric properties of organically coated gold-magnetite (Au-Fe3O4) hybrid nanoparticles for potential use in biomedical applications

期刊

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
卷 324, 期 15, 页码 2373-2379

出版社

ELSEVIER
DOI: 10.1016/j.jmmm.2012.03.005

关键词

Hybridnanoparticle; Superparamagnetic; MRI contrast agent

资金

  1. Foundation Cariplo [2010-0612]
  2. Italian MIUR through FIRB [RBPR05JH2P]

向作者/读者索取更多资源

We present the magnetic, optical and relaxometric properties of multifunctional Au-Fe3O4 hybrid nanoparticles (HNPs), as possible novel contrast agents (CAs) for magnetic resonance imaging (MRI). The HNPs have been synthesized by wet chemical methods in heterodimer and core-shell geometries and capped with oleylamine. Structural characterization of the samples have been made by X-ray diffraction and transmission electron microscopy, while magnetic properties have been investigated by means of Superconducting Quantum Interference Device-SQUID magnetometry experiments. As required for MRI applications using negative CAs, the samples resulted superparamagnetic at room temperature and well above their blocking temperatures. Optical properties have been investigated by analyzing the optical absorbtion spectra collected in UV-visible region. Relaxometric measurements have been performed on organic suspensions of HNPs and Nuclear Magnetic Resonance (NMR) dispersion curves have been obtained by measuring the longitudinal 1/T-1 and transverse 1/T-2 relaxation rates of solvent protons in the range 10 kHz1300 MHz at room temperature. NMR relaxivities r(1) and r(2) have been compared with ENDOREM (R), one of the commercial superparamagnetic iron oxide based MRI contrast agents. MRI contrast enhancement efficiencies have been investigated also by examining T-2-weighted MR images of suspensions. The experimental results suggest that the nanoparticles' suspensions are good candidates as negative CAs. (C) 2012 Elsevier B.V. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.5
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Chemistry, Multidisciplinary

3d Metal Doping of Core@Shell Wustite@ferrite Nanoparticles as a Promising Route toward Room Temperature Exchange Bias Magnets

Beatrice Muzzi, Martin Albino, Michele Petrecca, Claudia Innocenti, Cesar de Julian Fernandez, Giovanni Bertoni, Clara Marquina, Manuel Ricardo Ibarra, Claudio Sangregorio

Summary: In this study, the effect of dual-doping of Fe-(II) with Co-(II) and Ni-(II) on crystal structure and magnetic properties is investigated. The results show that Ni-Co doped iron oxide core@shell nanoparticles with high coercivity and increased antiferromagnetic ordering transition temperature close to room temperature can be obtained.
Article Physics, Applied

Magnetoplasmonics in confined geometries: Current challenges and future opportunities

Nicolo Maccaferri, Alessio Gabbani, Francesco Pineider, Terunori Kaihara, Tlek Tapani, Paolo Vavassori

Summary: Plasmonics offers a unique method to confine and enhance electromagnetic radiation below the diffraction limit, with potential applications in energy harvesting, optoelectronics, and nanoscale biochemistry. The emerging field of magnetoplasmonics aims to merge magnetism and plasmonics to control localized plasmons or electromagnetic-induced collective electronic excitations using magnetic properties. This Perspective reviews the current state, challenges, and future opportunities in confined magnetoplasmonics, highlighting research directions in hybrid systems and novel materials, and recent developments in plasmon-driven magnetization dynamics, nanoscale opto-magnetism, and acousto-magnetoplasmonics.

APPLIED PHYSICS LETTERS (2023)

Article Chemistry, Multidisciplinary

Multinuclear solid state nuclear magnetic resonance for studying CsPbBr3 nanocubes

Andrea Scarperi, Noemi Landi, Alessio Gabbani, Nabila Jarmouni, Silvia Borsacchi, Lucia Calucci, Andrea Pucci, Elisa Carignani, Francesco Pineider, Marco Geppi

Summary: Cesium lead bromide perovskite (CsPbBr3) cubic nanocrystals were obtained by colloidal synthesis and characterized using multinuclear Solid State NMR (SSNMR), X-Ray Diffraction (XRD), Transmission Electron Microscopy (TEM), and optical spectroscopy. The different components of the nanocubes were studied separately by NMR, which also investigated the surface ligands and their interactions. The structural investigation of the perovskite nanocubes was addressed by exploiting spectral properties using Pb-207 and Cs-133 nuclei.

