Article
Polymer Science
Kexuan Chen, Yuan Liu, Ren He, Qi Wang
Summary: This study proposes a novel strategy for preparing form-stable phase change materials using polyethylene glycol (PEG) and polyvinyl formal (PVF) in a foam structure. The PEG/PVF composites exhibit good performance in terms of phase transition enthalpy, residue amount, and thermal degradation temperature.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Materials Science, Composites
Dwane E. Cossey, Stephen A. Hodge, Panagiotis G. Karagiannidis
Summary: This study reports the fabrication of nanocomposites with a poly(benzoxazine-co-epoxy) matrix reinforced with 1 wt% graphene. The addition of single fillers caused a delay in polymerisation and an increase in exothermic peak temperature, resulting in a reduction in ΔH-Total. Copolymerisation led to a decrease in tensile modulus and strength compared to the neat copolymer, while the nanocomposite with 0.7 wt% Nanene-002 + 0.3 wt% Nanene-001 showed the highest increase in tensile strength and elongation at break. Additionally, the thermal stability of the materials was improved.
JOURNAL OF REINFORCED PLASTICS AND COMPOSITES
(2023)
Article
Multidisciplinary Sciences
Nianqing Zhu, Xinxing Gao, Jilei Liang, Yan Wang, Rongjie Hou, Zhongbing Ni
Summary: Melt blending is an effective method for preparing new composite materials, but most polymers are incompatible. By adding suitable compatibilizers, the interfacial tension can be reduced and fine and stable morphology can be obtained. In this study, LDPE/PS composites were compatibilized using SEBS-g-MAH and OMMT, leading to improved compatibility and enhanced mechanical properties.
Article
Chemistry, Physical
Haoxuan Sun, Jun Zhang
Summary: This study investigated the effect of SiO2 content on the superhydrophobicity of epoxy resin coatings and the improvement of cracking properties by SEBS-g-MAH. A robust superhydrophobic coating was successfully fabricated by combining EP, SEBS-g-MAH, and superhydrophobic SiO2 particles.
SURFACES AND INTERFACES
(2022)
Article
Chemistry, Multidisciplinary
A. Abdeldaym, Rania F. Khedr, Rabab S. Jassas
Summary: Polymer materials made of Polypyrrole (PPy) with different percentages of clay nanoparticles have shown significant impact on structure and mechanical behavior. These materials have demonstrated efficient removal of heavy metal water contaminants and potential for broader industrial applications.
SUSTAINABLE CHEMISTRY AND PHARMACY
(2021)
Article
Polymer Science
Kourosh Sayar Dogahe, Somaye Akbari, Mohammad Haghighat Kish
Summary: Eco-friendly PVA films and their composites with additives were fabricated and characterized, revealing chemical and physical interactions. The presence of APTES-HNTs significantly influenced the viscoelastic behavior of the films and improved the mechanical properties of PVA, making it suitable for further applications.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Polymer Science
Anna Raffaela de Matos Costa, Carlos Bruno Barreto Luna, Emanuel Pereira do Nascimento, Eduardo da Silva Barbosa Ferreira, Claudia de Matos Costa, Yeda Medeiros Bastos de Almeida, Edcleide Maria Araujo
Summary: In this study, PLA/ABS blends compatibilized with SEBS-g-MA were prepared using a co-rotational twin-screw extruder. The influence of the compatibilizing agent on the properties of the blends was analyzed, including morphology, mechanical, thermal, thermomechanical, and rheological properties. The results showed that the addition of SEBS-g-MA significantly improved the impact strength of the blends. Annealing also played a role in increasing the crystallinity and heat deflection temperatures of the blends. The study suggests that the PLA/ABS/SEBS-g-MA system has potential for use in 3D-printing filaments.
Article
Polymer Science
Md Abu Shaid Sujon, Tito Andriollo, Aminul Islam
Summary: This investigation focuses on enhancing the damping properties of MABS by blending it with VDT and SEBS-g-MAH. The results show that the blend's damping performance increases with the amount of VDT, while the inclusion of 4% SEBS-g-MAH leads to the most substantial improvements.
