Single-crystalline spherical beta-Ga2O3 particles: Synthesis, N-doping and photoluminescence properties

We report on the synthesis of single-crystalline spherical beta-Ga2O3 particles by a simple method in ambient atmosphere. No pre-treatment, catalyst, substrate, or gas flow was required during the synthesis process. The well-dispersed Ga2O3 particles display uniform spherical morphology with an average diameter of similar to 200 nm. Photoluminescence studies indicate that the Ga2O3 particles exhibit a broad blue-green light emission and an interesting red light emission at room temperature. The red light emission can be further tuned by post-annealing of the particles in ammonia atmosphere. The present single-crystalline beta-Ga2O3 particles with spherical morphology, uniform sub-micrometer sizes and tunable light emission are envisaged to be of high promise for applications in white-LED phosphors and optoelectronic devices. (c) 2013 Elsevier B.V. All rights reserved.