PURE AND APPLIED CHEMISTRY (2023)

Article Instruments & Instrumentation

Automatic thermograms segmentation, preliminary insight into spilling drop test

J. Melada, P. Arosio, M. Gargano, N. Ludwig

Summary: In this study, three different image segmentation methods were used to estimate the wet area of building surfaces characterized by the spilling drop test. The results were compared with standardized methods for moisture assessment, and pore size distribution was evaluated using nuclear magnetic resonance. The study shows the potential of thermographic methods in providing valuable information for the conservation of historical building materials.

QUANTITATIVE INFRARED THERMOGRAPHY JOURNAL (2023)

Article Chemistry, Multidisciplinary

Proton Therapy, Magnetic Nanoparticles and Hyperthermia as Combined Treatment for Pancreatic BxPC3 Tumor Cells

Francesca Brero, Paola Calzolari, Martin Albino, Antonio Antoccia, Paolo Arosio, Francesco Berardinelli, Daniela Bettega, Mario Ciocca, Angelica Facoetti, Salvatore Gallo, Flavia Groppi, Claudia Innocenti, Anna Laurenzana, Cristina Lenardi, Silvia Locarno, Simone Manenti, Renato Marchesini, Manuel Mariani, Francesco Orsini, Emanuele Pignoli, Claudio Sangregorio, Francesca Scavone, Ivan Veronese, Alessandro Lascialfari

Summary: This study investigates the effects of proton therapy combined with hyperthermia and magnetic fluid hyperthermia using magnetic nanoparticles on BxPC3 pancreatic cancer cells. The cells' response to the combined treatment was evaluated through various analyses. The results showed that the combination therapy had a stronger inhibitory effect on the survival of cancer cells compared to single irradiation treatment, suggesting a new and effective approach for treating pancreatic tumors. The presence of magnetic nanoparticles and hyperthermia also played a role in enhancing the therapeutic effects.

NANOMATERIALS (2023)

Article Chemistry, Multidisciplinary

1H-NMR Relaxation of Ferrite Core-Shell Nanoparticles: Evaluation of the Coating Effect

Francesca Brero, Paolo Arosio, Martin Albino, Davide Cicolari, Margherita Porru, Martina Basini, Manuel Mariani, Claudia Innocenti, Claudio Sangregorio, Francesco Orsini, Alessandro Lascialfari

Summary: We investigated the effect of different organic coatings on the H-1-NMR relaxation properties of ultra-small iron-oxide-based magnetic nanoparticles. Magnetization measurements revealed similar behavior as a function of temperature and field for nanoparticles with different coatings but the same core diameter. However, the H-1-NMR longitudinal relaxivity showed different intensity and frequency behavior for the smallest particles depending on the kind of coating, indicating different electronic spin dynamics. On the other hand, no differences were found in the relaxivity of the biggest particles when the coating was changed.

NANOMATERIALS (2023)

Article Chemistry, Multidisciplinary

Shaping Silver Nanoparticles' Size through the Carrier Composition: Synthesis and Antimicrobial Activity

Margherita Cacaci, Giacomo Biagiotti, Gianluca Toniolo, Martin Albino, Claudio Sangregorio, Mirko Severi, Maura Di Vito, Damiano Squitieri, Luca Contiero, Marco Paggi, Marcello Marelli, Stefano Cicchi, Francesca Bugli, Barbara Richichi

Summary: The worldwide crisis of bacterial resistance to traditional antibiotics has prompted research into the development of silver-based nanomaterials with enhanced antibacterial activity. This study describes the synthesis of three different silver nanoparticle hybrids using organic and inorganic supports. The tuning of the silver nanoparticles' shape and size according to the type of support used was also investigated. The resulting composite materials showed effective antibacterial activity against clinically relevant multi-drug-resistant bacteria and the fungus Candida albicans.