JOURNAL OF POLYMER RESEARCH
(2023)
Article
Biochemistry & Molecular Biology
Udangshree Boro, Aradhana Priyadarsini, Vijayanand S. Moholkar
Summary: In this study, nanocomposites of polylactic acid (PLA) with clove essential oil (CEO) and alkali treated halloysite nanotubes (NHNT) were synthesized. The nanocomposite films showed enhanced physical, thermal, mechanical and water vapor barrier properties. Practical packaging tests on apples stored at room temperature showed substantially improved results compared to PLA in terms of weight loss, microbial count, firmness, acidity, pH, and total soluble solids. The results demonstrate the potential of PLA/CEO/NHNT nanocomposite films as active food packaging material.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2022)
Article
Polymer Science
Fatin Najwa Joynal Abedin, Hamidah Abdul Hamid, Abbas F. M. Alkarkhi, Salem S. Abu Amr, Nor Afifah Khalil, Ahmad Naim Ahmad Yahaya, Md. Sohrab Hossain, Azman Hassan, Muzafar Zulkifli
Summary: The incorporation of talc reduces the stiffness of composites, while the addition of graphene oxide and SEBS-g-MAH significantly improves the mechanical and thermal properties of ABS polymer matrix. ABS/talc composites prepared through melt mixing showed increased tensile strength, flexural strength, and flexural modulus, as well as comparable impact strength to ABS. The addition of GO and SEBS-g-MAH also provided higher thermal stability for both composites with and without talc.
Article
Materials Science, Multidisciplinary
Udangshree Boro, Vijayanand S. Moholkar
Summary: Nanocomposites of PLA with ZnO deposited HNT were synthesized by ultrasound assisted solvent casting. The synthesized films showed improved physical, thermal, mechanical properties, UV-shielding, barrier properties, and antimicrobial activities for food packaging applications. The 2 wt% ZnO@HNT nanocomposite film exhibited the best performance and demonstrated potential as an effective food packaging material.
MATERIALS TODAY COMMUNICATIONS
(2022)
Article
Polymer Science
Akihiko Toda
Summary: The crystallization kinetics of poly(butylene terephthalate) under high supercooling was investigated using Temperature-Modulated Fast Scanning Calorimetry (TM-FSC). The study found a temperature dependence of crystal growth rate and compared it with the peak time of heat flow during isothermal crystallization. The crystal growth rate was found to be practically determined by a mobility factor near the glass transition.
Article
Polymer Science
Nader Zirak, Mohammadali Shirinbayan, Khaled Benfriha, Michael Deligant, Abbas Tcharkhtchi
Summary: This study investigates the effects of different sub-build orientations on the thermal and mechanical properties of acrylate-based 3D printing SLA rapid-prototyping photosensitive resin during UV and thermal post-curing. Polymerization is shown to play a key role in determining the final mechanical and thermal properties.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Thermodynamics
Rui Zhang, Fanfan Du, Katalee Jariyavidyanont, Evgeny Zhuravlev, Christoph Schick, Rene Androsch
Summary: By analyzing different grades of PDLLA using fast scanning calorimetry, it is found that the glass transition dynamics of PDLLA and PLLA are essentially the same, suggesting that stereoisomerism does not influence the glass transition dynamics.
THERMOCHIMICA ACTA
(2022)
Article
Polymer Science
Xiangning Wen, Yunlan Su, Guoming Liu, Shaofan Li, Alejandro J. Muller, Sanat K. Kumar, Dujin Wang
Summary: The correlation between the dispersion quality of PEG-grafted silica nanoparticles and the crystallization ability of PEO nanocomposites was systematically investigated, revealing that high sigma and low P/N conditions can increase the nucleation rate of PEO. This study highlights the importance of nanoparticle dispersion and grafting characteristics in influencing the crystallization behavior of polymer nanocomposites, leading to novel and unexpected results.