NANOMATERIALS (2023)

Article Materials Science, Multidisciplinary

Dosimetric Double Network Hydrogel Based on Poly(vinyl-alcohol)/ Phenylalanine-Derivatives with Enhanced Mechanical Properties

Silvia Locarno, Salvatore Gallo, Paolo Arosio, Chantal Biordi, David Dallasega, Marco Gargano, Nicola Ludwig, Francesco Orsini, Emanuele Pignoli, Ivan Veronese, Cristina Lenardi

Summary: An innovative double network hydrogel with improved mechanical-elastic properties was obtained by adding self-assembling phenylalanine derivatives to a PVA hydrogel. Mechanical tests showed that the addition of phenylalanine derivatives increased the stiffness, toughness, and stretchability of the hydrogel.

ACS APPLIED POLYMER MATERIALS (2023)

Article Chemistry, Physical

Water Dynamics in Dextran-Based Hydrogel Micro/Nanoparticles Studied by NMR Diffusometry and Relaxometry

Evrim Umut, Maria Jardim Beira, Mecit Halil Oztop, Nurettin Sahiner, Pedro Jose Sebastiao, Danuta Kruk

Summary: Water dynamics in mesoporous dextran hydrogel micro/nanoparticles was investigated using NMR techniques. The study found different fractions of water molecules based on their interaction with the gel matrix. The mechanisms of molecular motion were further clarified based on the relaxation contribution and diffusion coefficients.

JOURNAL OF PHYSICAL CHEMISTRY B (2023)

Article Chemistry, Multidisciplinary

Full Spectroscopic Characterization of the Molecular Oxygen-Based Methane to Methanol Conversion over Open Fe(II) Sites in a Metal-Organic Framework

Alessandro Tofoni, Francesco Tavani, Marco Vandone, Luca Braglia, Elisa Borfecchia, Paolo Ghigna, Dragos Costantin Stoian, Toni Grell, Sara Stolfi, Valentina Colombo, Paola D'Angelo

Summary: Iron-based enzymes efficiently activate molecular oxygen to perform the oxidation of methane to methanol (MTM). In this study, the MIL-100(Fe) metal-organic framework (MOF) is used as a catalyst for the direct MTM conversion using O-2 as the oxidant under mild conditions. Advanced operando X-ray techniques are employed to investigate the mechanism and reaction pathway of the MOF catalyst, confirming its potential for active site regeneration.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2023)

Review Chemistry, Inorganic & Nuclear

The effect of size, shape, coating and functionalization on nuclear relaxation properties in iron oxide core-shell nanoparticles: a brief review of the situation

Paolo Arosio, Francesco Orsini, Francesca Brero, Manuel Mariani, Claudia Innocenti, Claudio Sangregorio, Alessandro Lascialfari

Summary: In this perspective article, we review the most significant case studies on magnetic nanoparticles for potential applications in nanomedicine, especially in magnetic resonance imaging. The dependence of the relaxation behavior of magnetic nanoparticles on their chemico-physical properties is discussed in detail. The correlations between the efficiency of magnetic nanoparticles as contrast agents in magnetic resonance imaging and their magnetic core (mainly iron oxides), size and shape, and the coating and solvent used for biocompatibility and dispersibility in physiological media are critically reviewed. Finally, the heuristic model proposed by Roch and coworkers is presented, and its advantages and limitations are highlighted through the analysis of a large amount of experimental data.

DALTON TRANSACTIONS (2023)

Article Chemistry, Multidisciplinary

Magnetic Circular Dichroism Elucidates Molecular Interactions in Aggregated Chiral Organic Materials

Alessio Gabbani, Andrea Taddeucci, Marco Bertuolo, Francesco Pineider, Laura Antonella Aronica, Lorenzo Di Bari, Gennaro Pescitelli, Francesco Zinna

Summary: Magnetic circular dichroism can elucidate the molecular interactions and structural parameters of organic chiral materials, making it a valuable tool for studying supramolecular order and structure-property relationships.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

Article Chemistry, Physical

Rapid self-healing in IR-responsive plasmonic indium tin oxide/polyketone nanocomposites

Esteban Araya-Hermosilla, Alessio Gabbani, Arianna Mazzotta, Marina Ruggeri, Felipe Orozco, Valentina Cappello, Mauro Gemmi, Ranjita K. Bose, Francesco Picchioni, Francesco Pineider, Virgilio Mattoli, Andrea Pucci

Summary: In this study, a thermo-responsive nanocomposite containing homogeneously dispersed indium tin oxide (ITO) nanocrystals was designed, which showed rapid heating and self-healing capabilities using an infrared photothermal source.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

Article Materials Science, Multidisciplinary

Remote detection of bovine serum albumin (BSA) using cantilever beam magnetometer

Bibhutibhusan Nayak, S. Narayana Jammalamadaka

Summary: This article presents a method for remote detection of bovine serum albumin (BSA) using modified cantilever beam magnetometry (CBM). By combining a magnetostrictive Fe70Ga30 cantilever with optical detection technique, researchers were able to detect high concentrations of BSA remotely. The results of this study demonstrate the potential of this method in estimating the magnetostriction of thin films.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

Influence of magnetic external field and particle size on the formation of a single domain state

Yu Hao, R. E. Camley, Z. Celinski

Summary: Magnetic particles have various applications and their magnetic state is determined by their size and the strength of an applied magnetic field. Numerical simulations were performed to study the effect of an applied field on the critical size of single-domain magnetic particles, and the critical field at which a particle becomes single-domain was determined.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

Smart nanocomposite SrFe12O19/α or γ - Fe2O3 thin films with adaptive magnetic properties

Nitesh Singh, Naresh Kumar, Dharohar Sahadot, Anil Annadi, Vidyadhar Singh, Murtaza Bohra

Summary: The unique magnetic properties of FM/AFM and hard-FM/soft-FM nanocomposite thin films have significant relevance for numerous applications. The composition and performance of different magnetic phases in the nanocomposite films can be significantly affected by the laser ablation conditions and annealing temperature.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

A symmetric T-H shape wideband negative index metamaterial for 28-GHz millimeter-wave applications

Alya Ali Musaed, Samir Salem Al-Bawri, Khaled Aljaloud, Wazie M. Abdulkawi, Mohammad Tariqul Islam, Mandeep Jit Singh, Zaini Sakawi, Husam Hamid Ibrahim

Summary: This research presents a wideband tunable metamaterial for body-centric applications in the millimeter-wave frequency band. The proposed metamaterial has a wide operating frequency range and enhanced gain, making it suitable for improving the antenna performance in 5G wireless communication systems.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

Structure and properties of NdCuGa3 single crystals

Binod K. Rai, Boris Maiorov, Krzysztof Gofryk, Patrick O'Rourke, Catherine Housley, Henry Ajo, Asraf Sawon, Arjun K. Pathak, Narayan Poudel, Qiang Zhang, Travis J. Williams, Matthias Frontzek

Summary: This manuscript reports on the structural and magnetic properties of NdCuGa3. The study confirmed the crystal structure and magnetic phase transition of NdCuGa3 using XRD, neutron diffraction, magnetization, and specific heat measurements. The neutron diffraction data further confirmed the antiferromagnetic phase of NdCuGa3.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

A multiferroic coupling mechanism in the polar interface region of GaN-ZnO heterojunction: A first-principle study

Haonan Li, Cong Li, Hailiang Huang, Guodong Hao, Fei Wang

Summary: The electronic structure and ferroelectric-ferromagnetic coupling properties of Y-doped and vacancy-containing GaN-ZnO heterojunctions are systematically investigated. The magnetism in vacancy-containing systems is generated by the spin polarization of unpaired electrons induced by cationic vacancies, while in Y-doped systems, bound magnetic polarons are formed by the orbital hybridization of s-state and d-state electrons of Y-doped elements.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

Co-precipitation method followed by ultrafast sonochemical synthesis of aluminium doped M type BaFe11.4-xAlxCo0.6O19 hexaferrites for various applications

Muhammad Ijaz, Hafeez Ullah, Bandar Ali Al-Asbahi, Mati Ullah Khan, Zaheer Abbas, Sana Ullah Asif

Summary: M-type BaFe11.4-xAlxCo0.6O19 hexaferrites with Al3+ substitutions were synthesized using the co-precipitation method followed by Sonochemical process. The synthesized materials were characterized using XRD, FTIR, UV-vis spectroscopy, VSM, SEM, and LCR meter. The results showed that aluminum doping decreased the band gap and enhanced the magnetic and dielectric properties of the hexaferrites, making them suitable for various applications.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

Magnons in the fan phase of anisotropic frustrated antiferromagnets

Oleg I. Utesov

Summary: The elementary excitations spectrum of anisotropic frustrated antiferromagnets in the fan phase is discussed. It is found that the low-energy part of the spectrum consists of a gapless phason branch with linear dispersion and a gapped optical branch corresponding to the fan structure amplitude oscillations. In the high-energy part of the spectrum, the excitations are similar to the magnons of the fully polarized phase.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

Vapor bubbles departure frequency at ferrofluid boiling on a single nucleation site in a uniform horizontal magnetic field

Alexander Ya. Simonovskii, Alexander A. Yanovskii, Arthur R. Zakinyan

Summary: In this study, the departure frequency of vapor bubbles during boiling of ferrofluid in a horizontal magnetic field is experimentally investigated. Two methods, visual and inductive, are used to measure the frequency of bubble departure. The results show that the bubble departure frequency can decrease with increasing magnetic field strength and increase with increasing temperature of the heat-emitting surface. A linear stability analysis is conducted to analyze the influence of the magnetic field on the frequency of bubble formation during ferrofluid boiling.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

Magnetic and transformation properties of Ni2MnGa combinatorically substituted with 5 at.% of transition elements from Cr to Cu - Experimental insight

Oleg Heczko, Michal Rames, Vit Kopecky, Petr Vertat, Michal Varga, Ladislav Straka

Summary: Heusler Ni-Mn-Ga alloys are multiferroic materials that exhibit magnetic shape memory (MSM) phenomena. By doping transition elements into Ni2MnGa alloys, the transformation temperatures can be modified and complex behaviors can be observed, such as the variation in saturation magnetization and the effects of elemental substitution on compound properties.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

DFT calculations for electronic and magnetic properties of full Heusler Fe2MnAs alloy in perfect and defect structures

Carlos Ariel Samudio Perez, Ariel Flaig de Marchi

Summary: This study investigates the electronic and magnetic properties of the Full-Heusler Fe2MnAs alloy using first-principles calculations. The alloy may form spontaneously and exhibits a ferromagnetic order and high spin-polarization. It can be transformed into a half-metal by contracting the lattice constant. Additionally, certain defects contribute to the spin-polarization of the alloy, making it a fully half-metallic material.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

Enhancing electromagnetic properties through carbon Nanotube-Based polymer composites

Satish Geeri, Aditya Kolakoti, Prasadarao Bobbili

Summary: In this study, an electromagnetic wave-absorbing material was fabricated using a polymer composite material with fiber orientation and Multiwall Carbon Nanotubes as filler materials, along with a Perfect Electric Conducting material. The experiments demonstrated strong electromagnetic absorbing properties for the composites with PEC-coated and non-PEC-coated materials. Mechanical, thermal, and morphological analysis confirmed the similar trend in properties. CRITIC analysis helped identify the sequence order of sustaining properties for the fabricated composites.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

First-principles prediction of intrinsic piezoelectricity, spin-valley splitting and magneto-crystal anisotropy in 2H-VS2 magnetic semiconductor

Yankai Chen, Ruoxue Zhang, Yukai An

Summary: The piezoelectricity, valley character, and magnetic properties of 2H-VS2 monolayer were studied, revealing its potential applications in spintronics and valleytronics due to its bipolar magnetic semiconductor characteristics and superior physical properties.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

Thermodynamic, entanglement and spin Hall conductivity on kagome-honeycomb lattice system

Leonardo S. Lima

Summary: This study investigates the thermodynamic quantities, such as entropy, specific heat, and magnetic susceptibility, in the next-nearest-neighbors Heisenberg model on a honeycomb-kagome lattice. The linear spin-wave approach is applied to obtain the temperature-dependent behavior of these quantities. Additionally, the entanglement negativity, a quantifier of quantum entanglement, and the spin Hall conductivity are also studied. The results show that all the thermodynamic quantities, as well as the entanglement negativity and spin Hall conductivity, exhibit an increasing trend with temperature. Furthermore, it is found that all the analyzed quantities approach zero in the low-temperature limit, consistent with experimental observations.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)

Article Materials Science, Multidisciplinary

Large conventional and inverse magnetocaloric effects in RE2Ga2Mg (RE = Tm, Er, Ho) compounds

Zhaoxing Wang, Maximilian Kai Reimann, Wang Chen, Yikun Zhang, Rainer Poettgen

Summary: The Mo2FeB2-type compounds RE2Ga2Mg (RE = Tm, Er, Ho) exhibit a large magnetocaloric effect, making them promising for cryogenic magnetic cooling applications.

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS (2024)